Citation: WANG Li-bao, WANG Dong-zhe, ZHANG Lei, QING Shao-jun, HAN Jiao, ZHANG Cai-shun, GAO Zhi-xian, ZHANG Hai-juan, FENG Xu-hao. Influence of cerium sources on CuO/CeO₂ catalysts for hydrogen production from steam reforming of methanol[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(7): 852-859. shu

Influence of cerium sources on CuO/CeO₂ catalysts for hydrogen production from steam reforming of methanol

1.
Petrochemical College, Liaoning Shihua University, Fushun 113001, China
2.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
3.
No.3 Refinery of Fushun Petrochemical Company, CNPC, Fushun 113001, China

Corresponding author: ZHANG Lei, lnpuzhanglei@163.com
Received Date: 15 June 2020
Revised Date: 8 July 2020

Fund Project: The project was supported by the National Natural Science Foundation of China (21376237), Scientific Research Funds Project of Liaoning Education Department (L2019038), the Project of the National Science Fund in Liaoning Province (2019-MS-221)the Project of the National Science Fund in Liaoning Province 2019-MS-221Scientific Research Funds Project of Liaoning Education Department L2019038the National Natural Science Foundation of China 21376237

Figures(9)

CeO₂ support was synthesized by precipitation method and used to prepare CuO/CeO₂ catalyst using impregnation method. The effects of cerium sources (Ce(NO₃)₃·6H₂O, CeCl₃·6H₂O, Ce(NH₄)₂(NO₃)₆ and Ce(SO₄)₂·4H₂O) on the catalytic performance of CuO/CeO₂ catalyst were investigated. XRD, SEM, N₂O titration, BET and H₂-TPR were used to study the structure and properties of the catalysts. The CuO/CeO₂ catalysts with different cerium sources have obvious differences in Cu specific surface area, reduction performance and interaction between active component and support. Moreover, CuO/CeO₂ catalyst prepared with Ce(NO₃)₃·6H₂O has large Cu specific surface area, low reduction temperature and strong interaction between CeO₂ support and CuO and shows better catalytic activity in methanol steam reforming. The methanol conversion is 100% at reaction temperature of 553 K, water/methanol ratio in feed of 1.2 and methanol water gas hourly space velocity of 1760 h^-1. Besides, the CO molar content in reformed gas is 0.84%.
- method of precipitation,
- cerium source,
- methanol steam reforming,
- hydrogen
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Influence of cerium sources on CuO/CeO2 catalysts for hydrogen production from steam reforming of methanol

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通讯作者: 陈斌, bchen63@163.com

Influence of cerium sources on CuO/CeO₂ catalysts for hydrogen production from steam reforming of methanol