Citation: LIU Shou-guang, LIU Yue, LIU Yi-mo, WANG Yu-he. Hydrogen production by steam reforming of bio-oils over mesoporous Ni/MgO catalyst[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(4): 424-431. shu

Hydrogen production by steam reforming of bio-oils over mesoporous Ni/MgO catalyst

College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, China

Corresponding author: WANG Yu-he, wangyuhe@hrbnu.edu.cn
Received Date: 9 January 2020
Revised Date: 1 February 2020

Fund Project: Overseas Scholars Program of Department of Education, Heilongjiang Province 1155h019The project was supported by Overseas Scholars Program of Department of Education, Heilongjiang Province (1155h019)

Figures(6)

A catalyst support of mesoporous MgO was prepared using hydrothermal method, with which a mesoporous Ni/MgO catalyst was prepared by impregnation method. The hydrogen production experiment by steam reforming of biomass oil models and two kinds of commercial biomass oils over the mesoporous Ni/MgO catalyst was conducted. The results show that the furfural conversion, hydrogen yield and hydrogen selectivity increase with increasing the reaction temperature. When the reaction temperature is increased to 600 ℃, the furfural conversion and the hydrogen yield reach 94.9% and 83.2%, respectively. In addition, the hydrogen yields for steam reforming of furfural/acetic acid and furfural/hydroxyacetone reach 87.3% and 86.8%, respectively, which are higher than the corresponding hydrogen yields in steam reforming furfural. The result indicates that the acetic acid or hydroxyacetone can promote the conversion of furfural which is the main organic component in the simulated biomass oil. When the commercial biomass oils is used, the conversion of main organics, hydrogen yield and hydrogen selectivity exhibit an increasing trend with the increase of the ratio of water to the carbon of reactant (S/C = 5, 10, 15, 20, 25). Under the S/C(molar ratio)=20, the conversion of main organic components (furfural, acetic acid, and hydroxyacetone) in two kinds of biomass oils can reach more than 90% and the yield of hydrogen can also be more than 81.0%, showing that the mesoporous Ni/MgO catalyst also has higher catalytic activity for the steam reforming of commercial biomass oils.
- hydrogen production,
- mesoporous Ni/MgO catalyst,
- furfural,
- biomass oil
1. [1]
  DAS D, VEZIROGLU T N. Hydrogen production by biological processes:A survey of literature[J]. Int J Hydrogen Energy, 2001,26(1):13-28.
2. [2]
  SIRIRUANG C, CHAROJROCHKUL S, TOOCHINDA P. Hydrogen production from methanol-steam reforming at low temperature over Cu-Zn/ZrO₂-doped Al₂O₃[J]. Monatsh Chem, 2016,147(7):1143-1151.
3. [3]
  BLEISCHWITZ R, BADER N. Policies for the transition towards a hydrogen economy:the EU case[J]. Energy Policy, 2010,38(10):5388-5398.
4. [4]
  FIERRO J L G, PENA M A, GOMEZ J P. New catalytic routes for syngas and hydrogen production[J]. Appl Catal A:Gen, 1996,144(1/2):7-57.
5. [5]
  KOTHARI R, BUDDHI D, SAWHNEY R L. Comparison of environmental and economic aspects of various hydrogen production methods[J]. Renewable Sustainable Energy Rev, 2008,12(2):553-563.
6. [6]
  TANG Can. Research status of bio-oil steam catalytic reforming for hydrogen production[J]. Appl Energy Technol, 2019(6):1-3.
7. [7]
  NAKAMURA K, MIYAZAWA T, SAKURAI T, MIYAO T, NAITO S, BEGUM N, KUNIMORI K, TOMISHIGE K. Promoting effect of MgO addition to Pt/Ni/CeO₂/Al₂O₃ in the steam gasification of biomass[J]. Appl Catal B:Environ, 2009,86(1/2):36-44.
8. [8]
  SATO K, FUJIMOTO K. Development of new nickel based catalyst for tar reforming with superior resistance to sulfur poisoning and coking in biomass gasification[J]. Catal Commun, 2007,8(11):1697-1701.
9. [9]
  XIE Deng-yin, ZHANG Su-ping, CHEN Zhi-yuan, CHEN Zhen-qi, XU Qing-li. Co and Cu modified Ni/Al₂O₃ steam reforming catalysts for hydrogen production from model bio-oil[J]. J Fuel Chem Technol, 2015,43(3):302-308.
10. [10]
  WANG Yi-shuang, CHEN Ming-qiang, LIU Shao-min, YANG Zhong-lian, SHEN Chao-ping, LIU Ke. Hydrogen production via catalytic steam reforming of bio-oil model compounds over NiO-Fe₂O₃-loaded palygouskite[J]. J Fuel Chem Technol, 2015,43(12):1470-1475.
11. [11]
  YANG X, WANG Y, LI M, SUN B, LI Y, WANG Y. Enhanced hydrogen production by steam reforming of acetic acid over a Ni catalyst supported on mesoporous MgO[J]. Energy Fuels, 2016,30(3):2198-2203.
12. [12]
  WANG Y, YANG X, WANG Y. Catalytic performance of mesoporous MgO supported Ni catalyst in steam reforming of model compounds of biomass fermentation for hydrogen production[J]. Int J Hydrogen Energy, 2016,41(40):17846-17857.
13. [13]
  YANG X, WANG Y, WANG Y. Significantly improved catalytic performance of Ni-based MgO catalyst in steam reforming of phenol by inducing mesostructure[J]. Catalysts, 2015,5(4):1721-1736.
14. [14]
  WANG Y, JI T, YANG X, WANG Y. Comparative study on steam reforming of single- and multicomponent model compounds of biomass fermentation for producing biohydrogen over mesoporous Ni/MgO catalyst[J]. Energy Fuels, 2016,30(10):8432-8440.
15. [15]
  JI Ting-ting, YANG Xiao-xuan, WANG Ya-jing, WANG Yu-he. Steam reforming of phenol for producing hydrogen by metal Ni support on MgO prepared by different methods[J]. J Fuel Chem Technol, 2016,44(9):1131-1137.
16. [16]
  LING Z, ZHENG M, DU Q, WANG Y, SONG J, DAI W, ZHANG L, JI G, CAO J. Synthesis of mesoporous MgO nanoplate by an easy solvothermal-annealing method[J]. Solid State Sci, 2011,13(12):2073-2079.
17. [17]
  ROSEN J, HUTCHINGS G, JIAO F. Synthesis, structure, and photocatalytic properties of ordered mesoporous metal-doped Co₃O₄[J]. J Catal, 2014,310(1):2-9.
18. [18]
  LI Y, LU G, MA J. Highly active and stable nano NiO-MgO catalyst encapsulated by silica with a core-shell structure for CO₂ methanation[J]. RSC Adv, 2014,4(34)17420.
19. [19]
  YU M, ZHU K, LIU Z, XIAO H, DENG W, ZHOU X. Carbon dioxide reforming of methane over promoted Ni_xMg_1-xO (111) platelet catalyst derived from solvothermal synthesis[J]. Appl Catal B:Environ, 2014,148/149:177-190.
20. [20]
  TZIMAS E, PETEVES D S. The impact of carbon sequestration on the production cost of electricity and hydrogen from coal and natural-gas technologies in Europe in the medium term[J]. Energy, 2005,30(14):2672-2689.
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