Citation: Ye Xingke, Zhou Qianlong, Wan Zhongquan, Jia Chunyang. Research Progress in Electrode Materials and Devices of Flexible Supercapacitors[J]. Chemistry, ;2017, 80(1): 10-33, 76. shu

Research Progress in Electrode Materials and Devices of Flexible Supercapacitors

State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Microelectronics and Solid-State Electronics, University of Electronic Science and Technology of China, Chengdu 610054

Corresponding author: Jia Chunyang, cyjia@uestc.edu.cn
Received Date: 26 May 2016
Accepted Date: 19 July 2016

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Supercapacitor (SC), also called electrochemical capacitor, which has higher power density and longer cycling life than lithium ion battery as well as higher energy density than dielectric capacitor, is a kind of promising energy storage device. The different kinds of flexible and wearable electronic devices are emerging with consumers' increasing requirements for electronic devices. Flexible SC, which is a kind of portable energy storage device, has attracted much attention. The two-dimensional planar-structure and one-dimensional fiber-shaped SCs have been developed rapidly with the flexible electronic devices advancing. In this review, the energy storage mechanism of SCs, the diverse performance metrics and evaluation for SCs as a foundation are first introduced to understand different research approaches. Then, the current state-of-the-art progress in devices' structure design and electrode materials fabrication of the flexible two-dimensional planar-structure and one-dimensional fiber-shaped SCs are summarized. Last, perspectives on the future development of flexible SCs and highlighted key technical challenges with hope of stimulating further research progress are presented.
- Supercapacitor,
- Flexibility,
- Device structure,
- Electrode materials,
- Electrochemical performance
1. [1]
  H W Chen, C Y Hong, C W Kung et al. J. Power Sources, 2015, 288:221-228.
2. [2]
  T Chen, L B Qiu, Z B Yang et al. Angew. Chem. Int. Ed., 2012, 51(48):11977-11980.
3. [3]
  K Jost, D P Durkin, L M Haverhals et al. Adv. Energy Mater., 2015, 5:1401286.
4. [4]
  Q Wu, Y Xu, Z Yao et al. ACS Nano, 2010, 4(4):1963-1970.
5. [5]
  A Pyattaev, K Johnsson, S Andreev et al.IEEE Wireless Commun., 2015, 22:12-18.
6. [6]
  J W Park, J Jang. Carbon, 2015, 87:275-281.
7. [7]
  R F Service. Science, 2003, 301(5635):909-911.
8. [8]
  Y Fu, H Wu, S Ye et al. Energy Environ. Sci., 2013, 6(3):805-812.
9. [9]
  K Jost, G Dion, Y Gogotsi. J. Mater. Chem. A, 2014, 2(28):10776-10787.
10. [10]
  G Wang, L Zhang, J Zhang. Chem. Soc. Rev., 2012, 41(2):797-828.
11. [11]
  K Jost, D Stenger, C R Perez et al. Energy Environ. Sci., 2013, 6(9):2698-2705.
12. [12]
  M Beidaghi, Y Gogotsi. Energy Environ. Sci., 2014, 7(3):867-884.
13. [13]
  Y Huang, J Liang, Y Chen. Small, 2012, 8(12):1805-1834.
14. [14]
  M Zhi, C Xiang, J Li et al. Nanoscale, 2013, 5(1):72-88.
15. [15]
  X Chen, H Lin, P Chen et al. Adv. Mater., 2014, 26(26):4444-4449.
16. [16]
  X Peng, L Peng, C Wu et al. Chem. Soc. Rev., 2014, 43(10):3303-3323.
17. [17]
  X Lu, M Yu, G Wang et al. Energy Environ. Sci., 2014, 7(7):2160-2181.
18. [18]
  Z Weng, Y Su, D W Wang et al. Adv. Energy Mater., 2011, 1(5):917-922.
19. [19]
  G Zhao, F G Zhao, J Sun et al. Carbon, 2015, 94:114-119.
20. [20]
  Y Xu, C Y Chen, Z Zhao et al. Nano Lett., 2015, 15(7):4605-4610.
21. [21]
  F Liu, S Song, D Xue et al. Adv. Mater., 2012, 24(8):1089-1094.
22. [22]
  Z Bo, W Zhu, W Ma et al. Adv. Mater., 2013, 25(40):5799-5806.
23. [23]
  X Yang, J Zhu, L Qiu et al. Adv. Mater., 2011, 23(25):2833-2838.
24. [24]
  Y Xu, Z Lin, X Huang et al. ACS Nano, 2013, 7(5):4042-4049.
25. [25]
  M F El-Kady, V Strong, S Dubin et al. Science, 2012, 335(6074):1326-1330.
26. [26]
  M F El-Kady, R B Kaner. Nat. Commun., 2013, 4:1475.
27. [27]
  T Chen, H Peng, M Durstock et al. Sci. Rep., 2014, 4:3612.
28. [28]
  Z Chen, D Zhang, X Wang et al. Adv. Mater., 2012, 24(15):2030-2036.
29. [29]
  H C Youn, S H Park, K C Roh et al. Curr. Appl. Phys., 2015, 15:S21-S26.
30. [30]
  S K Ujjain, R Bhatia, P Ahuja et al. PLoS One, 2015, 10(7):e0131475.
31. [31]
  A K Geim, I V Grigorieva. Nature, 2013, 499(7459):419-425.
32. [32]
  S Park, R S Ruoff. Nat. Nanotechnol., 2009, 4(4):217-224.
33. [33]
  P Li, C Kong, Y Shang et al. Nanoscale, 2013, 5(18):8472-8479.
34. [34]
  Y Z Zheng, H Y Ding, M L Zhang. Mater. Res. Bull., 2009, 44(2):403-407.
35. [35]
  Y Huang, Y Li, Z Hu et al. J. Mater. Chem. A, 2013, 1(34):9809-9813.
36. [36]
  Y X Zhang, M Huang, F Li et al. J. Power Sources, 2014, 246:449-456.
37. [37]
  C Hao, F Wen, J Xiang et al. Adv. Funct. Mater., 2014, 24(42):6700-6707.
38. [38]
  C Yuan, L Yang, L Hou et al. Energy Environ. Sci., 2012, 5(7):7883-7887.
39. [39]
  A Ramadoss, S J Kim. Electrochim. Acta, 2014, 136:105-111.
40. [40]
  H Xu, X Li, G Wang. J. Power Sources, 2015, 294:16-21.
41. [41]
  F Grote, Y Lei. Nano Energy, 2014, 10:63-70.
42. [42]
  P Tang, L Han, L Zhang et al. ChemElectroChem, 2015, 2(7):949-957.
43. [43]
  M F Warsi, I Shakir, M Shahid et al. Electrochim. Acta, 2014, 135:513-518.
44. [44]
  N R Chiou, C Lui, J Guan et al. Nat. Nanotechnol., 2007, 2(6):354-357.
45. [45]
  J Xu, K Wang, S Z Zu et al. ACS Nano, 2010, 4(9):5019-5026.
46. [46]
  K Wang, W Zou, B Quan et al. Adv. Energy Mater., 2011, 1(6):1068-1072.
47. [47]
  K Wang, P Zhao, X Zhou et al. J. Mater. Chem., 2011, 21(41):16373-16378.
48. [48]
  K Wang, H Wu, Y Meng et al. Energy Environ. Sci., 2012, 5(8):8384-8389.
49. [49]
  Y Meng, K Wang, Y Zhang et al. Adv. Mater., 2013, 25(48):6985-6990.
50. [50]
  J Chen, C Jia, Z Wan. Synth. Met., 2014, 189:69-76.
51. [51]
  W S Hummers, R E Offeman. J. Am. Chem. Soc., 1958, 80:1339-1339.
52. [52]
  J Chen, C Jia, Z Wan. Electrochim. Acta, 2014, 121:49-56.
53. [53]
  Q Zhou, X Ye, Z Wan et al. J. Power Sources, 2015, 296:186-196.
54. [54]
  W Liu, C Lu, X Wang et al. ACS Nano, 2015, 9(2):1528-1542.
55. [55]
  X Cai, M Peng, X Yu et al. J. Mater. Chem. C, 2014, 2(7):1184-1200.
56. [56]
  L V Thong, H Kim, A Ghosh et al. ACS Nano, 2013, 7(7):5940-5947.
57. [57]
  D Yu, Q Qian, L Wei et al. Chem. Soc. Rev., 2015, 44(3):647-662.
58. [58]
  W Zeng, L Shu, Q Li et al. Adv. Mater., 2014, 26(31):5310-5336.
59. [59]
  J Bae, M K Song, Y J Park et al. Angew. Chem. Int. Ed., 2011, 50(7):1683-1687.
60. [60]
  S H Aboutalebi, R Jalili, D Esrafilzadeh et al. ACS Nano, 2014, 8(3):2456-2466.
61. [61]
  Y Meng, Y Zhao, C Hu et al. Adv. Mater., 2013, 25(16):2326-2331.
62. [62]
  M Miao. Carbon, 2011, 49:3755-3761.
63. [63]
  X Chen, L Qiu, J Ren et al. Adv. Mater., 2013, 25(44):6436-6441.
64. [64]
  Z Yang, J Deng, X Chen et al. Angew. Chem. Int. Ed., 2013, 52(50):13453-13457.
65. [65]
  J Ren, W Bai, G Guan et al. Adv. Mater., 2013, 25(41):5965-5970.
66. [66]
  Y Fu, X Cai, H Wu et al. Adv. Mater., 2012, 24(42):5713-5718.
67. [67]
  L Kou, T Huang, B Zheng et al. Nat. Commun., 2014, 5:3754.
68. [68]
  F Su, M Miao, H Niu et al. ACS Appl. Mater. Interf., 2014, 6(4):2553-2560.
69. [69]
  H Xu, X Hu, Y Sun et al. Nano Res., 2015, 8(4):1148-1158.
70. [70]
  D Harrison, F Qiu, J Fyson et al. Phys. Chem. Chem. Phys., 2013, 15(29):12215-12219.
71. [71]
  S T Senthilkumar, R K Selvan. Phys. Chem. Chem. Phys., 2014, 16(29):15692-15698.
72. [72]
  Y Li, K Sheng, W Yuan et al. Chem. Commun., 2013, 49(3):291-293.
73. [73]
  K Jost, D P Durkin, L M Haverhals et al. Adv. Energy Mater., 2015, 5:1401286.
74. [74]
  Z Yu, J Thomas. Adv. Mater., 2014, 26(25):4279-4285.
75. [75]
  H Xu, X Hu, Y Sun et al. Nano Res., 2014, 8(4):1148-1158.
76. [76]
  X Ye, Q Zhou, C Jia et al. Electrochim. Acta, 2016, 206:155-164.
77. [77]
  Q Zhou, C Jia, X Ye et al. J. Power Sources, 2016, 327:365-373.
78. [78]
  L Liu, Y Yu, C Yan et al. Nat. Commun., 2015, 6:7260.
79. [79]
  N Liu, W Ma, J Tao et al. Adv. Mater., 2013, 25(35):4925-4931.
80. [80]
  Y Gogotsi, P Simon. Science, 2011, 334(6058):917-918.
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