Citation: LAN Mei-chen, SHEN Bo-xiong, WANG Jian-qiao, ZHAO Peng. Performance of activated carbon supported nickel catalysts in the pyrolysis of waste plastics to produce carbon nanotubes[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(11): 1313-1319. shu

Performance of activated carbon supported nickel catalysts in the pyrolysis of waste plastics to produce carbon nanotubes

School of Energy and Environmental Engineering, Hebei University of Technology, Tianjin 300401, China

Corresponding author: SHEN Bo-xiong, shenbx@hebut.edu.cn
Received Date: 29 August 2019
Revised Date: 25 September 2019

Fund Project: The project was supported by the Natural Science Foundation of Tianjin (18JCZDJC39800), Major Science and Technology Special Projects in Tianjin (18ZXSZSF00040), Tianjin Science Popularization Project(18KPXMSF00080), Tianjin Science and Technology Special Project(18PTZWHZ00010)and Hebei Postgraduate Innovation Subsidy Project (CXZZBS2019035)the Natural Science Foundation of Tianjin 18JCZDJC39800Major Science and Technology Special Projects in Tianjin 18ZXSZSF00040Hebei Postgraduate Innovation Subsidy Project CXZZBS2019035Tianjin Science and Technology Special Project 18PTZWHZ00010Tianjin Science Popularization Project 18KPXMSF00080

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A series of Ni based catalysts are prepared through impregnation method with coconut shell, bamboo charcoal and charcoal activated carbons as the support; their catalytic performance in the pyrolysis of waste plastics to produce carbon nanotubes was comparatively investigated. The structure and morphology of the catalyst and carbon nanotubes were characterized by X-ray diffraction, scanning electron microscope, transmission electron microscope, Raman spectroscopy, thermogravimetric analysis and nitrogen physisorption. The results show that carbon nanotubes with the highest yield and the best quality can be produced by using the nickel catalyst supported on coconut shell activated carbon (Ni/CSAC). In addition, the effect of reaction temperature and nickel loading on the catalytic performance of Ni/CSAC in the pyrolysis of waste plastics was considered.
- activated carbon,
- supported Ni-based catalysts,
- waste plastics,
- catalytic pyrolysis,
- carbon nanotubes
1. [1]
  DONG Xin. Waste plastics treatment: Energy utilization maybe become breakthrough[N]. China Energy Daily, 2018-06-11(19).
2. [2]
  TRIPATHI P K, DURBACH S, COVILLE N J. Synthesis of multi-walled carbon nanotubes from plastic waste using a stainless-steel CVD reactor as catalyst[J]. Nanomaterials, 2017,7(10):284-292. doi: 10.3390/nano7100284
3. [3]
  MOO J G S, VEKSHA A, OH W D, GIANNIS A, UDAYANGA W D C, LIN S X, GE L Y, LISAK G. Plastic derived carbon nanotubes for electrocatalytic oxygen reduction reaction:Effects of plastic feedstock and synthesis temperature[J]. Electrochem Commun, 2019,101:11-18. doi: 10.1016/j.elecom.2019.02.014
4. [4]
  ZHANG Ling. The optical properties and applications of carbon nanotube film[D]. Beijing: University of Tsinghua, 2017.
5. [5]
  LIU X T, SHEN B X, WU Z T, PARLETT C M A, HAN Z N, GEORGE A, YUAN P, PATEL D, WU C F. Producing carbon nanotubes from thermochemical conversion of waste plastics using Ni/ceramic based catalyst[J]. Chem Eng Sci, 2018,192:882-891. doi: 10.1016/j.ces.2018.07.047
6. [6]
  HUH Y, GREEN M L H, KIM Y H, KIM Y H, LEE J Y, LEE C J. Control of carbon nanotube growth using cobalt nanoparticles as catalyst[J]. Appl Surf Sci, 2005,249(1/4):145-150.
7. [7]
  MHLANGA S D, MONDAL K C, CARTER R, WITCOMB M J, COVILLE N J. The effect of synthesis parameters on the catalytic synthesis of multiwalled carbon nanotubes using Fe-Co/CaCO₃ catalysts[J]. S Afr J Chem, 2009,65(14):39-49.
8. [8]
  YAO D D, WU C F, YANG H P, ZHANG Y S, NAHIL M A, CHEN Y Q, WILLIAMS P T, CHEN H P. Co-production of hydrogen and carbon nanotubes from catalytic pyrolysis of waste plastics on Ni-Fe bimetallic catalyst[J]. Energy Convers Manage, 2017,148:692-700. doi: 10.1016/j.enconman.2017.06.012
9. [9]
  LIU X T, ZHANG Y S, NAHIL M A, WILLIAMS P T, WU C F. Development of Ni-and Fe-based catalysts with different metal particle sizes for the production of carbon nanotubes and hydrogen from thermo-chemical conversion of waste plastics[J]. J Anal Appl Pyrolysis, 2017,125:32-39. doi: 10.1016/j.jaap.2017.05.001
10. [10]
  SIVAKUMAR V M, ABDULLAH A Z, MOHAMED A R, CHAI S P. Optimized parameters for carbon nanotubes synthesis over Fe and Ni catalysts VIA methane CVD[J]. Rev Adv Mater Sci, 2011,27(1):25-30.
11. [11]
  ACOMB J C, WU C, WILLIAMS P T. The use of different metal catalysts for the simultaneous production of carbon nanotubes and hydrogen from pyrolysis of plastic feedstocks[J]. Appl Catal B:Environ, 2016,180(894):497-510.
12. [12]
  ZHENG Yang-fan, WANG Jun-kai, LI Sai-sai, SONG Jian-bo, ZHANG Hai-jun. Research progress in preparaton of carbon nanotubes bu catalytic pyrolysis of polymer plastics[J]. Refractories, 2018,52(4):304-309+314. doi: 10.3969/j.issn.1001-1935.2018.04.016
13. [13]
  JIANG Z W, SONG R J, BI W G, LU J, TANG T. Polypropylene as a carbon source for the synthesis of multi-walled carbon nanotubes via catalytic combustion[J]. Carbon, 2007,45(2):449-458. doi: 10.1016/j.carbon.2006.08.012
14. [14]
  ZHANG Li-jian. Expermental study on construction of advanced reduction system and removal of Cr(Ⅵ)from wastewater based on activated carbon[D]. Changchun: University of Jilin, 2018.
15. [15]
  GONZÁLEZ Y S, COSTA C, MARQUEZ M C, RAMOS P. Thermal and catalytic degradation of polyethylene wastes in the presence of silica gel, 5A molecular sieve and activated carbon[J]. J Hazard Mater, 2011,187(1/3):101-112.
16. [16]
  GONG J, LIU J, JIANG Z W, WEN X, CHEN X C, MIJOWSKA E, WANG Y H, TANG T. Effect of the added amount of organically-modified montmorillonite on the catalytic carbonization of polypropylene into cup-stacked carbon nanotubes[J]. Chem Eng J, 2013,225(6):798-808.
17. [17]
  GONG J, LIU J, WAN D, CHEN X C, WEN X, MIJOWSKA E, JIANG ZW, WANG Y H, TANG T. Catalytic carbonization of polypropylene by the combined catalysis of activated carbon with Ni₂O₃ into carbon nanotubes and its mechanism[J]. Appl Catal A:Gen, 2012,449(1):112-120.
18. [18]
  FUERTES A B, ALVAREZ S. Graphitic mesoporous carbons synthesised through mesostructured silica templates[J]. Carbon, 2004,42(15):3049-3055. doi: 10.1016/j.carbon.2004.06.020
19. [19]
  LIOU T H. Development of mesoporous structure and high adsorption capacity of biomass-based activated carbon by phosphoric acid and zinc chloride activation[J]. Chem Eng J, 2010,158(2):129-142.
20. [20]
  WAN H Z, LI L, CHEN Y, GONG J L, DUAN M Q, LIU C, ZHANG J, WANG H. One pot synthesis of Ni₁₂P₅ hollow nanocapsules as efficient electrode materials for oxygen evolution reactions and supercapacitor applications[J]. Electrochim Acta, 2017,229:380-386. doi: 10.1016/j.electacta.2017.01.169
21. [21]
  HUANG Z P, CHEN Z B, CHEN Z Z, LV C C, MENG H, ZHANG C. Ni₁₂P₅ Nanoparticles as an efficient catalyst for hydrogen generation via electrolysis and photoelectrolysis[J]. ACS Nano, 2014,8(8):8121-8129. doi: 10.1021/nn5022204
22. [22]
  ABOUL-ENEIN A A, AWADALLAH A E. Production of nanostructured carbon materials using Fe-Mo/MgO catalysts via mild catalytic pyrolysis of polyethylene waste[J]. Chem Eng J, 2018,354:802-816. doi: 10.1016/j.cej.2018.08.046
23. [23]
  GONG J, LIU J, WAN D, CHEN X C, WEN X, MIJOWSKA E, JIANG Z W, WANG Y H, TANG T. Catalytic carbonization of polypropylene by the combined catalysis of activated carbon with Ni₂O₃ into carbon nanotubes and its mechanism[J]. Appl Catal A:Gen, 2012,449:112-20. doi: 10.1016/j.apcata.2012.09.028
24. [24]
  LIU X T, SUN H M, WU C F, PATEL D, HUANG J. Thermal chemical conversion of high-density polyethylene for the production of valuable carbon nanotubes using Ni/AAO membrane catalyst[J]. Energy Fuels, 2018,32(4):4511-4520. doi: 10.1021/acs.energyfuels.7b03160
25. [25]
  DANAFAR F, FAKHRU'L-RAZI A, SALLEH M A M, BIAK D R A. Fluidized bed catalytic chemical vapor deposition synthesis of carbon nanotubes-A review[J]. Chem Eng J, 2009,155(1/2):37-48.
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