Citation: Wang Linqing, Yang Dongxu, Wang Rui. The in-situ Magnesium Catalysts Generated by Mono-Active Hydrogen Containing Ligands and their Applications in Asymmetric Synthesis[J]. Chemistry, ;2020, 83(3): 209-217. shu

The in-situ Magnesium Catalysts Generated by Mono-Active Hydrogen Containing Ligands and their Applications in Asymmetric Synthesis

School of Basic Medical Sciences, Laboratory of Preclinical Study for New Drugs of Gansu Province, Lanzhou University, Lanzhou, 730000

Corresponding author: Yang Dongxu, yangdx@lzu.edu.cn
Received Date: 12 October 2019
Accepted Date: 23 November 2019

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This review summarized the recent works on in-situ generated magnesium catalysts, especially for the systematic induction and category of in-situ magnesium catalysts generated from mono-active hydrogen containing ligands. We try to introduce the design and development of chiral ligands with mono-nitrogen-hydrogen bond, mono-phenol and mono-alcohol, and the related applications in in-situ generated magnesium catalysts, for realizing multi-types of asymmetric catalyzed transformations and the ways of chemical bonds formation. Further exploration of the strategy of in-situ generated magnesium catalysis would be beneficial to study and expand more types of chemical transformations mediated by cheap and low pollution metal resources.
- In-situ magnesium catalysts,
- Asymmetric catalysis,
- Mono-active hydrogen containing ligands
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