Citation: Xiao Kang, Wang Xinxing, Wu Xiaofei, Qi Xingzhen, Su Haixia, Zhong Liangshu. Reductive Loading of Noble Metal Nanoparticles on Layered Double Hydroxide with Interlayer Anion as Reductant[J]. Chemistry, ;2018, 81(4): 332-338. shu

Reductive Loading of Noble Metal Nanoparticles on Layered Double Hydroxide with Interlayer Anion as Reductant

1.
School of Materials Science & Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023
2.
CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210
3.
SINOPEC Catalyst Beijing Co., Ltd., Beijing 102400

Corresponding author: Zhong Liangshu, zhongls@sari.ac.cn
Received Date: 25 December 2017
Accepted Date: 23 January 2018

Figures(6)

A facile method was developed for reductive loading of well-dispersed noble metal (Pd, Ag, Ru and Au) nanoparticles on layered double hydroxide (LDH). It involves the preparation of formate-LDH by coprecipitation and the subsequent in situ reduction of noble metal precursors by interlayer formate anion. Nanoparticles from both anionic (Au) and cationic (Pd, Ag, Ru) precursors could be loaded successfully, demonstrating the feasibility of this method. In addition, as an example, the obtained Pd/LDH shows a good activity for Suzuki cross-coupling reaction, suggesting potential catalytical application of prepared composites.
- Layered double hydroxide,
- Nanoparticles,
- In situ loading,
- Formate,
- Suzuki reaction
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沈阳化工大学材料科学与工程学院沈阳 110142