Citation: Chang Wen HU, Qing Lin HE, Yong Hua ZHANG, Tian Di TANG, En Bo WANG. STUDY ON SYNTHESIS,CHARACTERIZATION AND CATALYSIS OF PILLARED ANION CLAY(Ⅲ)——SYNTHESIS OF ZnAl-BW₁₁O₃₉Z(H₂O)^n-[J]. Chinese Chemical Letters, ;1995, 6(7): 609-612. shu

STUDY ON SYNTHESIS,CHARACTERIZATION AND CATALYSIS OF PILLARED ANION CLAY(Ⅲ)——SYNTHESIS OF ZnAl-BW₁₁O₃₉Z(H₂O)^n-

Department of Chemistry, Northeast University, Changchun 130024

Received Date: 14 November 1994

Fund Project: Thanks for the support of Foundation of CEC and the open lab of Hydrothermal Synthesis in Jilin University.

ZnAl hydrotalcites have been intercalated by THPOMs[BW₁₁O₃₉Z(H₂O)^n-(Z=Ni²⁺, Cu²⁺ and Al³⁺)] via both hydrothermal reaction and ion exchange reaction.The spectra of powder X-ray diffraction and IR show that the synthesized complexes pillared by THPOMs are layered compounds with gallery heights of 9.7~9.9Å, The anions entering the layer retain their Keggin structure.
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