Citation: Jin Xiaojuan, Zhang Yangyang, Zuo Chuan, Han Xu, Feng Yangyang, Gao Anli, Yu Juan, Liu Weiping. Syntheses and Catalytic Activities of Palladium Complexes of Organic Bidentate Phosphine Ferrocene[J]. Chemistry, ;2018, 81(2): 165-169. shu

Syntheses and Catalytic Activities of Palladium Complexes of Organic Bidentate Phosphine Ferrocene

Jin Xiaojuan ¹ ,
Zhang Yangyang ¹ ,
Zuo Chuan ² ,
Han Xu ¹ ,
Feng Yangyang ² ,
Gao Anli ¹ ,
Yu Juan ^1,, ,
Liu Weiping ¹

1.
State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106
2.
Sino-Platinum Metals Co. Ltd, Kunming 650106

Corresponding author: Yu Juan, juanyu1210@126.com
Received Date: 13 September 2017
Accepted Date: 16 October 2017

Four palladium(Ⅱ) complexes of organic bidentate phosphine ferrocene, [(dppf)PdCl₂], [(dtbpf)PdCl₂], [(dppf)PdBr₂], [(dtbpf)PdBr₂], were prepared via a direct reaction in an inert atmosphere using Na₂PdX₄ (X=Cl, Br) as the palladium precursor and the corresponding phosphine ferrocene as the ligand (dppf=1, 1'-bis(dipheny-phosphino)ferrocene, dtbpf=1, 1'-bis(di-tert-butylphosphino) ferrocene). The complexes were characterized by ¹H NMR. The catalytic performance of the complexes was evaluated not only in three well-kunown coupling reactions (Suzuki, Sonogashira and Heck coupling reaction) but also in the coupling reaction between 2-hydroxypyridine and boronic acid reagent. The results showed that the complexes are stable and can efficiently catalyze a series of coupling reactions in a non-protective atmosphere. The catalyst not only has high catalytic activity in unilateral Sonogashira coupling reaction, but also has good selectivity, showing a good application prospect.
- Organic bidentate phosphine ferrocene palladium complexes,
- Synthesis,
- Catalytic activity
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沈阳化工大学材料科学与工程学院沈阳 110142