Citation: ZHAO Ruinian, LIANG Wenzhong. EFFECT OF SOLVENT ON THE COPOLYMERIZATION OF 2,2,6,6-TETRAMETHYL 4-PIPERIDINYL METHACRYLATE WITH STYRENE[J]. Chinese Journal of Polymer Science, ;1988, 6(3): 223-229. shu

EFFECT OF SOLVENT ON THE COPOLYMERIZATION OF 2,2,6,6-TETRAMETHYL 4-PIPERIDINYL METHACRYLATE WITH STYRENE

Received Date: 12 May 1987

The radical copolymerizations of 2,2,6, 6-tetramethyl 4-piperidinyl methacrylate (TMPM) with styrene in various solvents have been studied. The monomer reactivity ratios r1 and r2 were determined. It is observed that in all of these reaction systems, there are appreciable solvent effects on both r1 and r2, which can be correlated to the difference in chemical shifts of olefinic protons of TMPM. And the variance of the copolymer microstructure in various media was discussed.
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