Citation: BAI Yun-po, YANG Yong, WANG Jue, ZHENG Lin, LIAN Peng-fei, QING Ming, WANG You-liang, WANG Hong, ZHANG Guang-ji. Effect of carbonization process on the strength and structure of Fe-based Fischer-Tropsch synthesis catalyst[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(2): 204-210. shu

Effect of carbonization process on the strength and structure of Fe-based Fischer-Tropsch synthesis catalyst

BAI Yun-po ^1,2,3 ,
YANG Yong ^2,4,, ,
WANG Jue ² ,
ZHENG Lin ² ,
LIAN Peng-fei ² ,
QING Ming ² ,
WANG You-liang ² ,
WANG Hong ² ,
ZHANG Guang-ji ^3,,

1.
University of Chinese Academy of Sciences, Beijing 100049, China
2.
Synfuels China Co.Ltd., Beijing 101407, China
3.
Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
4.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Corresponding author: YANG Yong, yyong@sxicc.ac.cn ZHANG Guang-ji, gjzhang@ipe.ac.cn
Received Date: 30 October 2017
Revised Date: 22 December 2017

Figures(10)

In order to gain an insight into the relationship between pretreatment condition and catalyst attrition resistance, an iron-based model catalyst for Fisher-Tropsch synthesis was carburized at 300℃ for different times and extensively characterized by multiple techniques; the effect of carburization and carbon deposition on the catalyst attrition resistance was then investigated.The results indicated that at the initial stage of pretreatment, the carbide content increases with the increase of carburization time, whereas the BET surface area and particle size are decreased, leading to an increase in the catalyst attrition resistance.With further increasing the carburization time above 72 h, the carbide content keeps almost constant, whereas the carbon deposition content, particle size and catalyst weight are increased, accompanying with a decrease in the attrition resistance.
- Fischer-Tropsch synthesis,
- iron-based catalysts,
- pretreatment duration,
- attrition resistance,
- carburization,
- carbon deposition
1. [1]
  LI Juan, WU Liang-peng, QIU Yong, DING Ming-yue, WANG Tie-jun, LI Xin-jun, MA Long-long. LI Juan, WU Liang-peng, QIU Yong, DING Ming-yue, WANG Tie-jun, LI Xin-jun, MA Long-long.Research progress of catalysts for Fischer Tropsch synthesis[J]. Chem Ind Eng Prog, 2013,32(s1):100-109.
2. [2]
  DAVIS B H. Fischer-Tropsch synthesis:Reaction mechanisms for iron catalysts[J]. Catal Today, 2009,141(1):25-33.
3. [3]
  DRY M E, HOOGENDOORN J C. Technology of the Fischer-Tropsch process[J]. Cat Rev-Sci Eng, 1981,23(1/2):265-278.
4. [4]
  DRY M E. The Fischer-Tropsch process:1950-2000[J]. Catal Today, 2002,71(3):227-241.
5. [5]
  DRY M E. The Fischer-Tropsch process-commercial aspects[J]. Catal Today, 1990,6(3):183-206. doi: 10.1016/0920-5861(90)85002-6
6. [6]
  KROGH A. A review on coal-to-liquid fuels and its coal consumption[J]. Int J Energy Res, 2010,34(10):848-864. doi: 10.1002/er.v34:10
7. [7]
  SHROFF M D, KALAKKAD D S, COULTER K E, KOHLER S D, HARRINGTON M S, JACKSON N B. Activation of precipitated iron Fischer-Tropsch synthesis catalysts[J]. J Catal, 1995,156(2):185-207. doi: 10.1006/jcat.1995.1247
8. [8]
  BUKUR D B, OKABE K, ROSYNEK M P, LI C P, WANG D J. Activation studies with a precipitated iron catalyst for Fischer-Tropsch synthesis.Ⅰ.Characterization studies[J]. J Catal, 1995,155(2):353-365. doi: 10.1006/jcat.1995.1217
9. [9]
  BUKUR D B. Activation studies with a precipitated iron catalysts for Fischer-Tropsch synthesis.Ⅱ.Reaction studies[J]. J Catal, 1995,155(2):366-375. doi: 10.1006/jcat.1995.1218
10. [10]
  AMELSE J A, BUTT J B, SCHWARTZ L H. Carburization of supported iron synthesis catalysts[J]. J Phys Chem B, 1978,82(5):558-563. doi: 10.1021/j100494a012
11. [11]
  REYMOND J P, MÉRIAUDEAU P, TEICHNER S J. Changes in the surface structure and composition of an iron catalyst of reduced or unreduced Fe₂O₃, during the reaction of carbon monoxide and hydrogen[J]. J Catal, 1982,75(1):39-48. doi: 10.1016/0021-9517(82)90119-1
12. [12]
  KALAKKAD D S, SHROFF M D, KÖHLER S, JACKSON N, DATYE A K. Attrition of precipitated iron Fischer-Tropsch catalysts[J]. Appl Catal A:Gen, 1995,133(2):335-350. doi: 10.1016/0926-860X(95)00200-6
13. [13]
  ZHAO R, GOODWIN J G, JOTHIMURUGESAN , SANTOSH K, GANGWAL S K, SPIVEY J J. Spray-dried iron Fischer-Tropsch catalysts.1.Effect of structure on the attrition resistance of the catalysts in the calcined state[J]. Ind Eng Chem Res, 2001,40(4):1065-1075. doi: 10.1021/ie000644f
14. [14]
  ZHAO R, SUDSAKORN K, GOODWIN J G, JOTHIMURUGESAN K, SANTOSH K, GANGWAL , SPIVEY J J. Attrition resistance of spray-dried iron F-T catalysts:Effect of activation conditions[J]. Catal Today, 2002,71(3):319-326.
15. [15]
  ZHAO R, GOODWIN J G, JOTHIMURUGESAN , SANTOSH K, GANGWAL S K, SPIVEY J J. Spray-dried Iron Fischer-Tropsch catalysts.2.Effect of carburization on catalyst attrition resistance[J]. Ind Eng Chem Res, 2001,40(5):1320-1328. doi: 10.1021/ie0006458
16. [16]
  BAI Liang. Reaction engineering study on slurry fischer-tropsch synthesis over iron-based catalysts[D]. Taiyuan: Institute of Coal Chemistry, Chinese Academy of Sciences, 2004.
17. [17]
  YANG Y, XIANG H W, TIAN L, WANG H, ZHANG C H, TAO Z C. Structure and Fischer-Tropsch performance of iron-manganese catalyst incorporated with SiO₂[J]. Appl Catal A:Gen, 2005,284(1):105-122.
18. [18]
  QING Ming. Support effects of the iron-based catalysts for Fischer-Tropsch synthesis[D]. Taiyuan: Institute of Coal Chemistry, Chinese Academy of Sciences, 2011.
19. [19]
  SUO H Y, WANG S, ZHANG C H, XU J, WU B S, YANG Y. Chemical and structural effects of silica in iron-based Fischer-Tropsch synthesis catalysts[J]. J Catal, 2012,286(2):111-123.
20. [20]
  NING W, KOIZUMI N, CHANG H, MOCHIZUKI T, ITOH T, YAMADA M. Phase transformation of unpromoted and promoted Fe catalysts and the formation of carbonaceous compounds during Fischer-Tropsch synthesis reaction[J]. Appl Catal A:Gen, 2006,312(9):35-44.
21. [21]
  XU J, BARTHOLOMEW C H. Temperature-programmed hydrogenation (TPH) and in situ Mössbauer spectroscopy studies of carbonaceous species on silica-supported iron Fischer-Tropsch catalysts[J]. J Phys Chem B, 2005,109(6):2392-2403. doi: 10.1021/jp048808j
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沈阳化工大学材料科学与工程学院沈阳 110142