Citation: SHI Xun-wang, Xin XIN, LIU Zhao, LU Yao, LI Hong-xia, LI Jian-fen, CHEN Qun-peng. Preparation and characterization of Ni/TPC catalyst and applied in straw pyrolysis gas reforming[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(6): 659-665. shu

Preparation and characterization of Ni/TPC catalyst and applied in straw pyrolysis gas reforming

School of Chemical and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023, China

Corresponding author: LI Jian-fen, lijfen@163.com
Received Date: 6 March 2018
Revised Date: 18 April 2018

Fund Project: the Public Welfare Industry (agriculture) Research Special 201503135The project was supported by the Public Welfare Industry (agriculture) Research Special (201503135) and Technological Innovation Major Project of Hubei Province(2017ABA155)Technological Innovation Major Project of Hubei Province 2017ABA155

Figures(9)

Tire pyrolysis char (TPC) was used as a carrier to prepare Ni/TPC catalyst by homogeneous precipitation method. The characteristic of synthetic catalyst was determined by EDX, SEM, XRD, TG and BET. Meanwhile, the performance of Ni/TPC catalyst including reforming temperature, holding time, nickel loading and usage time on the straw pyrolysis gas reforming was investigated in a tube furnace. The results showed that TPC was rich in char and metal. Ni was well loaded on TPC which had a good thermal stability with a specific surface area of 62 m²/g. The Ni/TPC catalyst could obviously improve the burning gas content. The highest catalytic efficiency was obtained at reforming temperature of 750 ℃ and 10 min holding time with 30% Ni loading. The content of H₂ in the gas was high and relatively increased by 50% after using the catalyst for 850 min. The Ni₃ZnC_0.7 active component structure converted to FeNi₃ after long-term used with high and stable catalytic activity. TPC had the ability to be a new type of carrier for nickel catalyst.
- biomass pyrolysis,
- gas reforming,
- carrier,
- Ni catalyst,
- catalyst life
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