Citation: WU Jiang-hong, XUE Wei, SU Li-hong, LI Jun-tian, WANG Hai-tang. Effect of treatment method on the performance of boron nitride supported iron catalysts in the Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(10): 1245-1250. shu

Effect of treatment method on the performance of boron nitride supported iron catalysts in the Fischer-Tropsch synthesis

1.
Shanxi Institute of Energy, Jinzhong 030600, China
2.
China Research Institute of Daily Chemical Co., Ltd, Taiyuan 030001, China

Corresponding author: WU Jiang-hong, wujianghong2006@126.com
Received Date: 16 May 2019
Revised Date: 19 August 2019

Fund Project: The project was supported by the Foundation of Shanxi Institute of Energy (ZB-2018001)the Foundation of Shanxi Institute of Energy ZB-2018001

Figures(4)

Three boron nitride (BN) supported iron catalysts were prepared by the incipient-wetness impregnation method and characterized by XRD, TEM, FT-IR, and H₂-TPR; their phase structure, morphology, reduction behavior and performance in the F-T synthesis were investigated. The results indicate that the addition of Cu promoter has little influence on the phase structure of BN support, whereas the addition of sodium borate can improve the crystallinity of BN support. Although the change in the catalyst morphology by introducing Cu and sodium borate is very small, the addition of Cu and sodium borate can decrease the reduction temperature of the BN-supported iron-based catalysts. For F-T synthesis under 340℃, 2 MPa, GHSV=1500 h^-1 and n(H₂)/n(CO)=2, the conversions of CO over Fe/BN, Fe/BNM and Fe-Cu/BN are 12.3%, 36.2% and 31.6%, respectively and the corresponding selectivities to CH₄ are 57.9%, 26.8% and 44.7%, respectively. Fe-Cu/BN and Fe/BNM exhibit higher activity than Fe/BN, suggesting that adding promoter and improving the interaction between support and active component can both enhance the activity of boron nitride supported iron catalysts in F-T synthesis, which may give a clue to the design of highly active BN-supported iron catalysts.
- boron nitride,
- iron-based catalysts,
- Fischer-Tropsch synthesis,
- treatment method
1. [1]
  ZHANG Xiang-fa, LIANG Hao, MENG Ming-qiang. Preparation of hexagonal boron nitride and its application in the establishment of hexagonal boron nitride[J]. Diamond Abrasives Eng, 2012,4(32):14-18.
2. [2]
  SUN W, MENG Y, FU Q, WANG F, WANG G, GAO W, HUANG X, LU F. High-yield production of boron nitride nanosheets and its uses as a catalyst support for hydrogenation of nitroaromatics[J]. ACS Appl Mater Interfaces, 2016,8(15):9881-9888. doi: 10.1021/acsami.6b01008
3. [3]
  GU Y, ZHENG M, LIU Y, XU Z. Low-temperature synthesis and growth of hexagonal boron-nitride in a lithium bromide melt[J]. J Am Ceram Soc, 2007,90(5):1589-1591. doi: 10.1111/j.1551-2916.2007.01551.x
4. [4]
  GAO R, YIN L. High-yield synthesis of boron nitride nanosheets with strong ultraviolet cathodoluminescence emission[J]. J Phys Chem C, 2009,113(34):15160-15165. doi: 10.1021/jp904246j
5. [5]
  JIA Yan. Preparation of AlN and BN nanomaterials by direct-current arc method and study on high temperature and high pressure[D]. Jilin: Jilin University, 2013.
6. [6]
  HE Dong-qing, LIANG Jia-ming, LIANG Bing. Progress in preparation of hexagonal boron nitride particles[J]. Mater Re, 2015,29(9):92-96.
7. [7]
  ZHENG Sheng-zhi, DIAO Jie. Synthesis of hexagonal boron nitride and high temperature fineness[J]. J Liaodong Univ, 2008,15(2):69-70. doi: 10.3969/j.issn.1673-4939.2008.02.003
8. [8]
  WU J H, WANG L C, LV B L, CHEN J G. Facile fabrication of BCN nanosheet-encapsulated nano-Iron as highly stable Fischer-Tropsch synthesis catalyst[J]. ACS Appl Mater Interfaces, 2017,9(16):14319-14327. doi: 10.1021/acsami.7b00561
9. [9]
  ANGSHUMAN N, RAO C N R. Graphene analogues of BN: Novel synthesis and properties[J]. ACS Nano, 2010,4(3):1539-1544. doi: 10.1021/nn9018762
10. [10]
  TANG S L, LIU Y J, WANG H X, ZHAO J X, CAI Q H, WANG X Z. Modifying the electronic and magnetic properties of the boron nitride (BN) nanosheet by NH_x (x=0, 1, and 2) groups[J]. Diamond Relat Mater, 2014,44:54-61. doi: 10.1016/j.diamond.2013.12.005
11. [11]
  KUMAR R, RAO C N R. Functionality preservation with enhanced mechanical integrity in the nanocomposites of the metal-organic framework, ZIF-8, with BN nanosheets[J]. 2014, 1(1): 513-517.
12. [12]
  DENG X R, KOUSKA H, TOKOROYAMA T, UMEHARA N. Deposition and tribological behaviors of ternary BCN coatings at elevated temperatures[J]. Surf Coat Technol, 2014,259:2-6. doi: 10.1016/j.surfcoat.2014.08.087
13. [13]
  ZHAO Guo-wei, QIAN Qiong-li. Surface modification and application of boron nitride nanotubes[J]. J Wuhan Inst Technol, 2011,33:14-20.
14. [14]
  WU J H, WANG L C, YANG X, LV B L, CHEN J G. Support effect of the Fe/BN catalyst on Fischer-Tropsch performances: Role of the surface B-O defect[J]. Ind Eng Chem Res, 2018,57(8):2805-2810. doi: 10.1021/acs.iecr.7b04864
15. [15]
  YUAN Lei, YU Jing-kun. Preparation and crystallization conversion behavior of t-BN[J]. J Northeast Univ, 2008,29:93-95. doi: 10.3321/j.issn:1005-3026.2008.01.024
16. [16]
  GUO Shu-peng, LI De-bao. Study on F-T reaction performance of Co/Al₂O₃-SiO₂ catalyst[J]. J Fuel Chem Technol, 2018,46(2):198-203. doi: 10.3969/j.issn.0253-2409.2018.02.009
17. [17]
  ROZENBERG A S, STNENKO Y A, CHUKANOV N V. I. R. Spectroscopy characterization of various types of structural irregularities in pyrolytic boron nitride[J]. J Mater Sci, 1993,28:5675-5678. doi: 10.1007/BF00367846
18. [18]
  MA Cai-lian, CHEN Jian-gang. Effect of Cu promoter on the performance of polyvinyl alcohol-assisted precipitated iron catalyst for Fischer-Tropsch synthesis[J]. J Fuel Chem Technol, 2018,46(7):835-840. doi: 10.3969/j.issn.0253-2409.2018.07.009
19. [19]
  ZIELINSKI I Z J, ZNAK L, KASZKUR Z. Reduction of Fe₂O₃ with hydrogen[J]. Appl Catal A: Gen, 2010,381(1/2):191-196.
20. [20]
  DING J, CHEN J G. Hydrogenation of diethyl oxalate over Cu/SiO₂ catalyst with enhanced activity and stability: Contribution of the spatial restriction by varied pores of support[J]. Appl Catal A: Gen, 2018,508:68-79.
21. [21]
  XIONG H, MOTCHELAHO M A, MOYO M, JEWELL L L, COVILLE N J. Effect of group I alkali metal promoters on Fe/CNT catalysts in Fischer-Tropsch synthesis[J]. Fuel, 2015,150(15):687-696.
22. [22]
  DE SMIT E, DE GROOT F M, BLUME R, HAVECKER M, KNOP-GERICKE A, WECKHUYSEN B M. The role of Cu on the reduction behavior and surface properties of Fe-based Fischer-Tropsch catalysts[J]. Phys Chem Chem Phys, 2010,12(3):667-680. doi: 10.1039/B920256K
23. [23]
  AN Xia. Effects of some preparation factors on the structure of iron-based catalysts and the performance of F-T synthesis[D]. Taiyuan: Institute of Coal Chemistry, Chinese Academy of Sciences, 2007.
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沈阳化工大学材料科学与工程学院沈阳 110142