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Citation: Shi Shuangqun, Liu Zhixian, Li Dianxun. Synthesis and O₂^-° Scavenging Effect of meso- Tetra(4-substituted pyridyl)porphyrin Complexes with Copper(Ⅱ)[J]. Chinese Journal of Applied Chemistry, ;1998, 15(2): 55-58. shu

Synthesis and O₂^-° Scavenging Effect of meso- Tetra(4-substituted pyridyl)porphyrin Complexes with Copper(Ⅱ)

Department of Chemistry, Hebei Normal University, Shijiazhuang 050016

Received Date: 10 July 1997
Revised Date: 11 November 1997

The complexes of meso tetra(4-N-R pyridyl)porphyrin(R=CH₃, PhCH₂) with Cu(Ⅱ) (CuTMPyP and CuTBPyP) were synthesized by heterogeneous metal insertion reaction. The improved method is advangeous in simplicity and having good yield. Both complexes showed a distinct O₂^-° scavenging effect and some protective effects on hemoglobin of human erythrocyte in the system of O₂^-° generating riboflavin on irradiation.
- copper porphyrin complex,
- synthesis,
- peroxide anion radical,
- scavenging effect,
- hemoglobin
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Synthesis and O2-° Scavenging Effect of meso- Tetra(4-substituted pyridyl)porphyrin Complexes with Copper(Ⅱ)

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通讯作者: 陈斌, bchen63@163.com

Synthesis and O₂^-° Scavenging Effect of meso- Tetra(4-substituted pyridyl)porphyrin Complexes with Copper(Ⅱ)