Citation: YANG Gang-sheng, ZENG Gan-ning, ZHAO Qiang, CHEN Xu, CHEN Sheng-ji, AI Ning. Preparation of silica gel supported amino acid ionic liquids and their performance capacity towards carbon dioxide[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(1): 106-112. shu

Preparation of silica gel supported amino acid ionic liquids and their performance capacity towards carbon dioxide

YANG Gang-sheng ^1,2 ,
ZENG Gan-ning ³ ,
ZHAO Qiang ¹ ,
CHEN Xu ³ ,
CHEN Sheng-ji ¹ ,
AI Ning ^1,2,*,,

1.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
2.
Zhejiang Province Key Laboratory of Biofuel, Hangzhou 310014, China
3.
Ocean College, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: AI Ning, aining@zjut.edu.cn
Received Date: 24 July 2015
Revised Date: 29 September 2015

Fund Project: The project was supported by the Public Welfare Project of Science and Technology Department of Zhejiang Province 2013C33005

Figures(6)

Two amino acid ionic liquids (AAILs), viz., tetramethyl ammonium glycinate ([N₁₁₁₁][Gly]) and tetramethyl ammonium lysine ([N₁₁₁₁][Lys]) were supported on porous silica gel through impregnation evaporation method and used as the adsorbents for carbon dioxide. They were characterized by elemental analysis (EA), thermogravimetric analysis (TGA), nitrogen physisorption and Fourier transform infrared (FT-IR) spectroscopy; the effects of AAIL type, loading and temperature on their adsorption capacity towards carbon dioxide were investigated. The results illustrate that AAILs are successfully immobilized into the porous silica gel and the supported sorbents exhibit excellent performance towards carbon dioxide, i.e. fast adsorption rate and high capacity. At 303.15-323.15 K, the adsorption capacity reduces with the increase of temperature, whereas there is a optimal loading of ionic liquids to get highest adsorption capacity towards carbon dioxide. Under 30 ℃ and 0.1 MPa, the [N₁₁₁₁][Gly]/SG adsorbent with a [N₁₁₁₁][Gly] loading of 22.4% exhibits the highest CO₂ capture capacity, i.e. 41 mg/g, equivalent to 0.62 mol CO₂ per mol AAILs; moreover, 90% of the equilibrium adsorption amount can be achieved in 20 min. Furthermore, no obvious decrease in the adsorption capacity is observed after recycling for six times.
- amino acid ionic liquids,
- CO₂ capture,
- support,
- impregnation evaporation method
1. [1]
  GIANNOULAKIS S, VOLKART K, BAUER C. Life cycle and cost assessment of mineral carbonation for carbon capture and storage in European power generation[J]. Int J Greenhouse gas Control, 2014,21(2):140-157.
2. [2]
  FEI W Y, AI N, CHEN J. Capture and separation of greenhouse gases CO₂-the challenge and opportunity for separation technology[J]. Chem Ind Eng Prog, 2005,24(1):1-4.
3. [3]
  MACDOWELL N, FLORIN N, BUCHARD A, HALLETT J, GALINDO A, JACKSON G, ADJIMAN C S, WILLIAMS C K, SHAH N, FENNELL P. An overview of CO₂ capture technologies[J]. Energy Environ Sci, 2010,3(11):1645-1669. doi: 10.1039/c004106h
4. [4]
  HASIB-UR-RAHMAN M, SIAJ M, LARACHI F. Ionic liquids for CO₂ capture-Development and progress[J]. Chem Eng Prog, 2010,49(4):313-322. doi: 10.1016/j.cep.2010.03.008
5. [5]
  BLANCHARD L A, HANCU D, BECKMAN E J, BRENNECKE J F. Green processing using ionic liquid and CO₂[J]. Nature, 1999,399:28-29.
6. [6]
  BATES E D, MAYTON R D, NTAI I, DAVIS J H, J R. CO₂ capture by a task-specific ionic liquid[J]. J Am Chem Soc, 2002,124(6):926-927. doi: 10.1021/ja017593d
7. [7]
  WANG C M, LUO X Y, ZHU X, CUI G K, JIANG D E, DENG D S, LI H R, DAI S. The strategies for improving carbon dioxide chemisorption by functionalized ionic liquids[J]. RSC Adv, 2013,3(36):15518-15527. doi: 10.1039/c3ra42366b
8. [8]
  PENG H, ZHOU Y L, LIU J, ZHANG H B, XIA C L, ZHOU X H. Synthesis of novel amino-functionalized ionic liquids and their application in carbon dioxide capture[J]. RSC Adv, 2013,3(19):6859-6864. doi: 10.1039/c3ra23189e
9. [9]
  WANG X F, AKHMEDOV N G, DUAN Y H, LUEBKE D, LI B Y. Immobilization of amino acid ionic liquids into nanoporous microspheres as robust sorbents for CO₂ capture[J]. J Mater Chem A, 2013,1(9):2978-2982. doi: 10.1039/c3ta00768e
10. [10]
  WANG X F, AKHMEDOV N G, DUAN Y H, LUEBKE D, HOPKINSON D, LI B Y. Amino acid functionalized ionic liquid solid sorbents for post-combustion carbon capture[J]. ACS Appl Mater Interfaces, 2013,5(17):8670-8677. doi: 10.1021/am402306s
11. [11]
  JIANG B B, WANG X F, GRAY M L, DUAN Y H, LUEBKE D, LI B Y. Development of amino acid and amino acid-complex based solid sorbents for CO₂ capture[J]. Appl Energy, 2013,109(2):112-118.
12. [12]
  HANIOKA S, MARUYAMA T, SOTANI T, TERAMOTO M, MATSUYAMA H, NAKASHIMA K, HANAKI M, KUBOTA F, GOTO M. CO₂ separation facilitated by task-specific ionic liquids using a supported liquid membrane[J]. J Membrane Sci, 2008(1/2):1-4.
13. [13]
  ZHANG J M, ZHANG S J, DONG K, ZHANG Y Q, SHEN Y Q, LV X M. Supported absorption of CO₂ by tetrabutylphosphonium amino acid ionic liquids[J]. Chem Eur J, 2006,12(15):4021-4026. doi: 10.1002/(ISSN)1521-3765
14. [14]
  REN J, WU L B, LI B G. Preparation and CO₂ sorption/desorption of N-(3-aminopropyl) aminoethyl tributylphosphonium amino acid salt ionic liquids supported into porous silica particles[J]. Ind Eng Chem Res, 2012,51(23):7901-7909. doi: 10.1021/ie2028415
15. [15]
  CHEN Yi-feng, WANG Chang-song, DING Jian, YANG Zhu-hong, LU Xiao-hua. CO₂ absorption properties of supported[J]. CIESC J, 2014,65(5):1716-1720.
16. [16]
  YANG Na, WANG Rui. Preparation of supported amino-ionic liquid and its CO₂ adsorption capacity[J]. CIESC J, 2013,64(S1):128-132.
17. [17]
  XU X C, SONG C S, ANDRESEN J M, MILLER B G, SCARONI A W. Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for CO₂ capture[J]. Energy Fuels, 2002,16(6):1463-1469. doi: 10.1021/ef020058u
18. [18]
  LIU Zhi-lin, TENG Yang, ZHANG Kai, CAO Yan, PAN Wei-ping. CO₂ adsorption properties and thermal stability of different amine-impregnated MCM-41 materials[J]. J Fuel Chem Technol, 2013,41(4):469-475. doi: 10.1016/S1872-5813(13)60025-0
19. [19]
  CHEN Lin-lin, WANG Xia, GUO Qing-jie. Study on CO₂ adsorption properties of tetraethylenepentamine modified mesoporous silica gel[J]. J Fuel Chem Technol, 2015,43(1):108-115.
20. [20]
  JIANG Y Y, WANG G N, ZHOU Z, WU Y T, GENG J, ZHANG Z B. Tetraalkylammonium amino acids as functionalized ionic liquids of low viscosity[J]. Chem Commun, 2008,4(4):505-507.
21. [21]
  ZHANG Y Q, ZHANG S J, LU X M, ZHOU Q, FAN W, ZHANG X P. Dual amino-functionalised phosphonium ionic liquids for CO₂ capture[J]. Chem-Eur J, 2009,15(12):3003-3011. doi: 10.1002/chem.v15:12
22. [22]
  ZHANG F, FANG C G, WU Y T, WANG Y T, LI A M, ZHANG Z B. Absorption of CO₂ in the aqueous solutions of functionalized ionic liquids and MDEA[J]. Chem Eng J, 2010,160(2):691-697. doi: 10.1016/j.cej.2010.04.013
23. [23]
  HO N L, PORCHERON F, PELLENQ J M. Experimental and molecular simulation investigation of enhanced CO₂ solubility in hybrid adsorbents[J]. Langmuir, 2010,26(16):13287-13296. doi: 10.1021/la1015934
24. [24]
  GRAY M L, HOFFMAN J S, HREHA D C, FAUTH D J, HEDGES S W, CHAMPAGNE K J, PENNLINE H W. Parametric study of solid amine sorbents for the capture of carbon dioxide[J]. Energy Fuels, 2009,23(10):4840-4844. doi: 10.1021/ef9001204
25. [25]
  LEE J S, HILLESHEIM P C, HUANG D, LIVELY R P, OH K H, DAI S, KOROS W J. Hollow fiber-supported designer ionic liquid sponges for post-combustion CO₂ scrubbing[J]. Polymer, 2012,53(25):5806-5815. doi: 10.1016/j.polymer.2012.10.017
26. [26]
  ZHANG Hua-li, YAN Chun-jie, ZHOU Hong, CHEN Jie-yu, PAN Zhi-quan. Study on CO₂ adsorption of sepiolite modified by ionic-liquid[J]. Non-Met Mines, 2014,37(2):75-78.
27. [27]
  WANG X, AKHMEDOV N G, DUAN Y, LUEBKE D, HOPKINSON D, LI B. Amino acid functionalized ionic liquid solid sorbents for post-combustion carbon capture[J]. ACS Appl Mater Interfaces, 2013,5(17):8670-8677. doi: 10.1021/am402306s
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