Citation: WANG Sheng-kang, WEI Xian-yong, WANG Yu-gao, LI Zhan-ku, CHEN You-xiang, XU Dan-dan, TENG Qing-qing, LI Wei-tu, LIU Xiang-xue, ZHOU Ming-yao, ZONG Zhi-min. Compositional features of extracts from Shenmu char powder[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(1): 1-6. shu

Compositional features of extracts from Shenmu char powder

Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining & Technology, Xuzhou 221116, China

Corresponding author: WEI Xian-yong, wei_xianyong@163.com
Received Date: 22 September 2015
Revised Date: 2 December 2015

Fund Project: the Research and Innovation Project for College Graduates of Jiangsu Province KYLX_1396The project was supported by the National Natural Science Foundation of China 21276268

Figures(8)

Shenmu char powder (SCP) was sequentially extracted with petroleum ether, carbon disulfide, dichloromethane, acetone, and methanol in a Soxhlet extractor to obtain extracts 1-5 (E_1-5) and final residue. The total extract yield of SCP is 1.76%. All the extracts were characterized with gas chromatograph/mass spectrometer (GC/MS), atmospheric solid analysis probe/time-of-flight mass spectrometer (ASAP/TOF-MS), and electrospray ionization/time-of-flight mass spectrometer (ESI/TOF-MS). Normal alkanes with C₁₅ to C₂₄ and arenes with 3 and 4 rings are predominant in E₁ and E₂, respectively, while more heteroatom-containing organic species were identified in E_3-5. Organooxygen compounds are the most abundant in E₄ and E₅ based on analysis with GC/MS. Much more heteroatom-containing organic compounds were detected in E_3-5 with ASAP/TOF-MS and ESI/TOF-MS than with GC/MS.
- char powder,
- Soxhlet extraction,
- extracts,
- compositional features
1. [1]
  SUN H Q, QU S J, WANG L B. Present situation of the semi-coke production and utilization[J]. Clean Coal Technol, 2008,14(6):62-65.
2. [2]
  JIAO Y, HU B S, GUI Y L. Feasibility analysis of semi-coke as JISCO blast furnace with coal injection[J]. Energy Metall Ind, 2011,30(6):20-22.
3. [3]
  TIAN Y H, LAN X Z, ZHOU J, CHEN X Y, LI L B. Preparation of activated carbon from blue coke powder by microwave radiation and KOH activation[J]. Chem Eng, 2010,38(10):225-228.
4. [4]
  ZHANG C R, YE D M, CUI Y J, WU C Y, SHI X M. Study on industrial test of manufacture activated carbon in waste semi-coke powder[J]. Coal Convers, 1999,22(2):75-78.
5. [5]
  ZHENG M D, YAN S C, HE X J. High value-added-value utilization of coke fine[J]. Fuel Chem Process, 2007,38(2):21-23.
6. [6]
  WANG Y G, WEI X Y, LIU J, YAN H L, WEI Z H, LI Y, LI P, LIU F J, ZONG Z M. Oxidation of Shenmu char powder with aqueous hydrogen peroxide-acetic anhydride[J]. Fuel Process Technol, 2015,136:56-63. doi: 10.1016/j.fuproc.2014.09.023
7. [7]
  WU J J, HAN J Y, CHEN T B, YING Y, LI F M. Study of formed coke production and gasification experiment[J]. J China Univ Min Technol, 2005,34(6):779-783.
8. [8]
  LI Z K, WEI X Y, YANG Z S, YAN H L, WEI Z H, LI Y, ZONG Z M. Characterization of extracts from Geting bituminous coal[J]. Anal Lett, 2015,48(9):1494-1501. doi: 10.1080/00032719.2014.989529
9. [9]
  SHI D L, WEI X Y, FAN X, ZONG Z M, CHEN B, ZHAO Y P, WANG Y G, CAO J P. Characterizations of the extracts from Geting bituminous coal by spectrometries[J]. Energy Fuels, 2013,27(7):3709-3717. doi: 10.1021/ef4004686
10. [10]
  WEI X Y, WANG X H, ZONG Z M, NI Z H, ZHANG L F, JI Y F, XIE K C, LEE C W, LIU Z X, CHU N B, CUI J Y. Identification of organochlorines and organobromines in coals[J]. Fuel, 2004,83(17):2435-2438.
11. [11]
  SUN L B, ZONG Z M, KOU J H, CAO J P, YU G Y, ZHAO W, LI B M, LEE C W, XIE K C, WEI X Y. Identification of organic chlorines and iodines in the extracts from hydrotreated Argonne Premium coal residues[J]. Energy Fuels, 2007,21(4):2238-2239. doi: 10.1021/ef070091m
12. [12]
  WEI X Y, WANG X H, ZONG Z M. Extraction of organonitrogen compounds from five Chinese coals with methanol[J]. Energy Fuels, 2009,23(10):4848-4851. doi: 10.1021/ef900086h
13. [13]
  LIU Z X, LIU Z C. GC/MS analysis of water-soluble products from the mild oxidation of Longkou brown coal with H₂O₂[J]. Energy Fuels, 2003,17(2):424-426. doi: 10.1021/ef020071e
14. [14]
  LI P, ZONG Z M, LIU F J, WANG Y G, WEI X Y, FAN X, ZHAO Y P, ZHAO W. Sequential extraction and characterization of liquefaction residue from Shenmu-Fugu subbituminous coal[J]. Fuel Process Technol, 2015,136:1-7. doi: 10.1016/j.fuproc.2014.04.013
15. [15]
  LI P, ZONG Z M, LI Z K, WANG Y G, LIU F J, WEI X Y. Characterization of basic heteroatom-containing organic compounds in liquefaction residue from Shenmu-Fugu subbituminous coal by positive-ion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry[J]. Fuel Process Technol, 2015,132:91-98. doi: 10.1016/j.fuproc.2014.12.026
16. [16]
  RAMLUCKAN K, MOODLEY K G, BUX F. An evaluation of the efficacy of using selected solvents for the extraction of lipids from algal biomass by the soxhlet extraction method[J]. Fuel, 2014,116:103-108. doi: 10.1016/j.fuel.2013.07.118
17. [17]
  DUTTA R, SARKAR U, MUKHERJEE A. Soxhlet extraction of crotalaria Juncea oil using cylindrical and annular packed beds[J]. Int J Chem Eng Appl, 2015,6(2):130-133.
18. [18]
  LIU F J, WEI X Y, LI W T, GUI J, LI P, WANG Y G, XIE R L, ZONG Z M. Methanolysis of extraction residue from Xianfeng lignite with NaOH and product characterizations with different spectrometries[J]. Fuel Process Technol, 2015,136:8-16. doi: 10.1016/j.fuproc.2014.07.012
19. [19]
  ZONG Y, ZONG Z M, DING M J, ZHOU L, HUANG Y G, ZHENG Y Y, JIN X, MA Y M, WEI X Y. Separation and analysis of organic compounds in an Erdos coal[J]. Fuel, 2009,88(3):469-474. doi: 10.1016/j.fuel.2008.09.010
20. [20]
  MCEWEN C N, MCKAY R G, LARSEN B S. Analysis of solids, liquids, and biological tissues using solids probe introduction at atmospheric pressure on commercial LC/MS instruments[J]. Anal Chem, 2005,77(23):7826-7831. doi: 10.1021/ac051470k
21. [21]
  MCEWEN C N, LARSEN B S. Ionization mechanisms related to negative ion APPI, APCI, and DART[J]. J Am Soc Mass Spectrom, 2009,20(8):1518-1521. doi: 10.1016/j.jasms.2009.04.010
22. [22]
  BRUNS E A, PERRAUD V, GREAVES J, FINLAYSON-PITTS B J. Atmospheric solids snalysis probe mass spectrometry: A new approach for airborne particle analysis[J]. Anal Chem, 2010,82(14):5922-5927. doi: 10.1021/ac101028j
23. [23]
  BENNANI Y L. Drug discovery in the next decade: Innovation needed ASAP[J]. Drug Discovery Today, 2011,16(17/18):779-792.
24. [24]
  AHMED A, CHO Y J, NO M H, KOH J, TOMCZYK N, GILES K, YOO J S, KIM S. Application of the Mason-Schamp equation and ion mobility mass spectrometry to identify structurally related compounds in crude oil[J]. Anal Chem, 2010,83(1):77-83.
25. [25]
  TRIMPIN S, WIJERATHNE K, MCEWEN C N. Rapid methods of polymer and polymer additives identification: multi-sample solvent-free MALDI, pyrolysis at atmospheric pressure, and atmospheric solids analysis probe mass spectrometry[J]. Anal Chim Acta, 2009,654(1):20-25. doi: 10.1016/j.aca.2009.06.050
26. [26]
  SMITH M J, CAMERON N R, MOSELY J A. Evaluating atmospheric pressure solids analysis probe (ASAP) mass spectrometry for the analysis of low molecular weight synthetic polymers[J]. Analyst, 2012,137(19):4524-4530. doi: 10.1039/c2an35556f
27. [27]
  GARCÍA-VILLALBA R, CARRASCO-PANCORBO A, OLIVERAS-FERRAROS C, VÁZQUEZ-MARTÍN A, MENÉNDEZ J A, SEGURA-CARRETERO A, FERNÁNDEZ-GUTIÉRREZ A. Characterization and quantification of phenolic compounds of extra-virgin olive oils with anticancer properties by a rapid and resolutive LC-ESI-TOF MS method[J]. J Pharm Biomed Anal, 2010,51(2):416-429. doi: 10.1016/j.jpba.2009.06.021
28. [28]
  OUNI Y, TAAMALLI A, GOMEZ-CARAVACA A M, SEGURA-CARRETERO A, FERNÁNDEZ-GUTIÉRREZ A, ZARROUK M. Characterisation and quantification of phenolic compounds of extra-virgin olive oils according to their geographical origin by a rapid and resolutive LC-ESI-TOF MS method[J]. Food Chem, 2011,127(3):1263-1267. doi: 10.1016/j.foodchem.2011.01.068
29. [29]
  BAJOUB A, CARRASCO-PANCORBO A, AMINE AJAL E, OUAZZANI N, FERNÁNDEZ-GUTIÉRREZ A. Potential of LC-MS phenolic profiling combined with multivariate analysis as an approach for the determination of the geographical origin of north Moroccan virgin olive oils[J]. Food Chem, 2015,166(166):292-300.
30. [30]
  AL-QAIM F F, ABDULLAH M P, OTHMAN M R, LATIP J, AFIQ W. A validation method development for simultaneous LC-ESI-TOF/MS analysis of some pharmaceuticals in Tangkas river-Malaysia[J]. J Braz Chem Soc, 2014,25(2):271-281.
31. [31]
  ZHAO L, LIANG S, LV L, ZHANG H, CHAI Y, ZHANG G. Screening and analysis of metabolites in rat urine after oral administration of Apocynum venetum L. extracts using HPLC-TOF-MS[J]. J Sep Sci, 2014,37(5):515-526. doi: 10.1002/jssc.201301036
32. [32]
  XU F, LI D P, HUANG Z C, LU F L, WANG L, HUANG Y L, WANG R F, LIU G X, SHANG M Y, CAI S Q. Exploring in vitro, in vivo metabolism of mogroside V and distribution of its metabolites in rats by HPLC-ESI-IT-TOF-MSⁿ[J]. J Pharm Biomed Anal, 2015,115(11):418-430.
33. [33]
  ZONG Z M, ZHANG J W, XIE R L, WANG T X, GAO J S, WU Y Q, WANG F C, LI B M, WEI X Y. Effect of charring temperature on the composition and solubility of chars formed from rapid heating of Shenfu coal[J]. Energy Sources Part A, 2010,32(7):620-627. doi: 10.1080/15567030802564773
34. [34]
  LIANG H D. Secondary ion mass spectrometry of high-sulfur coal: Observation and interpretation of poly-sulfur ions[J]. Chin Sci Bull, 1999,44(13):1242-1245. doi: 10.1007/BF02885975
35. [35]
  LIANG H D. Experimental evidence for naturally occurring molecular chlorine (Cl₂) in organic phase of Chinese super-high sulfur coal[J]. J Fuel Chem Technol, 2001,29(5):385-389.
36. [36]
  RAO Z, LIANG H D, LI Y F. Analysis of sulfur forms in high sulfur coals[J]. Rock Miner Anal, 2001,20(3):183-186.
37. [37]
  PETUCCI C, DIFFENDAL J. Atmospheric solids analysis probe: A rapid ionization technique for small molecule drugs[J]. J Mass Spectrom, 2008,43(11):1565-1568. doi: 10.1002/jms.v43:11
38. [38]
  ZHU J L, FAN X, WEI X Y, WANG S Z, ZHU T G, ZHOU C C, ZHAO Y P, WANG R Y, LU Y, CHEN L, YOU C Y. Molecular characterization of heteroatomic compounds in a high-temperature coal tar using three mass spectrometers[J]. Fuel Process Technol, 2015,138:65-73. doi: 10.1016/j.fuproc.2015.04.020
39. [39]
  VENTER A, NEFLIU M, COOKS R G. Ambient desorption ionization mass spectrometry[J]. TrAC, Trends Anal Chem, 2008,27(4):284-290. doi: 10.1016/j.trac.2008.01.010
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