Citation: CHEN Wu-hua, WANG Ye-fei, HE Zhen-pei, DING Ming-chen. Stability, rheology and displacement performance of nano-SiO₂/HPAM/NaCl dispersion systems[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(5): 568-576. shu

Stability, rheology and displacement performance of nano-SiO₂/HPAM/NaCl dispersion systems

CHEN Wu-hua ^1,2,, ,
WANG Ye-fei ^1,2 ,
HE Zhen-pei ^1,2 ,
DING Ming-chen ^1,2

1.
Key Laboratory of Unconventional Oil & Gas Development, China University of Petroleum(East China), Qingdao 266580, China
2.
Shandong Key Laboratory of Oilfield Chemistry, School of Petroleum Engineering, China University of Petroleum(East China), Qingdao 266580, China

Corresponding author: CHEN Wu-hua, cwh8157@163.com
Received Date: 6 January 2020
Revised Date: 6 April 2020

Fund Project: the National Science and Technology Major Project of China 2016ZX05058-003-003The project was support by the National Science and Technology Major Project of China (2016ZX05058-003-003)

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The stability, rheological properties and oil/water interfacial tension of Nano-SiO₂/HPAM/NaCl systems at 60 ℃ were studied by Zetasizer, rheometer and spin-drop method, respectively. The results indicated that the zeta potential value of nano-SiO₂ became more negative and the particle size was significantly increased with addition of HPAM. Meanwhile, there was no obvious turbidity phenomenon after 10 d. The nano-SiO₂/HPAM suspensions had higher viscosity and the viscosity retention was improved in the presence of salt at high temperature and shear rate as compared to HPAM solution. In this work, the nano-SiO₂ threshold for 0.18%(mass ratio) HPAM solution was 0.5% (mass ratio). When the mass ratio of nano-SiO₂ was less than 0.5%, the viscosity, storage modulus, loss modulus and creeping recovery properties were enhanced as well as the critical strain was decreased with the increase of nano-SiO₂ mass fraction. However, the opposite phenomenon was investigated when the mass ratio of nano-SiO₂ was more than 0.5%. The reason for this result was that the polymer amounts, polymer conformation onto the nano-SiO₂ surface and the network structure between nano-SiO₂ and HPAM were different when the nano-SiO₂ mass fraction was different. Oil/water interfacial tension values of nano-SiO₂/HPAM suspensions were lower than that of HPAM solution, and thus with addition of 0.2% and 0.5% (mass ratio) nano-SiO₂, the nano-SiO₂/HPAM suspensions had ultimate oil recoveries of 4.5% and 6.0% higher than polymer flooding.
- nano-SiO₂,
- HPAM,
- viscoelasticity,
- stability,
- enhanced oil recovery
1. [1]
  WANG J, DONG M. Optimum effective viscosity of polymer solution for improving heavy oil recovery[J]. J Pet Sci Eng, 2009,67(3):155-158.
2. [2]
  LI Mei-rong, LIU Zhi, SONG Xin-wang, MA Bao-dong, ZHANG Wen. Effect of metal ions on the viscosity of polyacrylamide solution and the mechanism of viscosity degradation[J]. J Fuel Chem Technol, 2012,40(1):43-47. doi: 10.3969/j.issn.0253-2409.2012.01.007
3. [3]
  PEI H H, ZHANG G C, GE J J, ZHANG L, WANG H. Effect of polymer on the interaction of alkali with heavy oil and its use in improving oil recovery[J]. Colloid Surface A, 2014,446(5):57-64.
4. [4]
  LI Mei-rong, HUANG Man, QU Cai-xia, CAO Xu-long, ZHANG Ji-chao, LIU Kun. Effect of shear action on the microcosmic structure and performance of functional polymer used in oil displacement[J]. J Fuel Chem Technol, 2013,41(4):449-455. doi: 10.3969/j.issn.0253-2409.2013.04.010
5. [5]
  CORREDOR R L M, SARAPARDEH A H, HUSEIN M M, DONG P M. Rheological behavior of surface modified silica nanoparticles dispersed in partially hydrolyzed polyacrylamide and xanthan gum solutions:Experimental measurements, mechanistic understanding, and model development[J]. Energy Fuels, 2018,32(10):10628-10638. doi: 10.1021/acs.energyfuels.8b02658
6. [6]
  CAO J, SONG T, WANG X J, ZHU Y J, WANG S S, ZHAO M T, MIAO Y J, ZHANG J. Studies on the rheological properties of amphiphilic nanosilica and a partially hydrolyzed polyacrylamide hybrid for enhanced oil recovery[J]. Chem Eng Sci, 2019,206:146-155. doi: 10.1016/j.ces.2019.05.034
7. [7]
  ZHENG Chao. Preparation of surface modified nanosilica and its impact on enhanced oil recovery of HPAM solution[D]. Kaifeng: Henan University, 2017.
8. [8]
  QIN Xiao-ping. The feasible research of improving sweep efficiency using the modified nano-SiO₂/AA/AM copolymer[D]. Chengdu: Southwest Petroleum University, 2014.
9. [9]
  MOHAMMED B A, KOUROSH R, RADZUAN J, ALI E B. Appraising the impact of metal-oxide nanoparticles on rheological properties of HPAM in different electrolyte solutions for enhanced oil recovery[J]. J Pet Sci Eng, 2019,172:1057-1068. doi: 10.1016/j.petrol.2018.09.013
10. [10]
  KANG W L, CAO C X, GUO S J, TANG X C, ZEESHAN A L, GAO Y B, ZHANG X F, MUHAMMAD W I, YANG H B. Mechanism of silica nanoparticles better-thickening effect on amphiphilic polymers in high salinity condition[J]. J Mol Liq, 2019,277:254-260. doi: 10.1016/j.molliq.2018.12.092
11. [11]
  NEETISH K M, AJAY M. Studies on behavior of suspension of silica nanoparticle in aqueous polyacrylamide solution for application in enhanced oil recovery[J]. Pet Sci Technol, 2016,34(5):429-436. doi: 10.1080/10916466.2016.1145693
12. [12]
  MAGHZI A, KHARRAT R, MOHEBBI A, GHAZANFARI M H. The impact of silica nanoparticles on the performance of polymer solution in presence of salts in polymer flooding for heavy oil recovery[J]. Fuel, 2014,123:123-132. doi: 10.1016/j.fuel.2014.01.017
13. [13]
  KHALILINEZHAD S S, CHERAGHIAN G, ROAYAEI E, TABATABAEE H, KARAMBEIGI M S. Improving heavy oil recovery in the polymer flooding process by utilizing hydrophilic silica nanoparticles[J]. Energy Sources Part A, 2017,12:1-10. doi: 10.1080/15567249.2014.881931
14. [14]
  SAEED J D S, LESLEY A J, ZHANG , Y H. Insight into the stability of hydrophilic silica nanoparticles in seawater for Enhanced oil recovery implications[J]. Fuel, 2018,216:559-571. doi: 10.1016/j.fuel.2017.11.091
15. [15]
  METIN C O, LAKEA L W, MIRANDA C R, NGUYEN Q P. Stability of aqueous silica nanoparticle dispersions[J]. J Nanopart Res, 2010,13(2):839-850. doi: 10.1007/s11051-010-0085-1
16. [16]
  WANG Ting. pH-induced self-assembly of HPAM and HPAM/HEC in aqueous solution[D]. Wuxi: Jiangnan University, 2009.
17. [17]
  LIN Di. Adsorption and aggregation mechanisms between bacterial extracellular polymeric substrances and soil minerals and nanoparticles[D]. Wuhan: Huazhong Agricultural University, 2018.
18. [18]
  GIRALDO L J, GIRALDO M A, LLANOS S, MAYA G, ZABALA R D, NASSAR N N, FRANCO C A, ALVARADO V, CORTES F B. The effects of SiO₂ nanoparticles on the thermal stability and rheological behavior of hydrolyzed polyacrylamide based polymeric solutions[J]. J Pet Sci Eng, 2017,159:841-852. doi: 10.1016/j.petrol.2017.10.009
19. [19]
  BARANY S. Polymer adsorption and electrokinetic potential of dispersed particles in weak and strong electric fields[J]. Adv Colloid Interface, 2015,222:58-69. doi: 10.1016/j.cis.2014.09.009
20. [20]
  LIU FU Sheng-cong, XIAO Han-ning, LI Yu-ping. Adsorption behavior of poly(acrylic acid) on the surface of nanoparticulate titanium dioxide[J]. Chem J Chin Univ, 2005,26(4):742-746. doi: 10.3321/j.issn:0251-0790.2005.04.028
21. [21]
  GREGORY J, BARANY S. Adsorption and flocculation by polymers and polymer mixtures[J]. Adv Colloid Interface Sci, 2011,169(1):1-12. doi: 10.1016/j.cis.2011.06.004
22. [22]
  SUN Xiu-zhi. Study on shearing stability of HPAM solution in flooding[D]. Qingdao: China University of Petroleum(East China), 2009.
23. [23]
  CHEN W H, CHEN J. Crystallization behaviors of biodiesel in relation to its rheological properties[J]. Fuel, 2016,171:178-185. doi: 10.1016/j.fuel.2015.12.049
24. [24]
  PU Wan-fen, PENG Cai-zhen, YANG Qing-yan, WU Xiao-ling, HUANG Ai-bin. Effect of creeping reversion of polymer solution in porous medium on the displacement efficiency[J]. J Southwest Pet Inst, 2000,22(2):62-67. doi: 10.3863/j.issn.1674-5086.2000.02.019
25. [25]
  BINKS B P, RODRIGUES J A, FRITH W J. Synergistic interaction in emulsions stabilized by a mixture of silica nanoparticles and cationic surfactant[J]. Langmuir, 2007,23(14):3626-3636.
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Stability, rheology and displacement performance of nano-SiO2/HPAM/NaCl dispersion systems

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通讯作者: 陈斌, bchen63@163.com

Stability, rheology and displacement performance of nano-SiO₂/HPAM/NaCl dispersion systems