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Citation: Tan Wenyuan, Chen Yuqin, Su Rui, Huang Kanghui, Wang Zhuqing. Preparation and Characterization of PVDF Hydrophilic Composite Membrane[J]. Chemistry, ;2020, 83(2): 156-160. shu

Preparation and Characterization of PVDF Hydrophilic Composite Membrane

1.
School of Chemical Engineering, Sichuan University of Science and Engineering, Zigong, 643000
2.
Petrochina Southwest Oil&Gasfield Company Dazhu Branch of Chongqing General Naturalgas Purification Plant, Chongqing, 404100
3.
Key Laboratories of Fine Chemicals and Surfactants in Sichuan Provincial Universities, Zigong, 643000

Received Date: 14 August 2019
Accepted Date: 2 November 2019

Figures(7)

The strong hydrophobicity of polyvinylidene fluoride (PVDF) membrane materials is its main drawback, and hydrophilization modification is the main way to solve this problem. The PVDF/PVA composite membrane was prepared by phase inversion method using PVDF as the base material, polyvinyl alcohol (PVA) as the blending material and N, N-dimethylacetamide (DMAc) as the solvent. The effects of blending ratio of PVDF/PVA, solid content, small molecule additives and polymer additives on the contact angle of the composite film were investigated. The results showed that when the PVDF/PVA blending ratio is 7/3 and the solid content is 13%, the contact angle of the prepared composite membrane is 22.92°; when the additive is anhydrous lithium chloride, nano-silica, and PVP, the contact angle of the composite film is reduced from 53.12°, 30.51° and 41.89° to 0°, respectively. The composite film has the best hydrophilicity when nano-silica is used as an additive. When the additive is glycerin, PMMA, PEG, the contact angle of the composite film increases, and the hydrophilicity deteriorates.
- PVDF membrane,
- PVA,
- Blending,
- Hydrophilicity,
- Modification
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
  Chen G, Xu S, Xu Z, et al. Polym. Eng. Sci., 2016, 56(8): 955~967.
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
  Li N, Xiao C, An S, et al. Desalination, 2010, 250(2): 530~537.
1. [1]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
2. [2]
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3. [3]
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5. [5]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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19. [19]
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20. [20]
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1.
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