Citation: BAI Yun-po, YANG Yong, WANG Jue, ZHENG Lin, LIAN Peng-fei, QING Ming, WANG You-liang, WANG Hong, ZHANG Guang-ji. Effect of carbonization process on the strength and structure of Fe-based Fischer-Tropsch synthesis catalyst[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(2): 204-210. shu

Effect of carbonization process on the strength and structure of Fe-based Fischer-Tropsch synthesis catalyst

BAI Yun-po ^1,2,3 ,
YANG Yong ^2,4,, ,
WANG Jue ² ,
ZHENG Lin ² ,
LIAN Peng-fei ² ,
QING Ming ² ,
WANG You-liang ² ,
WANG Hong ² ,
ZHANG Guang-ji ^3,,

1.
University of Chinese Academy of Sciences, Beijing 100049, China
2.
Synfuels China Co.Ltd., Beijing 101407, China
3.
Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
4.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Corresponding author: YANG Yong, yyong@sxicc.ac.cn ZHANG Guang-ji, gjzhang@ipe.ac.cn
Received Date: 30 October 2017
Revised Date: 22 December 2017

Figures(10)

In order to gain an insight into the relationship between pretreatment condition and catalyst attrition resistance, an iron-based model catalyst for Fisher-Tropsch synthesis was carburized at 300℃ for different times and extensively characterized by multiple techniques; the effect of carburization and carbon deposition on the catalyst attrition resistance was then investigated.The results indicated that at the initial stage of pretreatment, the carbide content increases with the increase of carburization time, whereas the BET surface area and particle size are decreased, leading to an increase in the catalyst attrition resistance.With further increasing the carburization time above 72 h, the carbide content keeps almost constant, whereas the carbon deposition content, particle size and catalyst weight are increased, accompanying with a decrease in the attrition resistance.
- Fischer-Tropsch synthesis,
- iron-based catalysts,
- pretreatment duration,
- attrition resistance,
- carburization,
- carbon deposition
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