Citation: QIAO Wei-jun, ZHANG Kai-wen, ZHANG Na, ZHANG Lei, QING Shao-jun, GAO Zhi-xian. Study on CuAl₂O₄ catalytic material for methanol steam reforming[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(8): 980-985. shu

Study on CuAl₂O₄ catalytic material for methanol steam reforming

1.
Institute of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China
2.
Department of Chemical Engineering, Fushun Vocational Technology Institute, Fushun 113122, China
3.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Corresponding author: ZHANG Lei, lnpuzhanglei@163.com GAO Zhi-xian, gaozx@sxicc.ac.cn
Received Date: 9 July 2020
Revised Date: 28 July 2020

Fund Project: Scientific Research Funds project of Liaoning Education Department L2019038the National Natural Science Foundation of China 21376237the Natural Science Fund in Liaoning Province 2019-MS-221The project was supported by the National Natural Science Foundation of China (21376237), Scientific Research Funds project of Liaoning Education Department (L2019038), the Natural Science Fund in Liaoning Province (2019-MS-221)

Figures(5)

The CuAl₂O₄ catalytic material was in-situ synthesized using γ-Al₂O₃ as raw material. The catalytic material was characterized by XRF, XRD, BET and H₂-TPR. The effect of the copper-aluminum molar ratios on the structure and properties of CuAl₂O₄ spinel catalytic material and its performance in hydrogen production from methanol steam reforming were investigated. The results show that the copper-aluminum molar ratios affects reduction performance of copper species, which affects its performance in catalyzing methanol steam reforming to produce hydrogen. When the copper-aluminum molar ratios is 1:2, CuAl₂O₄ catalytic material has better catalytic performance. When the reaction temperature is 260℃, with a water-methanol molar ratio of 1.2 and methanol gas hourly space velocity of 800 h^-1, the methanol conversion reaches 100%, the hydrogen production rate is 895 mL/(kg·s).
- CuAl₂O₄,
- methanol steam reforming,
- hydrogen,
- in-situ synthesis
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Study on CuAl₂O₄ catalytic material for methanol steam reforming