Citation: WANG Li-bao, WANG Dong-zhe, ZHANG Lei, QING Shao-jun, HAN Jiao, ZHANG Cai-shun, GAO Zhi-xian, ZHANG Hai-juan, FENG Xu-hao. Influence of cerium sources on CuO/CeO₂ catalysts for hydrogen production from steam reforming of methanol[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(7): 852-859. shu

Influence of cerium sources on CuO/CeO₂ catalysts for hydrogen production from steam reforming of methanol

1.
Petrochemical College, Liaoning Shihua University, Fushun 113001, China
2.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
3.
No.3 Refinery of Fushun Petrochemical Company, CNPC, Fushun 113001, China

Corresponding author: ZHANG Lei, lnpuzhanglei@163.com
Received Date: 15 June 2020
Revised Date: 8 July 2020

Fund Project: The project was supported by the National Natural Science Foundation of China (21376237), Scientific Research Funds Project of Liaoning Education Department (L2019038), the Project of the National Science Fund in Liaoning Province (2019-MS-221)the Project of the National Science Fund in Liaoning Province 2019-MS-221Scientific Research Funds Project of Liaoning Education Department L2019038the National Natural Science Foundation of China 21376237

Figures(9)

CeO₂ support was synthesized by precipitation method and used to prepare CuO/CeO₂ catalyst using impregnation method. The effects of cerium sources (Ce(NO₃)₃·6H₂O, CeCl₃·6H₂O, Ce(NH₄)₂(NO₃)₆ and Ce(SO₄)₂·4H₂O) on the catalytic performance of CuO/CeO₂ catalyst were investigated. XRD, SEM, N₂O titration, BET and H₂-TPR were used to study the structure and properties of the catalysts. The CuO/CeO₂ catalysts with different cerium sources have obvious differences in Cu specific surface area, reduction performance and interaction between active component and support. Moreover, CuO/CeO₂ catalyst prepared with Ce(NO₃)₃·6H₂O has large Cu specific surface area, low reduction temperature and strong interaction between CeO₂ support and CuO and shows better catalytic activity in methanol steam reforming. The methanol conversion is 100% at reaction temperature of 553 K, water/methanol ratio in feed of 1.2 and methanol water gas hourly space velocity of 1760 h^-1. Besides, the CO molar content in reformed gas is 0.84%.
- method of precipitation,
- cerium source,
- methanol steam reforming,
- hydrogen
1. [1]
  SU Shi-long, ZHANG Lei, ZHANG Yan, LEI Jun-teng, GUI Jian-zhou, LIU Dan, LIU Dao-sheng, PAN Li-wei. Thermodynamic simulation for hydrogen production in the methanol steam reforming system of kilowatt PEMFC[J]. J Petrochem Univ, 2015,28(2):19-25. doi: 10.3969/j.issn.1006-396X.2015.02.004
2. [2]
  YANG S C, SU W N, LIN S D, RICK J, HWANG B J. Preparation of highly dispersed catalytic Cu from rod-like CuO-CeO₂ mixed metal oxides:Suitable for applications in high performance methanol steam reforming[J]. Catal Sci Technol, 2012,2(4):807-812. doi: 10.1039/c2cy00330a
3. [3]
  HE J P, YANG Z X, ZHANG L, LI Y, PAN L W. Cu supported on ZnAl-LDHs precursor prepared by in-situ synthesis method onγ -Al₂O₃ as catalytic material with high catalytic activity for methanol steam reforming[J]. Int J Hydrogen Energy, 2017,42(15):9930-9937. doi: 10.1016/j.ijhydene.2017.01.229
4. [4]
  ZHANG L, PAN L W, NI C J, SUN T J, ZHAO S S, WANG S D, WANG A J, HU Y K. CeO₂-ZrO₂-promoted CuO/ZnO catalyst for methanol steam reforming[J]. Int J Hydrogen Energy, 2013,38(11):4397-4406. doi: 10.1016/j.ijhydene.2013.01.053
5. [5]
  LIU N, YUAN Z S, WANG C W, WANG S D, ZHANG C X, WANG S J. The role of CeO₂-ZrO₂ as support in the ZnO-ZnCr₂O₄ catalysts for autothermal reforming of methanol[J]. Fuel Process Technol, 2008,89(6):574-581. doi: 10.1016/j.fuproc.2007.11.029
6. [6]
  PATEL S, PANT K K. Selective production of hydrogen via oxidative steam reforming of methanol using Cu-Zn-Ce-Al oxide catalysts[J]. Chem Eng Sci, 2007,62(18/20):5436-5443.
7. [7]
  HAO C, ANDOLINA C M, LI J, CURNAN M T, SAIDI W A, ZHOU G W, YANG J C, VESER G. Dependence of H₂ and CO₂ selectivity on Cu oxidation state during partial oxidation of methanol on Cu/ZnO[J]. Appl Catal A:Gen, 2018,556:64-72. doi: 10.1016/j.apcata.2018.02.028
8. [8]
  MA Y F, GUAN G Q, PHANTHONG P, LI X M, CAO J, HAO X G, WANG Z D, ABUDULA A. Steam reforming of methanol for hydrogen production over nanostructured wire-like molybdenum carbide catalyst[J]. Int J Hydrogen Energy, 2014,39(33):18803-18811. doi: 10.1016/j.ijhydene.2014.09.062
9. [9]
  LI Yong-feng, LIN Wei-ming, YU Lin. Study on two hydrogen production catalysts for methanol steam reforming[J]. J Fuel Chem Technol, 2004,32(5):106-110.
10. [10]
  LIU Yu-juan, XU Ji, TONG Yu-fei, ZHANG Na, ZHANG Lei, LIU Dao-sheng, HAN Jiao, ZHANG Cai-shun. Progress in research of the synthesis methods of nanometer ceria[J]. J Liaoning Shihua Univ, 2017,37(5):8-12. doi: 10.3969/j.issn.1672-6952.2017.05.002
11. [11]
  LIU Y, HAYAKAWA T, TSUNODA T, SUZUKI K, HAMAKAWA S, MURATA K, NSHIOZAKI R, ISHII T, KUMAGAI M. Steam reforming of methanol over Cu/CeO₂ catalysts studied in comparison with Cu/ZnO and Cu/Zn(Al)O catalysts[J]. Top Catal, 2003,22(3/4):205-213. doi: 10.1023/A:1023519802373
12. [12]
  SUN C W, LI H, ZHANG H R, WANG Z X, CHEN L Q. Controlled synthesis of CeO₂ nanorods by a solvothermal method[J]. Nanotechnol, 2005,16(9):1454-1463. doi: 10.1088/0957-4484/16/9/006
13. [13]
  ZHANG C Y, CHU W, CHEN F, LI L, JIANG R Y, YAN J L. Effects of cerium precursors on surface properties of mesoporous CeMnO_x catalysts for toluene combustion[J]. J Rare Earths, 2019,38(1):70-75.
14. [14]
  LIU Yu-juan, WANG Dong-zhe, ZHANG Lei, WANG Hong-hao, CHEN Lin, LIU Dao-sheng, HAN Jiao, ZHANG Cai-shun. Effect of support calcination atmospheres on the activity of CuO/CeO₂ catalysts for methanol steam reforming[J]. J Fuel Chem Technol, 2018,46(8):992-999. doi: 10.3969/j.issn.0253-2409.2018.08.011
15. [15]
  YANG Shu-qian, HE Jian-ping, ZHANG Na, SUI Xiao-wei, ZHANG Lei, YANG Zhan-xu. Effect of rare-earth element modification on the performance of Cu/ZnAl catalysts derived from hydrotalcite precursor in methanol steam reforming[J]. J Fuel Chem Technol, 2018,46(2):179-188. doi: 10.3969/j.issn.0253-2409.2018.02.007
16. [16]
  YANG S Q, ZHOU F, LIU Y J, ZHANG L, CHEN Y, WANG H H, TIAN Y, ZHANG C S, LIU D S. Morphology effect of ceria on the performance of CuO/CeO₂ catalysts for hydrogen production by methanol steam reforming[J]. Int J Hydrogen Energy, 2019,44(14):7252-7261. doi: 10.1016/j.ijhydene.2019.01.254
17. [17]
  ZHANG Y J, CHEN C Q, ZHANG Y Y, LIN Q, LOU B Y, ZHENG G C, ZHENG Q. Highly active Y-promoted CuO/ZrO₂ catalysts for the production of hydrogen through water-gas shift reaction[J]. J Fuel Chem Technol, 2017,45(9):1137-1149.
18. [18]
  ZHANG Y J, CHEN C Q, LIN X Y, LI D L, CHEN X H, ZHAN Y Y, ZHENG Q. CuO/ZrO₂ catalysts for water-gas shift reaction:Nature of catalytically active copper species[J]. Int J Hydrogen Energy, 2014,39(8):3746-3754. doi: 10.1016/j.ijhydene.2013.12.161
19. [19]
  XIE H M, DU Q X, LI H, ZHOU G L, CHEN S M, JIAO Z J, REN J M. Catalytic combustion of volatile aromatic compounds over CuO-CeO₂ catalyst[J]. Korean J Chem Eng, 2017,34(7):1944-1951. doi: 10.1007/s11814-017-0111-4
20. [20]
  BERA P, PRIOLKAR K R, SARODE P R, HEGDE M S, EMURA S, KUMASHIRO R, LALLA N P. Structural investigation of combustion synthesized Cu/CeO₂ catalysts by EXAFS and other physical techniques:Formation of a Ce_1-x Cu_xO_2-δ solid solution[J]. Chem Mater, 2002,14(8):3591-3601. doi: 10.1021/cm0201706
21. [21]
  AVGOUROPOULOS G, IOANNIDES T, MATRALIS H. Influence of the preparation method on the performance of CuO-CeO₂ catalysts for the selective oxidation of CO[J]. Appl Catal B:Environ, 2005,56(1/2):87-93.
22. [22]
  LUO M F, ZHONG Y J, YUAN X X, ZHENG X M. TPR and TPD studies of CuO/CeO₂ catalysts for low temperature CO oxidation[J]. Appl Catal A:Gen, 1997,162(1):121-131.
23. [23]
  ZHANG Lei, PAN Li-wei, NI Chang-jun, SUN Tian-jun, ZHAO Sheng-sheng, WANG Shu-dong, HU Yong-kang, WANG An-jie. Effect of precipitation temperature on the performance of CuO/ZnO/CeO₂/ZrO₂ catalyst for methanol steam reforming[J]. Chin J Catal, 2012,33(12):1958-1964.
24. [24]
  LIU Yu-juan, WANG Dong-zhe, ZHANG Lei, BAI Jin, CHEN Lin, LIU Dao-sheng. Effect of CeO₂ morphology on CuO/CeO₂ catalyst for methanol steam reforming[J]. Fine Chem, 2018,35(12):71-77+112.
25. [25]
  ZHAO Hong-xia, LI Yong-hong, YANG Cheng, WANG Xiu-zhi, REN Jie, SUN Yu-han. Hydrogen production by steam reforming of methanol on Fe modified Cu/Zn/Al catalysts[J]. J Fuel Chem Technol, 2001,29:137-139. doi: 10.3969/j.issn.0253-2409.2001.z1.043
26. [26]
  WANG Lu-cun, LIU Yong-mei, CAO Yong, WU Gui-sheng, YAO Cheng-zhang, DAI Wei-lin, HE He-yong, FAN Kang-nian. Preparation of high performance by oxalate solid phase chemical Cu/ZnO methanol steam reforming catalyst[J]. Acta Chim Sin, 2007,65(2):173-176. doi: 10.3321/j.issn:0567-7351.2007.02.016
1. [1]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
2. [2]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
3. [3]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
4. [4]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
5. [5]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
6. [6]
  Tiejun Su . The Construction and Application of the Calculation Formula for Endpoint Error in Precipitation Titration: A Case Study of the Mohr Method. University Chemistry, 2024, 39(11): 384-387. doi: 10.12461/PKU.DXHX202402039
7. [7]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
8. [8]
  Lei Shu , Zhengqing Hao , Kai Yan , Hong Wang , Lihua Zhu , Fang Chen , Nan Wang . Development of a Double-Carbon Related Experiment: Preparation, Characterization and Carbon-Capture Ability of Eggshell-Derived CaO. University Chemistry, 2024, 39(4): 149-156. doi: 10.3866/PKU.DXHX202310134
9. [9]
  Yuan GAO , Yiming LIU , Chunhui WANG , Zhe HAN , Chaoyue FAN , Jie QIU . A hexanuclear cerium oxo cluster stabilized by furoate: Synthesis, structure, and remarkable ability to scavenge hydroxyl radicals. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 491-498. doi: 10.11862/CJIC.20240271
10. [10]
  Ming Li , Zhaoyin Li , Mengzhu Liu , Shaoxiang Luo . Unveiling the Artistry of Mordant Dyeing: The Coordination Chemistry Beneath. University Chemistry, 2024, 39(5): 258-265. doi: 10.3866/PKU.DXHX202311085
11. [11]
  Mei Yan , Rida Feng , Yerdos·Tohtarkhan , Biao Long , Li Zhou , Chongshen Guo . Expansion and Extension of Liquid Saturated Vapor Measurement Experiment. University Chemistry, 2024, 39(3): 294-301. doi: 10.3866/PKU.DXHX202308103
12. [12]
  Zhou Fang , Zhihao Zhang , Weihan Jiang , Kin Shing Chan . Warfarin: From Poison to Cure, the Remarkable Journey of a Molecule. University Chemistry, 2025, 40(4): 326-330. doi: 10.12461/PKU.DXHX202406038
13. [13]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042
14. [14]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
15. [15]
  Feng Liang , Desheng Li , Yuting Jiang , Jiaxin Dong , Dongcheng Liu , Xingcan Shen . Method Exploration and Instrument Innovation for the Experiment of Colloid ζ Potential Measurement by Electrophoresis. University Chemistry, 2024, 39(5): 345-353. doi: 10.3866/PKU.DXHX202312009
16. [16]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
17. [17]
  Yujia Luo , Yunpeng Qi , Huiping Xing , Yuhu Li . The Use of Viscosity Method for Predicting the Life Expectancy of Xuan Paper-based Heritage Objects. University Chemistry, 2024, 39(8): 290-294. doi: 10.3866/PKU.DXHX202401037
18. [18]
  Jiahao Lu , Xin Ming , Yingjun Liu , Yuanyuan Hao , Peijuan Zhang , Songhan Shi , Yi Mao , Yue Yu , Shengying Cai , Zhen Xu , Chao Gao . 基于稳态电热法的石墨烯膜导热系数的精确可靠测量. Acta Physico-Chimica Sinica, 2025, 41(5): 100045-. doi: 10.1016/j.actphy.2025.100045
19. [19]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
20. [20]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(694)
HTML views(110)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of cerium sources on CuO/CeO2 catalysts for hydrogen production from steam reforming of methanol

Metrics

通讯作者: 陈斌, bchen63@163.com

Influence of cerium sources on CuO/CeO₂ catalysts for hydrogen production from steam reforming of methanol