Citation: WEI Xiao-li, SUN Tian-jun, KE Quan-li, LIU Xiao-wei, WANG Shu-dong. Adsorptive separation properties of CO₂/CH₄/N₂ on UZM-9 synthesized by seed-assisted method[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(7): 863-870. shu

Adsorptive separation properties of CO₂/CH₄/N₂ on UZM-9 synthesized by seed-assisted method

WEI Xiao-li ^1,2 ,
SUN Tian-jun ¹ ,
KE Quan-li ^1,2 ,
LIU Xiao-wei ^1,2 ,
WANG Shu-dong ^1,*,,

1.
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: WANG Shu-dong, wangsd@dicp.ac.cn; suntianjun@dicp.ac.cn
Received Date: 30 March 2017
Revised Date: 5 May 2017

Fund Project: the National Natural Science Foundation of China 21476231

Figures(7)

The UZM-9 zeolite was synthesized in 48 h via a seed-assisted method, in which TEAOH and TMAOH were used as organic structure directing agent (OSDA) while acid-treated UZM-9 zeolites were employed as seeds. The textural properties and hydrophobicity of the as synthesized UZM-9 zeolites and their adsorption properties for CO₂/CH₄/N₂ were characterized by XRD, physical adsorption, SEM, ICP and TG, respectively. The results show that UZM-9 zeolites can be obtained in 2 d with the Si/Al atomic ratio up to 3 and the yield up to 65%. At 298 K and 1atm, the capacity and adsorption heat of CO₂ are 5 mmol/g and 34 kJ/mol, and the selectivity of CO₂/CH₄, CO₂/N₂ and CH₄/N₂ are 100, 240 and 2.4 respectively. These results reveal that the as synthesized UZM-9 zeolites have good performances for carbon capture and possess considerable water resistance.
- acid-treated seed,
- UZM-9,
- adsorptive separation properties,
- CO₂,
- adsorption heat
1. [1]
  TAGLIABUE M, FARRUSSENG D, VALENCIA S, AGUADO S, RAVON U, RIZZO C, CORMA A, MIRODATOS C. Natural gas treating by selective adsorption:Material science and chemical engineering interplay[J]. Chem Eng J, 2009,155(3):553-566. doi: 10.1016/j.cej.2009.09.010
2. [2]
  BAO Z B, YU L, REN Q, LU X Y, DENG S G. Adsorption of CO₂ and CH₄ on a magnesium-based metal organic framework[J]. J Colloid Interface Sci, 2011,353(2):549-556. doi: 10.1016/j.jcis.2010.09.065
3. [3]
  RUFFORD T E, SMART S, WATSON G C Y, GRAHAM B F, BOXALL J, DINIZ DA COSTA J C, MAY E F. The removal of CO₂ and N₂ from natural gas:A review of conventional and emerging process technologies[J]. J Pet Sci Eng, 2012,94:123-154.
4. [4]
  CHEN Zhao-yuan, Gas Deep Cooling Method[M]. Beijing:Chemical Industry Press, 2005.
5. [5]
  WANG Xue-song. Membrane Technology[M]. Beijng:Chemical Industry Press, 2010.
6. [6]
  FAN Shuan-shi, CHENG Hong-yuan, CHEN Guang-jin. Separation technique based on gas hydrate formation[J]. Mod Chem Ind, 1999,19(2):11-12.
7. [7]
  LV Bi-hong, JIN Jia-jia, ZHANG Li, LI Wei. A systematic review of CO₂ adsorption using amine[J]. Petrochem Technol, 2011,40(8):803-809.
8. [8]
  WANG Hong-mei, LUO Shi-zhong, WU Yong-yong, SUN Si, LI Tong. Study on modified silica gels and their adsorption properties for CO₂/CH₄ mixed gas separation[J]. Nat Gas Chem Ind:C1, 2012,37(5):1-5.
9. [9]
  ROCHA L A M, ANDREASSEN K A, GRANDE C A. Separation of CO₂/CH₄ using carbon molecular sieve (CMS) at low and high pressure[J]. Chem Eng Sci, 2017,164:148-157. doi: 10.1016/j.ces.2017.01.071
10. [10]
  ZHANG Bo, GU Min, XIAN Xue-fu. Effects structure and surface property on adsorptive separation of carbon molecular sieve for CH₄/N₂ and CO₂/N₂[J]. J Funct Mater, 2012,43(20):2858-2862. doi: 10.3969/j.issn.1001-9731.2012.20.029
11. [11]
  HIMENO S, KOMATSU T, FUJITA S. High-pressure adsorption equilibria of methane and carbon dioxide on several activated carbons[J]. J Chem Eng Data, 2005,50(2):369-376. doi: 10.1021/je049786x
12. [12]
  PENG X, WANG W, XUE R, SHEN Z. Adsorption separation of CH₄/CO₂ on mesocarbon microbeads:experiment and modeling[J]. AIChE J, 2006,52(3):994-1003. doi: 10.1002/(ISSN)1547-5905
13. [13]
  BAI B C, CHO S, YU H R, YI K B, KIM K D, LEE Y S. Effects of aminated carbon molecular sieves on breakthrough curve behavior in CO₂/CH₄separation[J]. J Ind Eng Chem, 2013,19(3):776-783. doi: 10.1016/j.jiec.2012.10.016
14. [14]
  HAO S, ZHANG J, ZHONG Y, ZHU W. Selective adsorption of CO₂ on amino-functionalized silica spheres with centrosymmetric radial mesopores and high amino loading[J]. Adsorpt, 2012,18(5/6):423-430.
15. [15]
  SONGOLZADEH M, SOLEIMANIOl M, TAKHT R M, SONGOLZADEH R. Carbon dioxide separation from flue gases:a technological review emphasizing reduction in greenhouse gas emissions[J]. Sci World J, 2014828131.
16. [16]
  SUN T, REN X, HU J, WANG S. Expanding pore size of Al-BDC Metal-Organic Frameworks as a way to achieve high adsorption selectivity for CO_2/CH₄ sseparation[J]. J Phys Chem C, 2014,118(29):15630-15639. doi: 10.1021/jp411536d
17. [17]
  VENNA S R, CARREON M A. Highly permeable zeolite imidazolate framework-8 membranes for CO₂/CH₄ separation[J]. J Am Chem Soc, 2009,132(1):76-78.
18. [18]
  PALOMINO M, CORMA A, REY F, VALENCIA S. New insights on CO₂-methane separation using LTA zeolites with different Si/Al ratios and a first comparison with MOFs[J]. Langmuir, 2009,26(3):1910-1917.
19. [19]
  LIU B, SMIT B. Molecular simulation studies of separation of CO₂/N₂, CO₂/CH₄, and CH₄/N₂ by ZIFs[J]. J Phys Chem C, 2010,114(18):8515-8522. doi: 10.1021/jp101531m
20. [20]
  JAIME G M, GREGORY J L, JANA L G, MARK A M, LISA M R. Crystalline aluminosilicate zeolitic composition:UZM-9:US, 6713041 B1[P]. 2004-3-30.
21. [21]
  PARK M B, LEE Y, ZHENG A, XIAO F S, NICHOLAS C P, LEWIS G J, HONG S B. Formation pathway for lta zeolite crystals synthesized via a charge density mismatch approach[J]. J Am Chem Soc, 2012,135(6):2248-2255.
22. [22]
  KIM S H, PARK M B, MIN H K, HONG S B. Zeolite synthesis in the tetraethylammonium-tetramethylammonium mixed-organic additive system[J]. Microporous Mesoporous Mater, 2009,123(1):160-168.
23. [23]
  TOTH J. Thermodynamical model and prediction of gas/solid adsorption isotherms[J]. J Colloid Interface Sci, 2004,275(1):2-8. doi: 10.1016/j.jcis.2004.02.073
24. [24]
  PETER S A, SEBASTIAN J, JASRA R V. Adsorption of nitrogen, oxygen, and argon in mono-, di-, and trivalent cation-exchanged zeolite mordenite[J]. Ind Eng Chem Res, 2005,44(17):6856-6864. doi: 10.1021/ie050128v
25. [25]
  PHAM T D, LIU Q, LOBO R F. Carbon dioxide and nitrogen adsorption on cation-exchanged SSZ-13 zeolites[J]. Langmuir, 2012,29(2):832-839.
26. [26]
  DO D D. Adsorption Analysis:Equilibria and Kinetics[M]. London:Imperial CollegePress, 1998.
27. [27]
  International Zeolite Association, Structure Commission. http://www.iza-structure.org.
28. [28]
  ZUKAL A, AREAN C O, DELGADO M R, NACHTIGALL P, PULIDO A, MAYEROVÁ J, Ĉejka J. Combined volumetric, infrared spectroscopic and theoretical investigation of CO₂ adsorption on Na-A zeolite[J]. Microporous Mesoporous Mater, 2011,146(1):97-105.
29. [29]
  DUNNE J A, RAO M, SIRCAR S, GORTE R J, MYERS A L. Calorimetric heats of adsorption and adsorption isotherms. 2. O₂, N₂, Ar, CO₂, CH₄, C₂H₆, and SF₆ on NaX, H-ZSM-5, and Na-ZSM-5 zeolites[J]. Langmuir, 1996,12(24):5896-5904. doi: 10.1021/la960496r
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沈阳化工大学材料科学与工程学院沈阳 110142

Adsorptive separation properties of CO2/CH4/N2 on UZM-9 synthesized by seed-assisted method

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Adsorptive separation properties of CO₂/CH₄/N₂ on UZM-9 synthesized by seed-assisted method