Citation: CHENG Chun-yuan, LIU Su-yao, WU Bao-shan. Support effects on ruthenium catalyst for the Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(5): 556-563. shu

Support effects on ruthenium catalyst for the Fischer-Tropsch synthesis

CHENG Chun-yuan ^1,2 ,
LIU Su-yao ^3,4 ,
WU Bao-shan ^1,3,4,*,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
National Engineering Laboratory for Indirect Coal Liquefaction, Beijing 101407, China
4.
Synfuels China Technology CO. LTD., Beijing 101407, China

Corresponding author: WU Bao-shan, wbs@sxicc.ac.cn
Received Date: 16 January 2017
Revised Date: 14 March 2017

Fund Project: National Natural Science Foundation of China 21473229

Figures(8)

Series of Ru-based F-T synthesis catalysts, respectively with different supports of SiO₂, Al₂O₃ and Beta zeolite, were prepared by impregnation method. Characterization techniques such as N₂-adsorption, XRD, NH₃-TPD, H₂-TPR, H₂-TPD, XPS and CO-DRIFTS were used to study the textural structure, phase, acidity, reduction behavior, chemical adsorption and electron properties of the catalysts. F-T synthesis performances of the catalysts were investigated as well. The results indicated that the supports imposed obvious effects on the reduction and dispersion of Ru, therefore led to the differences in acidity and surface properties of the catalysts. F-T reaction performance showed that the relatively stable Ru/SiO₂ catalyst exhibited high selectivity to heavy hydrocarbons, ascribing to its less acidity, weaker metal-support interaction, and better Ru particle dispersion.
- metal-support interaction,
- ruthenium catalyst,
- F-T synthesis
1. [1]
  HAMELINCK C, FAAIJ A, DENUIL H, BOERRIGTER H. Production of FT transportation fuels from biomass; technical options, process analysis and optimisation, and development potential[J]. Energy, 2004,29(11):1743-1771. doi: 10.1016/j.energy.2004.01.002
2. [2]
  DRY M E. Fischer-Tropsch reactions and the environment[J]. Appl Catal A: Gen, 1999,189(2):185-190. doi: 10.1016/S0926-860X(99)00275-6
3. [3]
  SCHULZ H. Short history and present trends of Fischer-Tropsch synthesis[J]. Appl Catal A: Gen, 1999,186(1/2):3-12.
4. [4]
  CLAEYS M, VAN STEEN E. On the effect of water during Fischer-Tropsch synthesis with a ruthenium catalyst[J]. Catal Today, 2002,71(3/4):419-427.
5. [5]
  BOUDART M, MCDONALD M A. Structure sensitivity of hydrocarbon synthesis from CO and H₂[J]. J Phys Chem, 1984,88(11):2185-2195. doi: 10.1021/j150655a004
6. [6]
  KING D. A Fischer-Tropsch study of supported ruthenium catalysts[J]. J Catal, 1978,51(3):386-397. doi: 10.1016/0021-9517(78)90277-4
7. [7]
  STOOP F, VERBIEST A M G, VAN DER WIELE K. The influence of the support on the catalytic properties of Ru catalysts in the CO hydrogenation[J]. Appl Catal, 1986,25(1/2):51-57.
8. [8]
  IGLESIA E. Fischer-Tropsch synthesis on cobalt and ruthenium. Metal dispersion and support effects on reaction rate and selectivity[J]. J Catal, 1992,137(1):212-224. doi: 10.1016/0021-9517(92)90150-G
9. [9]
  JOSEFINA P-Z M, MURIEL D, YANN H, ANNE G, LUCIEN L, GINETTE L, MIREYA G, LUISA C M, GEOFFREY B. Characterization and reactivity of Ru/single oxides catalysts for the syngas reaction[J]. Appl Catal A: Gen, 2004,274(1-2):295-301. doi: 10.1016/j.apcata.2004.07.013
10. [10]
  WANG Ye, CHENG Kang, ZHANG Qing-hong. Selectivity tuning for the hydrogenation of carbon monoxide into hydrocarbons[J]. Sci China Chem, 2012,42(4):363-375.
11. [11]
  WANG Zi-qing, ZHANG Liu-ming, LIN Jian-xin, WANG Rong, WEI Ke-mei. Preparation and application of nanometer materials supported ruthenium catalysts[J]. Chin J Catal, 2012,33(3):377-388.
12. [12]
  LI Bo, SHAO Ling-ling. Appraisal of alumina and aluminium hydroxide by XRD[J]. Inorg Chem Ind, 2008,40(2):54-57.
13. [13]
  CHENG K, KANG J, HUANG S, YOU Z, ZHANG Q, DING J, HUA W, LOU Y, DENG W, WANG Y. Mesoporous Beta zeolite-supported ruthenium nanoparticles for selective conversion of synthesis gas to C₅-C₁₁ isoparaffins[J]. ACS Catal, 2012,2(3):441-449. doi: 10.1021/cs200670j
14. [14]
  CHEN L, LI Y, ZHANG X, ZHANG Q, WANG T, MA L. Mechanistic insights into the effects of support on the reaction pathway for aqueous-phase hydrogenation of carboxylic acid over the supported Ru catalysts[J]. Appl Catal A: Gen, 2014,478:117-128. doi: 10.1016/j.apcata.2014.03.038
15. [15]
  SUN J, LI X, TAGUCHI A, ABE T, NIU W, LU P, YONEYAMA Y, TSUBAKI N. Highly-dispersed metallic Ru nanoparticles sputtered on H-Beta zeolite for directly converting syngas to middle isoparaffins[J]. ACS Catal, 2014,4(1):1-8. doi: 10.1021/cs4008842
16. [16]
  HOSOKAWA S, NOGAWA S, TANIGUCHI M, UTANI K, KANAI H, IMAMURA S. Oxidation characteristics of Ru/CeO₂ catalyst[J]. Appl Catal A: Gen, 2005,288(1/2):67-73.
17. [17]
  FU X, YU H, PENG F, WANG H, QIAN Y. Facile preparation of RuO₂/CNT catalyst by a homogenous oxidation precipitation method and its catalytic performance[J]. Appl Catal A: Gen, 2007,321(2):190-197. doi: 10.1016/j.apcata.2007.02.002
18. [18]
  NIU T, LIU G L, LIU Y. Preparation of Ru/graphene-meso-macroporous SiO₂ composite and their application to the preferential oxidation of CO in H₂-rich gases[J]. Appl Catal B: Environ, 2014,154:82-92.
19. [19]
  CHEN L, ZHU Y, ZHENG H, ZHANG C, ZHANG B, LI Y. Aqueous-phase hydrodeoxygenation of carboxylic acids to alcohols or alkanes over supported Ru catalysts[J]. J Mol Catal A: Chem, 2011,351:217-227. doi: 10.1016/j.molcata.2011.10.015
20. [20]
  BERNAS A, KUMAR N, LAUKKANEN P, VÄYRYNEN J, SALMI T, MURZIN D Y. Influence of ruthenium precursor on catalytic activity of Ru/Al₂O₃ catalyst in selective isomerization of linoleic acid to cis-9, trans-11-and trans-10, cis-12-conjugated linoleic acid[J]. Appl Catal A: Gen, 2004,267(1/2):121-133.
21. [21]
  LIN H Y, CHEN Y W. The kinetics of H₂ adsorption on supported ruthenium catalysts[J]. Thermochim Acta, 2004,419(1/2):283-290.
22. [22]
  MARTÍNEZ-PRIETO L M, CARENCO S, WU C H, BONNEFILLE E, AXNANDA S, LIU Z, FAZZINI P F, PHILIPPOT K, SALMERON M, CHAUDRET B. Organometallic ruthenium nanoparticles as model catalysts for CO hydrogenation: A nuclear magnetic resonance and ambient-pressure X-ray photoelectron spectroscopy study[J]. ACS Catal, 2014,4(9):3160-3168. doi: 10.1021/cs5010536
23. [23]
  CHIN S Y, WILLIAMS C T, AMIRIDIS M D. FTIR studies of CO adsorption on Al₂O₃ and SiO₂ supported Ru catalysts[J]. J Phys Chem B, 2006,110(2):871-82. doi: 10.1021/jp053908q
24. [24]
  ELMASIDES C, KONDARIDES D I, GRVNERT W, VERYKIOS X E. XPS and FT-IR Study of Ru/Al₂O₃ and Ru/TiO₂ catalysts: Reduction characteristics and interaction with a methane-oxygen mixture[J]. J Phys Chem B, 1999,103(25):5227-5239. doi: 10.1021/jp9842291
25. [25]
  LIUZZI D, PÉREZ-ALONSO F J, GARCÍA-GARCÍA F J, CALLE-VALLEJO F, FIERRO J L G, ROJAS S. Identifying the time-dependent predominance regimes of step and terrace sites for the Fischer-Tropsch synthesis on ruthenium based catalysts[J]. Catal Sci Technol, 2016,6(17):6495-6503. doi: 10.1039/C6CY00476H
26. [26]
  VAN SANTEN R A, GHOURI M M, SHETTY S, HENSEN E M H. Structure sensitivity of the Fischer-Tropsch reaction; molecular kinetics simulations[J]. Catal Sci Technol, 2011,1(6):891-911. doi: 10.1039/c1cy00118c
27. [27]
  SHETTY S, JANSEN A P, VAN SANTEN R A. Direct versus hydrogen-assisted CO dissociation[J]. J Am Chem Soc, 2009,131(36):12874-5. doi: 10.1021/ja9044482
28. [28]
  TISON Y, NIELSEN K, MOWBRAY D J, BECH L, HOLSE C, CALLE-VALLEJO F, ANDERSEN K, MORTENSEN J J, JACOBSEN K W, NIELSEN J H. Scanning tunneling microscopy evidence for the dissociation of carbon monoxide on ruthenium steps[J]. J Phys Chem C, 2012,116(27):14350-14359. doi: 10.1021/jp302424g
29. [29]
  GONZÁLEZ-CARBALLO J M, PÉREZ-ALONSO F J, OJEDA M, GARCÍA-GARCÍA F J, FIERRO J L G, ROJAS S. Evidences of two-regimes in the measurement of Ru particle size effect for CO dissociation during Fischer-Tropsch synthesis[J]. ChemCatChem, 2014,6(7):2084-2094. doi: 10.1002/cctc.v6.7
30. [30]
  SHINCHO E, EGAWA C, NAITO S, TAMARU K. The behaviour of CO adsorbed on Ru (1, 1, 1, 0) and Ru (001); the dissociation of CO at the step sites of the Ru (1, 1, 1, 0) surface[J]. Surf Sci, 1985,149(1):1-16. doi: 10.1016/S0039-6028(85)80009-1
31. [31]
  BARTHOLOMEW C H. Mechanisms of catalyst deactivation[J]. Appl Catal A: Gen, 2001,212(1/2):17-60.
32. [32]
  HE J, YONEYAMA Y, XU B, NISHIYAMA N, TSUBAKI N. Designing a capsule catalyst and its application for direct synthesis of middle isoparaffins[J]. Langmuir, 2005,21(5):1699-1702. doi: 10.1021/la047217h
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