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Citation: CHEN Ying, HE Han, KONG Xiang-sen, LIU Tian-cong. Preparation of compound magnetic Fe3O4/MgAl-layered double hydroxide and its application in biodiesel transesterification[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(10): 1217-1224. shu

Preparation of compound magnetic Fe3O4/MgAl-layered double hydroxide and its application in biodiesel transesterification

  • School of Chemical Engineering, Northeast Petroleum University, Daqing 163318, China

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  • Magnetic Fe3O4 was synthesized by chemical coprecipitation method, and used as a raw material for preparing Fe3O4/MgAl-LDH. The calcined Fe3O4/Mg(Al)O was taken as the catalyst for the transesterification of microalgae oil with methanol, and the biodiesel yield was used to evaluate the activity of the catalyst. Several instruments including TG-DTG, XRD, SEM, EDS, TEM, N2 absorption-desorption and VSM were employed to characterize the catalysts. The results show that MgAl-LDH and Mg(Al)O are successfully formed on Fe3O4 particles which have a strong magnetic response. When the reaction time is 4 h and the methanol/oil mol ratio is 13:1, the biodiesel oil yield reaches to 90%. After using for three times the catalyst still has certain activity and can be easily separated and recycled.
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