Citation: Yu Jie, Wang Jingyun, Wang Zhen, Zhou Mingdong, Wang Haiyan. Hydrolysis of Cellulose Catalyzed by Composite Zeolite[J]. Chemistry, ;2018, 81(10): 944-950. shu

Hydrolysis of Cellulose Catalyzed by Composite Zeolite

Yu Jie ^1,2 ,
Wang Jingyun ² ,
Wang Zhen ² ,
Zhou Mingdong ^2,, ,
Wang Haiyan ^1,2,,

1.
College of Chemical Engineering, China University of Petroleum, Qingdao 266580
2.
School of Chemistry and Materials Science, Liaoning Shihua University, Fushun 113001

Corresponding author: Zhou Mingdong, mingdong.zhou@lnpu.edu.cn Wang Haiyan, haiyan.wang@lnpu.edu.cn
Received Date: 9 May 2018
Accepted Date: 12 June 2018

Figures(4)

HY/ZSM-5 composite zeolite was prepared by hydrothermal method and characterized by XRD, SEM, N₂-adsorption, NH₃-TPD and Py-FTIR. The results indicated that HY was completely encapsulated by HZSM-5 and formed a core-shell morphology of HY/ZSM-5 composite zeolite. Compared with the mechanical mixture, the composite zeolites show lower microporous surface area and microporous volume, higher quantity of total and strong acid sites, lower quantity of weak acid sites, the similar Br nsted acid amount and the reduced Lewis acid amount. Cellulose was hydrolyzed in 1-ethyl-3-methylimidazolium chloride ([Emim]Cl) using HY/ZSM-5 as catalyst. Compared with the hydrolysis of cellulose catalyzed by HY zeolite, the optimal glucose yield could be significantly improved from 28.04% to 38.78%, and the glucose selectivity improved from 28.91% to 48.29%.
- Composite zeolite,
- HY/ZSM-5,
- Cellulose,
- Hydrolysis,
- Glucose
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沈阳化工大学材料科学与工程学院沈阳 110142