Citation: ZHANG Yu-bin, JING Jie-ying, LI Ting-yu, HUO Jun-mei, LI Wen-ying. Influence of preparation method on the structure of NiCo/MgO catalyst and its performance in the reforming of CH₄ with CO₂[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(7): 846-853. shu

Influence of preparation method on the structure of NiCo/MgO catalyst and its performance in the reforming of CH₄ with CO₂

Training Base of State Key Laboratory of Coal Science and Technology, Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province, . Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: JING Jie-ying, jingjieying@tyut.edu.cn LI Wen-ying, ying@tyut.edu.cn
Received Date: 8 April 2017
Revised Date: 18 May 2017

Fund Project: Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi 164010121-Sthe National Natural Science Foundation of China 21406155Shanxi Scholarship Council of China 2016-027the National Natural Science Foundation of China U1361202

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To enhance the performance of nickel-based catalysts in the reforming of CH₄ with CO₂ and alleviate the coke deposition, a series of NiCo/MgO catalysts were prepared by different methods, viz., deposition-precipitation (DP), co-precipitation method (CP) and co-impregnation (CI); the influence of preparation method on the structure and performance of NiCo/MgO catalyst was then investigated. The results show that during the deposition-precipitation process, CO(NH₂)₂ as the precipitant could created an alkaline atmosphere for the complete hydrolysis of Ni²⁺ and Co²⁺ ions, leading to a relatively fast nucleation and growth of active species; however, oversaturation may occur during the co-precipitation process with NaOH and Na₂CO₃ as the precipitants. In comparison with the catalysts prepared by CP and CI, the NiCo/MgO-DP catalyst is provided with superior reduction capacity, smaller particle size (9.7 nm), higher Ni/Co dispersion (10.4%) and larger specific surface area (68.1 m²/g) and then exhibits better resistance to coke deposition. Over the DP catalyst, the conversions of CH₄ and CO₂ at 800 ℃ reach 88% and 92%, respectively, much higher than those over the CP and CI catalysts; moreover, the DP catalyst also gives much higher yield of H₂ and CO as well as better stability for methane reforming with CO₂.
- methane reforming with CO₂,
- preparation method,
- Ni,
- Co,
- MgO,
- deposition-precipitation,
- co-precipitation method,
- co-impregnation
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Influence of preparation method on the structure of NiCo/MgO catalyst and its performance in the reforming of CH4 with CO2

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通讯作者: 陈斌, bchen63@163.com

Influence of preparation method on the structure of NiCo/MgO catalyst and its performance in the reforming of CH₄ with CO₂