Citation: Wang Tingting, Song Yu, Zhang Minna, Zhang Heng. Preparation of Cesium Tungsten Bronze and Its Catalytic Property for Glycerol Dehydration to Acrolein[J]. Chemistry, ;2019, 82(11): 1008-1012. shu

Preparation of Cesium Tungsten Bronze and Its Catalytic Property for Glycerol Dehydration to Acrolein

School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165

Received Date: 18 May 2019
Accepted Date: 16 August 2019

Figures(6)

Cesium tungsten bronze was synthesized by a hydrothermal method with ammonium paratungstate and cesium nitrate as raw materials. Ethylenediamine tetraacetic acid (EDTA) was used as both template and reductant in this system. The effects of preparation conditions, such as amount of EDTA, concentration of the precursor, ratio of Cs to W, on the composition and morphology of the products were investigated. The as-synthesized products was applied as catalyst to the dehydration of glycerol to acrolein, and the content of Cs in the cesium tungsten bronze was found to have significant effect on the catalytic property. The product with Cs/W molar ratio of 0.2:1 showed better performance than the others, with a glycerol conversion of 81.3% and a high selectivity of 92.9% to acrolein.
- Tungsten bronze,
- Hydrothermal,
- Glycerol,
- Acrolein
1. [1]
  N Rahmat, A Z Abdullah, A R Mohamed. Renew. Sustain. Energy Rev., 2010, 14(3): 987~1000.
2. [2]
  Y Zheng, X Chen, Y Shen. Chem. Rev., 2008, 108(12): 5253~5277.
3. [3]
  C H Zhou, J N Beltramini, Y X Fan et al. Chem. Soc. Rev., 2008, 37(3): 527~549.
4. [4]
  M M Diallo, S Laforge, Y Pouilloux et al. Catal. Lett., 2018, 148(8): 2283~2303.
5. [5]
  J Shan, Z Li, S Zhu et al. Catalysts, 2019, 9(2): 121.
6. [6]
  J Ding, T Ma, M Cui et al. Mol. Catal., 2018, 461: 1~9.
7. [7]
  J Ding, T Ma, R Shao et al. New J. Chem., 2018, 42(17): 14271~14280.
8. [8]
  B Katryniok, R Melendez, V Belliere-Baca et al. Front. Chem., 2019, 7: 127.
9. [9]
  L Liu, X P Ye, B Katryniok et al. Front. Chem., 2019, 7: 108.
10. [10]
  Q Xie, S Li, R Gong et al. Appl. Catal. B, 2019, 243: 455~462.
11. [11]
  K A Lee, H Ryoo, B C Ma et al. J. Nanosci. Nanotechnol., 2018, 18 (2): 1312~1315.
12. [12]
  P Lauriol-Garbey, S Loridant, V Bellière-Baca et al. Catal. Commun., 2011, 16 (1): 170~174.
13. [13]
  M Dalil, D Carnevali, J L Dubois et al. Chem. Eng. J., 2015, 270: 557~563.
14. [14]
  L S Leonova, A V Levchenko, E I Moskvina et al. Russ. J. Electrochem., 2009, 45 (5): 593~601.
15. [15]
  K S Lee, D K Seo, M H Whangbo. J. Am. Chem. Soc., 1997, 119: 4043~4049.
16. [16]
  R Brusetti, P Haen, J Marcus. Phys. Rev. B, 2002, 65: 144528.
17. [17]
  C Hoang-Van, O Zegaoui. Appl. Catal. A, 1995, 130: 89~103.
18. [18]
  T J Thibodeau, A S Canney, W J Desisto et al. Appl. Catal. A, 2010, 388: 86~95.
19. [19]
  Y Liu, S Shrestha, W E Mustain. ACS Catal., 2012, 2: 456~463.
20. [20]
  P Botella, B Solsona, E García-González et al. Chem. Commun., 2007, 47: 5040~5042.
21. [21]
  C S Griffith, V Luca, J V Hanna et al. Inorg. Chem., 2009, 48(13): 5648~5662.
22. [22]
  V Luca, C S Griffith, J V Hanna. Inorg. Chem., 2009, 48(13): 5663~5676.
23. [23]
  G Li, C Guo, M Yan et al. Appl. Catal. B, 2016, 183: 142~148.
24. [24]
  S H Chai, H P Wang, Y Liang et al. Green Chem., 2007, 9(10): 1130~1136.
25. [25]
  E Tsukuda, S Sato, R Takahashi et al. Catal. Commun., 2007, 8(9): 1349~1353.
26. [26]
  A Corma, G W Huber, L Sauvanaud et al. J. Catal., 2008, 257(1): 163~171.
27. [27]
  W Suprun, M Lutecki, T Haber et al. J. Mol. Catal. A, 2009, 309(1~2): 71~78.
28. [28]
  A K Kinage, P P Upare, P Kasinathan et al. Catal. Commun., 2010, 11(7): 620~623.
29. [29]
  R Liu, T Wang, Y Jin. Catal. Today, 2014, 233: 127~132.
1. [1]
  Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
2. [2]
  Xin Feng , Kexin Guo , Chunguang Jia , Bowen Liu , Suqin Ci , Junxiang Chen , Zhenhai Wen . Hydrogen Generation Coupling with High-Selectivity Electrocatalytic Glycerol Valorization into Formate in an Acid-Alkali Dual-Electrolyte Flow Electrolyzer. Acta Physico-Chimica Sinica, 2024, 40(5): 2303050-0. doi: 10.3866/PKU.WHXB202303050
3. [3]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
4. [4]
  Zizheng LU , Wanyi SU , Qin SHI , Honghui PAN , Chuanqi ZHAO , Chengfeng HUANG , Jinguo PENG . Surface state behavior of W doped BiVO₄ photoanode for ciprofloxacin degradation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 591-600. doi: 10.11862/CJIC.20230225
5. [5]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-0. doi: 10.3866/PKU.WHXB202312010
6. [6]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
7. [7]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
8. [8]
  Yang ZHOU , Lili YAN , Wenjuan ZHANG , Pinhua RAO . Thermal regeneration of biogas residue biochar and the ammonia nitrogen adsorption properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1574-1588. doi: 10.11862/CJIC.20250032
9. [9]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
10. [10]
  Yuting Bai , Cenqi Yan , Zhen Li , Jiaqiang Qin , Pei Cheng . Preparation of High-Strength Polyimide Porous Films with Thermally Closed Pore Property by In Situ Pore Formation Method. Acta Physico-Chimica Sinica, 2024, 40(9): 2306010-0. doi: 10.3866/PKU.WHXB202306010
11. [11]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
12. [12]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
13. [13]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
14. [14]
  Yongqing Xu , Yuyao Yang , Mengna Wu , Xiaoxiao Yang , Xuan Bie , Shiyu Zhang , Qinghai Li , Yanguo Zhang , Chenwei Zhang , Robert E. Przekop , Bogna Sztorch , Dariusz Brzakalski , Hui Zhou . Review on Using Molybdenum Carbides for the Thermal Catalysis of CO₂ Hydrogenation to Produce High-Value-Added Chemicals and Fuels. Acta Physico-Chimica Sinica, 2024, 40(4): 2304003-0. doi: 10.3866/PKU.WHXB202304003
15. [15]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
16. [16]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 2408015-0. doi: 10.3866/PKU.WHXB202408015
17. [17]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
18. [18]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
19. [19]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
20. [20]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(831)
HTML views(105)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142