Citation: SUN Zhao-lin, HUI Yu, YANG Ye, QIN Yu-cai, ZHANG Li, ZHANG Le, JIA Wei-ming, ZU Yun, SONG Li-juan. Mechanism and effects of cerium content on the nickel olerance of CeUSY zeolite[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(7): 856-863. shu

Mechanism and effects of cerium content on the nickel olerance of CeUSY zeolite

SUN Zhao-lin ^1,2 ,
HUI Yu ¹ ,
YANG Ye ¹ ,
QIN Yu-cai ¹ ,
ZHANG Li ³ ,
ZHANG Le ² ,
JIA Wei-ming ¹ ,
ZU Yun ² ,
SONG Li-juan ^1,2,,

1.
Key Laboratory of Petrochemical Catalytic Science and Technology, Liaoning ShiHua University, Fushun 113001, China
2.
College of Chemistry and Chemical Engineering, China University of Petroleum(East China), Qingdao 266555, China
3.
Lanzhou Petrochemical Research Center, Petrochemical Research Institute, Petro China Company Limited, Lanzhou 730060, China

Corresponding author: SONG Li-juan, lsong56@263.net
Received Date: 24 February 2018
Revised Date: 23 May 2018

Fund Project: the National Natural Science Foundation of China 21376114The project was supported by the National Natural Science Foundation of China (U1662135, 21376114)the National Natural Science Foundation of China U1662135

Figures(5)

The CeUSY zeolites loaded with Ce were prepared by liquid phase ion exchange method, and the Ni contamination was conducted by Mitchell impregnation method. The texture properties were characterized by inductively coupled plasma atomic emission spectrometry (ICP-AES), X-ray diffraction (XRD) and N₂ adsorption. Moreover, the nickel tolerance was evaluated by the MAT evaluation device. The results show that CeUSY zeolites with different Ce contents possess a nickel tolerance performance varying in a volcano type with the increase of Ce content. Through the H₂-TPR and Py-FTIR characterization of CeUSY zeolite before and after Ni contamination, it is evident that the change in Ce species morphology is one of the reasons affecting nickel tolerances. It is thought that the interaction between Ce(OH)²⁺ and Ni(OH)⁺ in the SOD cages of the CeUSY zeolite results in a loss of H₂O molecule to form a stable Ce³⁺-O-Ni²⁺ structure at high temperature, which hinders the combination of Ni species with the framework aluminum to prevent the destruction of the Brønsted acid sites in CeUSY zeolite and effectively inhibits the formation of reducible NiO species. However, with the increase of the content of Ce³⁺, the part of the introduced Ce would happen to self-assemble in the zeolites as multinuclear hydroxylated species which interacts weakly with Ni²⁺ species compared to mononuclear species and then reduces the nickel tolerance.
- rare earth,
- location,
- morphology,
- USY,
- nickel tolerance
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沈阳化工大学材料科学与工程学院沈阳 110142

Mechanism and effects of cerium content on the nickel olerance of CeUSY zeolite

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com