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Citation: Zhao Chao, Lu Yingxian, Cao Weixiao. Diazoresins with Organic Anion[J]. Chinese Journal of Applied Chemistry, ;1998, 15(5): 113-114. shu

Diazoresins with Organic Anion

College of Chemistry and Molecular Engineering, Peking University, Beijing 100871

Received Date: 11 November 1997
Revised Date: 4 May 1998

Diazoresins derived from diphenylamine 4-diazonium salt(DDS) and 3-methoxydiphenylamine-4-diazonium salt(MDDS) with various organic anions were prepared and their thermal decomposition temperatures(T_d) were determined. The results showed that the diazoresins from MDDS exhibited higher T_d than that from DDS and the diazoresins with BHMS(3-benzoyl-4-hydroxyl-6-methoxybenzsulfonic acid), NS(2-naphthalene sulfonic acid), DB-NS(4,8-dibutyl-2-naphthalene sulfonic acid) or PSS(polystyrene sulfonic acid) as anion possess higher T_d than that with DBS(dodecylbenzsulfonic acid) or SDS(dodecylsulfuric acid) as anion, but close to that with HSO₄^- as anion. The photoimaging behavior of the diazoresins with organic anion was examined.
- organic anion,
- diazoresin,
- thermal decomposition
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