Citation: Ye Xingke, Zhou Qianlong, Wan Zhongquan, Jia Chunyang. Research Progress in Electrode Materials and Devices of Flexible Supercapacitors[J]. Chemistry, ;2017, 80(1): 10-33, 76. shu

Research Progress in Electrode Materials and Devices of Flexible Supercapacitors

State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Microelectronics and Solid-State Electronics, University of Electronic Science and Technology of China, Chengdu 610054

Corresponding author: Jia Chunyang, cyjia@uestc.edu.cn
Received Date: 26 May 2016
Accepted Date: 19 July 2016

Figures(22)

Supercapacitor (SC), also called electrochemical capacitor, which has higher power density and longer cycling life than lithium ion battery as well as higher energy density than dielectric capacitor, is a kind of promising energy storage device. The different kinds of flexible and wearable electronic devices are emerging with consumers' increasing requirements for electronic devices. Flexible SC, which is a kind of portable energy storage device, has attracted much attention. The two-dimensional planar-structure and one-dimensional fiber-shaped SCs have been developed rapidly with the flexible electronic devices advancing. In this review, the energy storage mechanism of SCs, the diverse performance metrics and evaluation for SCs as a foundation are first introduced to understand different research approaches. Then, the current state-of-the-art progress in devices' structure design and electrode materials fabrication of the flexible two-dimensional planar-structure and one-dimensional fiber-shaped SCs are summarized. Last, perspectives on the future development of flexible SCs and highlighted key technical challenges with hope of stimulating further research progress are presented.
- Supercapacitor,
- Flexibility,
- Device structure,
- Electrode materials,
- Electrochemical performance
1. [1]
  H W Chen, C Y Hong, C W Kung et al. J. Power Sources, 2015, 288:221-228.
2. [2]
  T Chen, L B Qiu, Z B Yang et al. Angew. Chem. Int. Ed., 2012, 51(48):11977-11980.
3. [3]
  K Jost, D P Durkin, L M Haverhals et al. Adv. Energy Mater., 2015, 5:1401286.
4. [4]
  Q Wu, Y Xu, Z Yao et al. ACS Nano, 2010, 4(4):1963-1970.
5. [5]
  A Pyattaev, K Johnsson, S Andreev et al.IEEE Wireless Commun., 2015, 22:12-18.
6. [6]
  J W Park, J Jang. Carbon, 2015, 87:275-281.
7. [7]
  R F Service. Science, 2003, 301(5635):909-911.
8. [8]
  Y Fu, H Wu, S Ye et al. Energy Environ. Sci., 2013, 6(3):805-812.
9. [9]
  K Jost, G Dion, Y Gogotsi. J. Mater. Chem. A, 2014, 2(28):10776-10787.
10. [10]
  G Wang, L Zhang, J Zhang. Chem. Soc. Rev., 2012, 41(2):797-828.
11. [11]
  K Jost, D Stenger, C R Perez et al. Energy Environ. Sci., 2013, 6(9):2698-2705.
12. [12]
  M Beidaghi, Y Gogotsi. Energy Environ. Sci., 2014, 7(3):867-884.
13. [13]
  Y Huang, J Liang, Y Chen. Small, 2012, 8(12):1805-1834.
14. [14]
  M Zhi, C Xiang, J Li et al. Nanoscale, 2013, 5(1):72-88.
15. [15]
  X Chen, H Lin, P Chen et al. Adv. Mater., 2014, 26(26):4444-4449.
16. [16]
  X Peng, L Peng, C Wu et al. Chem. Soc. Rev., 2014, 43(10):3303-3323.
17. [17]
  X Lu, M Yu, G Wang et al. Energy Environ. Sci., 2014, 7(7):2160-2181.
18. [18]
  Z Weng, Y Su, D W Wang et al. Adv. Energy Mater., 2011, 1(5):917-922.
19. [19]
  G Zhao, F G Zhao, J Sun et al. Carbon, 2015, 94:114-119.
20. [20]
  Y Xu, C Y Chen, Z Zhao et al. Nano Lett., 2015, 15(7):4605-4610.
21. [21]
  F Liu, S Song, D Xue et al. Adv. Mater., 2012, 24(8):1089-1094.
22. [22]
  Z Bo, W Zhu, W Ma et al. Adv. Mater., 2013, 25(40):5799-5806.
23. [23]
  X Yang, J Zhu, L Qiu et al. Adv. Mater., 2011, 23(25):2833-2838.
24. [24]
  Y Xu, Z Lin, X Huang et al. ACS Nano, 2013, 7(5):4042-4049.
25. [25]
  M F El-Kady, V Strong, S Dubin et al. Science, 2012, 335(6074):1326-1330.
26. [26]
  M F El-Kady, R B Kaner. Nat. Commun., 2013, 4:1475.
27. [27]
  T Chen, H Peng, M Durstock et al. Sci. Rep., 2014, 4:3612.
28. [28]
  Z Chen, D Zhang, X Wang et al. Adv. Mater., 2012, 24(15):2030-2036.
29. [29]
  H C Youn, S H Park, K C Roh et al. Curr. Appl. Phys., 2015, 15:S21-S26.
30. [30]
  S K Ujjain, R Bhatia, P Ahuja et al. PLoS One, 2015, 10(7):e0131475.
31. [31]
  A K Geim, I V Grigorieva. Nature, 2013, 499(7459):419-425.
32. [32]
  S Park, R S Ruoff. Nat. Nanotechnol., 2009, 4(4):217-224.
33. [33]
  P Li, C Kong, Y Shang et al. Nanoscale, 2013, 5(18):8472-8479.
34. [34]
  Y Z Zheng, H Y Ding, M L Zhang. Mater. Res. Bull., 2009, 44(2):403-407.
35. [35]
  Y Huang, Y Li, Z Hu et al. J. Mater. Chem. A, 2013, 1(34):9809-9813.
36. [36]
  Y X Zhang, M Huang, F Li et al. J. Power Sources, 2014, 246:449-456.
37. [37]
  C Hao, F Wen, J Xiang et al. Adv. Funct. Mater., 2014, 24(42):6700-6707.
38. [38]
  C Yuan, L Yang, L Hou et al. Energy Environ. Sci., 2012, 5(7):7883-7887.
39. [39]
  A Ramadoss, S J Kim. Electrochim. Acta, 2014, 136:105-111.
40. [40]
  H Xu, X Li, G Wang. J. Power Sources, 2015, 294:16-21.
41. [41]
  F Grote, Y Lei. Nano Energy, 2014, 10:63-70.
42. [42]
  P Tang, L Han, L Zhang et al. ChemElectroChem, 2015, 2(7):949-957.
43. [43]
  M F Warsi, I Shakir, M Shahid et al. Electrochim. Acta, 2014, 135:513-518.
44. [44]
  N R Chiou, C Lui, J Guan et al. Nat. Nanotechnol., 2007, 2(6):354-357.
45. [45]
  J Xu, K Wang, S Z Zu et al. ACS Nano, 2010, 4(9):5019-5026.
46. [46]
  K Wang, W Zou, B Quan et al. Adv. Energy Mater., 2011, 1(6):1068-1072.
47. [47]
  K Wang, P Zhao, X Zhou et al. J. Mater. Chem., 2011, 21(41):16373-16378.
48. [48]
  K Wang, H Wu, Y Meng et al. Energy Environ. Sci., 2012, 5(8):8384-8389.
49. [49]
  Y Meng, K Wang, Y Zhang et al. Adv. Mater., 2013, 25(48):6985-6990.
50. [50]
  J Chen, C Jia, Z Wan. Synth. Met., 2014, 189:69-76.
51. [51]
  W S Hummers, R E Offeman. J. Am. Chem. Soc., 1958, 80:1339-1339.
52. [52]
  J Chen, C Jia, Z Wan. Electrochim. Acta, 2014, 121:49-56.
53. [53]
  Q Zhou, X Ye, Z Wan et al. J. Power Sources, 2015, 296:186-196.
54. [54]
  W Liu, C Lu, X Wang et al. ACS Nano, 2015, 9(2):1528-1542.
55. [55]
  X Cai, M Peng, X Yu et al. J. Mater. Chem. C, 2014, 2(7):1184-1200.
56. [56]
  L V Thong, H Kim, A Ghosh et al. ACS Nano, 2013, 7(7):5940-5947.
57. [57]
  D Yu, Q Qian, L Wei et al. Chem. Soc. Rev., 2015, 44(3):647-662.
58. [58]
  W Zeng, L Shu, Q Li et al. Adv. Mater., 2014, 26(31):5310-5336.
59. [59]
  J Bae, M K Song, Y J Park et al. Angew. Chem. Int. Ed., 2011, 50(7):1683-1687.
60. [60]
  S H Aboutalebi, R Jalili, D Esrafilzadeh et al. ACS Nano, 2014, 8(3):2456-2466.
61. [61]
  Y Meng, Y Zhao, C Hu et al. Adv. Mater., 2013, 25(16):2326-2331.
62. [62]
  M Miao. Carbon, 2011, 49:3755-3761.
63. [63]
  X Chen, L Qiu, J Ren et al. Adv. Mater., 2013, 25(44):6436-6441.
64. [64]
  Z Yang, J Deng, X Chen et al. Angew. Chem. Int. Ed., 2013, 52(50):13453-13457.
65. [65]
  J Ren, W Bai, G Guan et al. Adv. Mater., 2013, 25(41):5965-5970.
66. [66]
  Y Fu, X Cai, H Wu et al. Adv. Mater., 2012, 24(42):5713-5718.
67. [67]
  L Kou, T Huang, B Zheng et al. Nat. Commun., 2014, 5:3754.
68. [68]
  F Su, M Miao, H Niu et al. ACS Appl. Mater. Interf., 2014, 6(4):2553-2560.
69. [69]
  H Xu, X Hu, Y Sun et al. Nano Res., 2015, 8(4):1148-1158.
70. [70]
  D Harrison, F Qiu, J Fyson et al. Phys. Chem. Chem. Phys., 2013, 15(29):12215-12219.
71. [71]
  S T Senthilkumar, R K Selvan. Phys. Chem. Chem. Phys., 2014, 16(29):15692-15698.
72. [72]
  Y Li, K Sheng, W Yuan et al. Chem. Commun., 2013, 49(3):291-293.
73. [73]
  K Jost, D P Durkin, L M Haverhals et al. Adv. Energy Mater., 2015, 5:1401286.
74. [74]
  Z Yu, J Thomas. Adv. Mater., 2014, 26(25):4279-4285.
75. [75]
  H Xu, X Hu, Y Sun et al. Nano Res., 2014, 8(4):1148-1158.
76. [76]
  X Ye, Q Zhou, C Jia et al. Electrochim. Acta, 2016, 206:155-164.
77. [77]
  Q Zhou, C Jia, X Ye et al. J. Power Sources, 2016, 327:365-373.
78. [78]
  L Liu, Y Yu, C Yan et al. Nat. Commun., 2015, 6:7260.
79. [79]
  N Liu, W Ma, J Tao et al. Adv. Mater., 2013, 25(35):4925-4931.
80. [80]
  Y Gogotsi, P Simon. Science, 2011, 334(6058):917-918.
1. [1]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
2. [2]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . Strategies for enhancing capacity and rate performance of two-dimensional material-based supercapacitors. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-0. doi: 10.1016/j.actphy.2025.100063
3. [3]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
4. [4]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
5. [5]
  Zeqiu Chen , Limiao Cai , Jie Guan , Zhanyang Li , Hao Wang , Yaoguang Guo , Xingtao Xu , Likun Pan . Advanced electrode materials in capacitive deionization for efficient lithium extraction. Acta Physico-Chimica Sinica, 2025, 41(8): 100089-0. doi: 10.1016/j.actphy.2025.100089
6. [6]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
7. [7]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
8. [8]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF-Templated Synthesis of Nitrogen-Doped Carbon for Enhanced Electrochemical Sodium Ion Storage and Removal. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-0. doi: 10.3866/PKU.WHXB202405002
9. [9]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-0. doi: 10.3866/PKU.WHXB202311030
10. [10]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . Preparation of High Density Activated Carbon by Mechanical Compression of Precursors for Compact Capacitive Energy Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-0. doi: 10.3866/PKU.WHXB202406009
11. [11]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
12. [12]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008
13. [13]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
14. [14]
  Hongren RONG , Gexiang GAO , Zhiwei LIU , Ke ZHOU , Lixin SU , Hao HUANG , Wenlong LIU , Qi LIU . High-performance supercapacitor based on 1D cobalt-based coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1183-1195. doi: 10.11862/CJIC.20250034
15. [15]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
16. [16]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2406014-0. doi: 10.3866/PKU.WHXB202406014
17. [17]
  Yingtong FAN , Yujin YAO , Shouhao WAN , Yihang SHEN , Xiang GAO , Cuie ZHAO . Construction of copper tetrakis(4-carboxyphenyl)porphyrin/silver nanowire composite electrode for flexible and transparent supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1309-1317. doi: 10.11862/CJIC.20250043
18. [18]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
19. [19]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
20. [20]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084

Get Citation

PDF

XML

Metrics

PDF Downloads(679)
Abstract views(34653)
HTML views(8737)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142