Citation: Cui Hui, Tu Yan, Shang Yazhuo, Liu Honglai. Syntheses and Aggregation Behaviors of Ionic Liquid Surfactants 1-Butyl-3-methylimidazolium Alkyl Sulfate[J]. Chemistry, ;2017, 80(7): 672-678. shu

Syntheses and Aggregation Behaviors of Ionic Liquid Surfactants 1-Butyl-3-methylimidazolium Alkyl Sulfate

Key Laboratory for Advanced Materials, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237

Corresponding author: Shang Yazhuo, shangyazhuo@ecust.edu.cn
Received Date: 23 December 2016
Accepted Date: 6 February 2017

Figures(6)

Halogen-free alkyl sulfate-based surface active ionic liquids (SAILs), 1-butyl-3-methylimidazolium alkyl sulfate {[C₄mim] [C_nH_2n+1SO₄] (n=8, 12, 16)}, were synthesized through ion exchange reaction. The aggregation behaviors of synthesized SAILs in aqueous solution were investigated by surface tension, static fluorescence and static fluorescence quenching measurements. The results showed that the ionic liquid surfactants with organic imidazole cation ([C₄mim]⁺) as counter ions have higher surface activity compared to that surfactants with traditional inorganic counter ions. The effect of inhibiting molecular ordered arrangement derived from the existence of hydrogen bonding produced by [C₄mim]⁺ is less than the hydrophobic effect that can promote molecular ordered arrangement. The anions with long alkyl chains are the major components of interfacial film and micelles. The increase of anionic alkyl chain length promotes the formation of micelles but inhibits the participation of [C₄mim]⁺ to the formation of interface or micelles in some degree. The longer the anionic alkyl chain, the more unfavorable for the [C₄mim]⁺ to participate in the formation of interfacial film or micelles, which leads to the looser arrangement of surfactants in interfacial film or micelles. Correspondingly, the interfacial tension is higher and the micellar aggregation number is smaller.
- Ionic liquid surfactants,
- Surface active parameters,
- Aggregation behaviors,
- Micelle aggregation number
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