Citation: ZHANG Qiang, MA Xiao-yue, LIU Lu. Effect of seed form on the structure and properties of as-synthesized SAPO-34 molecular sieves and their catalytic performance in the conversion of methanol to olefins[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(10): 1225-1230. shu

Effect of seed form on the structure and properties of as-synthesized SAPO-34 molecular sieves and their catalytic performance in the conversion of methanol to olefins

ZHANG Qiang ^1,, ,
MA Xiao-yue ² ,
LIU Lu ¹

1.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266580, China
2.
Dongying Haike Spring Chemical Limited Liability Company, Dongying 257000, China

Corresponding author: ZHANG Qiang, xyz@upc.edu.cn
Received Date: 17 April 2018
Revised Date: 7 July 2018

Fund Project: the National Natural Science Foundation of China 21406270The project was supported by the National Natural Science Foundation of China (21406270)

Figures(4)

A series of SAPO-34 molecular sieves with low Si/Al ratio were synthesized by conventional hydrothermal method as well as adding powder crystal seed and liquid crystal seed containing SAPO-34 precursor. These SAPO-34 molecular sieves were characterized by XRD, SEM, FT-IR and NH₃-TPD and the effects of synthesis method on the structure, morphology, crystal size and acidity of the resultant SAPO-34 molecular sieves as well as their catalytic performance in the conversion of methanol to olefins (MTO) were investigated. The results indicate that although the seed form has little influence on the crystallinity, the silicon distribution in SAPO-34 framework, crystal size, and acidic properties are strongly related to the seed form. In comparison with the SAPO-34 sample synthesized with powder form seed, the SAPO-34 molecular sieves prepared using liquid crystal seed containing SAPO-34 precursor exhibit smaller crystal size, weaker acidic strength, and higher selectivity to light olefins in MTO.
- low silicon/aluminium ratio,
- SAPO-34,
- molecular sieves,
- methanol-to-olefin,
- solid seed method,
- liquid seed method
1. [1]
  LI Z, MARTÍNEZ-TDIGUERO J, CONCEPCIÓN P, YU J, COEMA A. Methanol to olefins:Activity and stability of nanosized SAPO-34molecular sieves and control of selectivity by silicon distribution[J]. Phys Chem Chem Phys, 2013,15(35):14670-14680. doi: 10.1039/c3cp52247d
2. [2]
  HAJIASHRAFI T, NEMATI K A. Study of preparation methods and their effect on the morphology and texture of SAPO-34 for the methanol to olefin reaction[J]. React Kinet Mech Catal, 2013,108(2):417-432. doi: 10.1007/s11144-012-0520-7
3. [3]
  IZADBAKHSH A, FARHADI F, KHORASHEH F, SAHEBDELFAR S, ASADI M, ZI FENG Y. Effect of SAPO-34's composition on its physico-chemical properties and deactivation in MTO process[J]. Appl Catal A:Gen, 2009,364(1/2):48-56.
4. [4]
  ASKARI S, HALLADJ R, SOHRABI M. An overview of the effects of crystallization time, template and silicon sources on hydrothermal synthesis of SAPO-34 molecular sieve with small crystals[J]. Rev Adv Mater Sci, 2012,32(2):83-93.
5. [5]
  CUNDY C S, COX P A. The hydrothermal synthesis of zeolites:Precursors, intermediates and reaction mechanism[J]. Microporous Mesoporous Mater, 2005,82(1):1-78.
6. [6]
  SEDIGHI M, TOWFIGHI J, MOHAMADALIZADEH A. Effect of phosphorus and water contents on physico-chemical properties of SAPO-34 molecular sieve[J]. Powder Technol, 2014,259(2):81-86.
7. [7]
  HIROTA Y, MURATA K, TANAKA S, NISHIYAMA N, EGASHIRA Y, UEYAMA K. Dry gel conversion synthesis of SAPO-34 nanocrystals[J]. Mater Chem Phys, 2010,123(2):507-509.
8. [8]
  WU L, LIU Z, QIU M, YANG C, XIA L, LIU X, SUN Y. Morphology control of SAPO-34 by microwave synthesis and their performance in the methanol to olefins reaction[J]. React Kinet Mech Catal, 2014,111(1):319-334. doi: 10.1007/s11144-013-0639-1
9. [9]
  ASKARI S, HALLADJ R. Ultrasonic pretreatment for hydrothermal synthesis of SAPO-34 nanocrystals[J]. Ultrason Sonochem, 2012,19(3):554-559. doi: 10.1016/j.ultsonch.2011.09.006
10. [10]
  SÁNCHEZ-SÁNCHEZ M, ROMERO Á A, PINILLA-HERRERO I, SASTRE E. Ionothermal preparation of triclinic SAPO-34 and its catalytic performance in the MTO process[J]. Catal Today, 2017,296:239-246. doi: 10.1016/j.cattod.2017.04.065
11. [11]
  JÚNIOR L V D S, SILVA A O S, SILVA B J B, ALENCAR S L. Synthesis of ZSM-22 in static and dynamic system using seeds[J]. Mod Res Catal, 2014,3(2):49-56. doi: 10.4236/mrc.2014.32007
12. [12]
  WU Q, NARTEY I, HUANG Y, FANG Y. Synthesis of hierarchical SAPO-11 via seeded crystallization[J]. Microporous Mesoporous Mater, 2015,218:24-32. doi: 10.1016/j.micromeso.2015.06.040
13. [13]
  WANG Y, WANG X, WU Q, MENG X, JI NY, ZHOU X, XIAO F S. Seed-directed and organotemplate-free synthesis of TON zeolite[J]. Catal Today, 2014,226(11):103-108.
14. [14]
  SOUSA L V, SILVA A O S, SILVA B J B, TEIXEIRA CM, ARCANJO AP, FRETY R, PACHECOA J G. A Fast synthesis of ZSM-22 zeolite by the seed-assisted method of crystallization with methanol[J]. Microporous Mesoporous Mater, 2017,254:192-200. doi: 10.1016/j.micromeso.2017.04.003
15. [15]
  WILSON S, BARGER P. The characteristics of SAPO-34 which influence the conversion of methanol to light olefins[J]. Microporous Mesoporous Mater, 1999,29(1/2):117-126.
16. [16]
  IZADBAKHSH A, FARHADI F, KHORASHEH F, SAHEBDELFAR S, ASADI M, YAN Z F. Key parameters in hydrothermal synthesis and characterization of low silicon content SAPO-34 molecular sieve[J]. Microporous Mesoporous Mater, 2009,126(1/2):1-7.
17. [17]
  DI Chun-yu, ZHANG He, XU Dan, LI Xiao-feng, DOU Tao. Synthesis of SAPO-34 molecular sieves by seed gel method and their catalytic performance in methanol to olefins reaction[J]. Ind Catal, 2012,20(2):33-37. doi: 10.3969/j.issn.1008-1143.2012.02.008
18. [18]
  CHEN J, THOMAS J M, WRIGHT P A, TOWNSEND R P. Silicoaluminophosphate number eighteen(SAPO-18):A new microporous solid acid catalyst[J]. Catal Lett, 1994,28(2/4):241-248.
19. [19]
  VENNA S R, CARREON M A. Synthesis of SAPO-34 crystals in the presence of crystal growth inhibitors[J]. J Phys Chem B, 2008,112(51):16261-16265. doi: 10.1021/jp809316s
20. [20]
  LIU X, DU S, ZHANG B. Seeded growth of dense and thin SAPO-34 membranes on porousα-Al₂O₃ substrates under microwave irradiation[J]. Mater Lett, 2013,91:195-197. doi: 10.1016/j.matlet.2012.09.076
21. [21]
  DAN Bao-song, WANG Wei, ZHAO Feng-wei, YANG Jan-ming, CUI Wen-hua, LÜ Jian. Synthesis of SAPO-34 molecular sieve[J]. Ind Catal, 2010,18(9):52-54. doi: 10.3969/j.issn.1008-1143.2010.09.010
22. [22]
  XU Ruren. Molecular Sieves and Porous Materials Chemistry[C]. Beijing: Science Press, 2004, 39.
23. [23]
  ZHAO Dong-pu, ZHAO Quan-sheng, ZHANG Yan, SHI Tuo, YAO Heng-guo, YU Jian-qiang. Synthesis and characterization of intergrowth structured SAPO-18/SAPO-34[J]. Chem J Chin Univ, 2016,37(2):342-348.
24. [24]
  NAJAFI N, ASKARI S, HALLADJ R. Hydrothermal synthesis of nanosized SAPO-34 molecular sieves by different combinations of multitemplates[J]. Powder Technol, 2014,254(25):324-330.
25. [25]
  TAN J, LIU Z, BAO X H. Crystallization and Si incorporation mechanisms of SAPO-34[J]. Microporous Mesoporous Mater, 2002,53(1/3):97-108.
26. [26]
  KIKHTYANIN O V, TOKTAREV A V, AYUPOV A B, ECHEVSKY G V. Influence of crystallinity on the physico-chemical properties of SAPO-31 and hydro conversion of n-octane over Pt loaded catalysts[J]. Appl Catal A:Gen, 2010,378(1):96-106. doi: 10.1016/j.apcata.2010.02.005
27. [27]
  LIU G, TIAN P, LIU Z. Synthesis of SAPO-34 molecular sieves templated with diethylamine and their properties compared with oher templates[J]. Chin J Catal, 2012,33(1):174-182. doi: 10.1016/S1872-2067(10)60325-2
28. [28]
  FIGUEIREDOA A L, ARAUJOA A S, LINARESB M, LINARES M, GARCIA P Á, SERRANO D P, FERNANDES JR V J. Catalytic cracking of LDPE over nanocrystalline HZSM-5 zeoliteprepared by seed-assisted synthesis from an organic-template-freesystem[J]. J Anal Appl Pyrolysis, 2016,117:132-140. doi: 10.1016/j.jaap.2015.12.005
29. [29]
  IZADBAKHSH A, FARHADI F, KHORASHEH F, SAHEBDELFAR S, ASADI M, YAN Z F. Effect of SAPO-34's composition on its physicochemical properties and deactivation in MTO process[J]. Appl Catal A:Gen, 2009,364(1/2):48-56.
30. [30]
  AGHAMOHAMMADI S, HAGHIGHI M. Dual-template synthesis of nanostructured CoAPSO-34 used inmethanol to olefins:Effect of template combinations on catalytic performance and coke formation[J]. Chem Eng J, 2015,264:359-375. doi: 10.1016/j.cej.2014.11.102
31. [31]
  RAHIMI K, TOWFIGHI J, SEDIGHI M, MASOUMI S, KOOSHKI Z. The effects of SiO₂/Al₂O₃ and H₂O/Al₂O₃ molar ratios on SAPO-34 catalysts in methanol to olefins (MTO) process using experimental design[J]. J Ind Eng Chem, 2016,35:123-131. doi: 10.1016/j.jiec.2015.12.015
32. [32]
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