Citation: Li Fangji, Bian Yanjiang, Chen Zhixin, Tang Lijun, Zhong Keli, Hou Shuhua. A Isophthalic Dihydrazide-Based Fluorescent Probe for Relay Recognition of Al³⁺ and Pyrophosphate[J]. Chemistry, ;2019, 82(8): 743-748. shu

A Isophthalic Dihydrazide-Based Fluorescent Probe for Relay Recognition of Al³⁺ and Pyrophosphate

College of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121013

Corresponding author: Bian Yanjiang, bianyanjiang@126.com
Received Date: 24 February 2019
Accepted Date: 8 March 2019

Figures(14)

A simple and efficient fluorescent probe L was synthesized by using 2-hydroxy-1-naphthaldehyde and isophthalic dihydrazide as raw materials. Its structure were characterized by ¹H NMR, ¹³C NMR and HRMS. Probe L displays an highly selective recognition and a lower detection limit (5.924×10^-6mol/L) for Al³⁺ over other tested metal ions, which has a significant fluorescence enhancement in the mixed ETOH and water (1:1) system. This probe L has a binding ratio of 1:2. In addition, the L-2Al³⁺ showed highly selective sequential recognition of pyrophosphate ions (PPi) with good sensitivity. The detection limit of L-2Al³⁺ to PPi could reach 4.756×10^-5mol/L. The fluorescent probe has potential application value.
- 2-Hydroxy-1-naphthaldehyde,
- Isophthalic dihydrazide,
- Al³⁺,
- Pyrophosphate
1. [1]
  A Sahana, A Benerjee, S Lohar et al. Dalton Transac., 2013, 42:13311~13315.
2. [2]
  S Das, M Dutta, D Das et al. Anal. Methods, 2013, 5:6262~6268.
3. [3]
  H Xu, M Fang, C S Cao et al. Inorg. Chem., 2016, 55:4790~4795.
4. [4]
  D Wang, Y Ke, H Guo et al. Spectrochim. Acta, 2014, 122:268~274.
5. [5]
  Y J Jang, Y H Yeon, H Y Yang et al. Inorg. Chem. Commun., 2013, 33:48~52.
6. [6]
  N R Chereddy, M V N Raju, B M Reddy et al. Sens. Actuat., 2016, 237:605~610.
7. [7]
  S Das, M Dutta, D Das et al. Anal. Methods, 2013, 205:6262~6268.
8. [8]
  Z Li, Q Hu, C Li et al. Tetrahed. Lett., 2014, 55:1258~1263.
9. [9]
  G D Fasman. Coord. Chem. Rev., 1996, 149:125~130.
10. [10]
  P Nayak. Environ. Res., 2002, 89:101~107.
11. [11]
  A P de Silva, H Q N Gunaratne, T Gunnlaugsson et al. Chem. Rev., 1997, 97:1515~1519.
12. [12]
  B Valeur, I Leray. Coord. Chem. Rev., 2000, 205:3~12.
13. [13]
  N Lu, T Jiang, H Tan et al. Anal. Methods, 2017, 9:2689~2695.
14. [14]
  T H Ma, M Dong, Y M Dong et al. Chem. Eur. J., 2010, 16:10313~10318.
15. [15]
  C Caltagirone, C Bazzicalupi, F Isaia et al. Org. Biomol. Chem., 2013, 11:2445~2452.
16. [16]
  R G G Russell. Bone, 2011, 49:2~19.
17. [17]
  Z Liu, C Peng, Z Lu et al. Dyes Pigments, 2015, 123:85~92.
18. [18]
  T G Jo, K H Bok, J Han et al. Dyes Pigments, 2017, 139:136~147.
19. [19]
  H R Xu, K Li, S Y Jiao et al. Analyst, 2015, 140:4182~4187.
20. [20]
  D Maity, T Govindaraju. Eur. Inorg. Chem., 2011, 36:5479~5485.
21. [21]
  H Lei, H Diao, W Liu et al. RSC Adv., 2016, 6(81):77291~77297.
22. [22]
23. [23]
24. [24]
  C Kim, S Hwang, K Min et al. New J. Chem., 2017, 41:24~30.
25. [25]
  T G Jo, K H Bok, J Han et al. Dyes Pigments, 2017, 139:136~142.
26. [26]
  Y G Zhao, B G Zhang, C Y Duan et al. New J. Chem., 2006, 30:1207~1213
27. [27]
  Z Ekmekci. Tetrahed. Lett., 2015, 56:1878~1885.
28. [28]
  Y Zhang, Z Liu, Y Zhang et al. Sens. Actuat. B, 2015, 211:449~454.
29. [29]
  T Raj, P Saluja, N Singh et al. Sens. Actuat. B, 2015, 206:98~106.
30. [30]
  H Jing, Hu, J B Li et al. RSC Adv., 2017, 7:29697~26703.
1. [1]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054
2. [2]
  Xiaorui Chen , Xuan Luo , Tongming Su , Xinling Xie , Liuyun Chen , Yuejing Bin , Zuzeng Qin , Hongbing Ji . Ga-doped Cu/γ-Al₂O₃ bifunctional interface sites promote the direct hydrogenation of CO₂ to DME. Acta Physico-Chimica Sinica, 2025, 41(10): 100126-0. doi: 10.1016/j.actphy.2025.100126
3. [3]
  Yuanyu YANG , Jianhua XUE , Yujia BAI , Lulu CUI , Dongdong YANG , Qi MA . Design, synthesis, and detection of Al³⁺ of two zinc complexes based on Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1207-1216. doi: 10.11862/CJIC.20250005
4. [4]
  Yuanyuan Ping , Wangqing Kong . 光催化碳氢键官能团化合成1-苯基-1,2-乙二醇. University Chemistry, 2025, 40(6): 238-247. doi: 10.12461/PKU.DXHX202408092
5. [5]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
6. [6]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
7. [7]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
8. [8]
  Xiyuan Zhang , Rui Dong , Yang Yang , Jiapeng Ding , Zhiwei Miao . Palladium-Catalyzed Tandem Cyclization of 4-Vinylbenzoxazinone and Indene-2-carbaldehyde: A Comprehensive Organic Chemistry Experiment. University Chemistry, 2025, 40(9): 361-367. doi: 10.12461/PKU.DXHX202410062
9. [9]
  Haotian Zhang , Shengfa Feng , Mufan Cao , Xiong Xiong Liu , Pengcheng Yuan , Yaping Wang , Min Gao , Long Pan , Zhengming Sun . Al₂O₃ coated polyimide porous films enable thin yet strong polymer-in-salt solid-state electrolytes for dendrite-free lithium metal batteries. Chinese Chemical Letters, 2025, 36(8): 111096-. doi: 10.1016/j.cclet.2025.111096
10. [10]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 2309027-0. doi: 10.3866/PKU.WHXB202309027
11. [11]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
12. [12]
  Xiaofei Liu , He Wang , Li Tao , Weimin Ren , Xiaobing Lu , Wenzhen Zhang . Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide. Acta Physico-Chimica Sinica, 2024, 40(9): 2307008-0. doi: 10.3866/PKU.WHXB202307008
13. [13]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
14. [14]
  Rong-Nan Yi , Wei-Min He . Photocatalytic Minisci-type multicomponent reaction for the synthesis of 1-(halo)alkyl-3-heteroaryl bicyclo[1.1.1]pentanes. Chinese Chemical Letters, 2024, 35(10): 110115-. doi: 10.1016/j.cclet.2024.110115
15. [15]
  Tao Cao , Fang Fang , Nianguang Li , Yinan Zhang , Qichen Zhan . Green Synthesis of p-Hydroxybenzonitrile Catalyzed by Spinach Extracts under Red-Light Irradiation: Research and Exploration of Innovative Experiments for Pharmacy Undergraduates. University Chemistry, 2024, 39(5): 63-69. doi: 10.3866/PKU.DXHX202309098
16. [16]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
17. [17]
  Xiaoyang Li , Xiaowei Huang , Yimeng Zhang , Huan Liu , Shao Jin , Junpeng Zhuang . Comprehensive Chemical Experiments on the Synthesis of 1,3-Dibromo-5,5-Dimethylhydantoin and Its Application as a Brominating Reagent. University Chemistry, 2025, 40(7): 286-293. doi: 10.12461/PKU.DXHX202408035
18. [18]
  Lirui Shen , Kun Liu , Ying Yang , Dongwan Li , Wengui Chang . Synthesis and Application of Decanedioic Acid-N-Hydroxysuccinimide Ester: Exploration of Teaching Reform in Comprehensive Applied Chemistry Experiment. University Chemistry, 2024, 39(8): 212-220. doi: 10.3866/PKU.DXHX202312035
19. [19]
  Jianding LI , Junyang FENG , Huimin REN , Gang LI . Proton conductive properties of a Hf(Ⅳ)-based metal-organic framework built by 2,5-dibromophenyl-4,6-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1094-1100. doi: 10.11862/CJIC.20240464
20. [20]
  Yuan GAO , Yiming LIU , Chunhui WANG , Zhe HAN , Chaoyue FAN , Jie QIU . A hexanuclear cerium oxo cluster stabilized by furoate: Synthesis, structure, and remarkable ability to scavenge hydroxyl radicals. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 491-498. doi: 10.11862/CJIC.20240271

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(573)
HTML views(126)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A Isophthalic Dihydrazide-Based Fluorescent Probe for Relay Recognition of Al3+ and Pyrophosphate

Metrics

通讯作者: 陈斌, bchen63@163.com

A Isophthalic Dihydrazide-Based Fluorescent Probe for Relay Recognition of Al³⁺ and Pyrophosphate