Citation: Jing Chun CHEN, Gang ZHOU, Wei Dong LI, Yu Lin LI. Dienone-phenol Rearrangement of C-9 Oxygenated Decalinic Dienone and Analogs through B-Ring Cleavage[J]. Chinese Chemical Letters, ;2003, 14(7): 689-692. shu

Dienone-phenol Rearrangement of C-9 Oxygenated Decalinic Dienone and Analogs through B-Ring Cleavage

National Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000

Received Date: 27 August 2002

Fund Project: This work was financially supported by the National Natural Science Foundation of China (Grant No.20072012 and 20272021) and the Foundation for University Key Teacher by the Ministry of Education of China.

Dehydrogenation of 9-hydroxy decalinic enones and analogs with DDQ resulted in a formal dienone-phenol type rearrangement via B-ring cleavage, while the corresponding dienone acetates underwent base-catalyzed formal dienone-phenol type rearrangement analogously.
- Dienone-phenol rearrangement,
- decalinic dienone,
- dehydrogenation,
- DDQ
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