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Citation: WEI Xiao-li, SUN Tian-jun, KE Quan-li, LIU Xiao-wei, WANG Shu-dong. Adsorptive separation properties of CO2/CH4/N2 on UZM-9 synthesized by seed-assisted method[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(7): 863-870. shu

Adsorptive separation properties of CO2/CH4/N2 on UZM-9 synthesized by seed-assisted method

  • 1.

    Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

  • 2.

    University of Chinese Academy of Sciences, Beijing 100049, China

  • Corresponding author: WANG Shu-dong, wangsd@dicp.ac.cn; suntianjun@dicp.ac.cn
  • Received Date: 30 March 2017
    Revised Date: 5 May 2017

    Fund Project: the National Natural Science Foundation of China 21476231

Figures(7)

  • The UZM-9 zeolite was synthesized in 48 h via a seed-assisted method, in which TEAOH and TMAOH were used as organic structure directing agent (OSDA) while acid-treated UZM-9 zeolites were employed as seeds. The textural properties and hydrophobicity of the as synthesized UZM-9 zeolites and their adsorption properties for CO2/CH4/N2 were characterized by XRD, physical adsorption, SEM, ICP and TG, respectively. The results show that UZM-9 zeolites can be obtained in 2 d with the Si/Al atomic ratio up to 3 and the yield up to 65%. At 298 K and 1atm, the capacity and adsorption heat of CO2 are 5 mmol/g and 34 kJ/mol, and the selectivity of CO2/CH4, CO2/N2 and CH4/N2 are 100, 240 and 2.4 respectively. These results reveal that the as synthesized UZM-9 zeolites have good performances for carbon capture and possess considerable water resistance.
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