Citation: YANG Xiao-dong, GUAN Xu, GAO Shan-bin, LU Xue-feng, JIANG Wei, SUN Fa-min. Effect of support properties on the performance of supported Pd catalysts in hydrodesulfurization[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(8): 980-985. shu

Effect of support properties on the performance of supported Pd catalysts in hydrodesulfurization

Petrochemical Research Institute, CNPC, Daqing 163714, China

Corresponding author: YANG Xiao-dong, xiaodongyang1983@126.com
Received Date: 6 April 2017
Revised Date: 27 May 2017

Fund Project: the China National Petroleum Corporation Fund 2014B-2508the China National Petroleum Corporation Fund 2013E-1502The project was supported by the China National Petroleum Corporation Fund (2013E-1502, 2014B-2508)

Figures(3)

SiO₂, siliceous MCM-41 (Si-MCM-41), physical mixture of Si-MCM-41 and ZSM-5 (Z-MCM-41-M), and Z-MCM-41 composite obtained by coating MCM-41 on ZSM-5 zeolite particles were prepared and characterized by XRD, HRTEM, N₂ adsorption-desorption and NH₃-TPD. The performances of the supported Pd catalysts in hydrodesulfurization (HDS) were evaluated in a fixed-bed reactor with dibenzothiophene (DBT) as the model sulfur-containing molecule; the effect of support properties on the performance of supported Pd catalysts in HDS was then investigated. The results indicated that the performance in HDS of supported Pd catalysts are significantly influenced by the support properties. Although the specific surface has a minor influence on the HDS activity of the supported Pd catalysts, the hydrogenation (HYD) selectivity is probably related to the pore structure of support; the mesoporous structure is beneficial to the improvement of HYD selectivity. The acid supports can give the Pd catalysts higher HDS activity, owing to the hydrogen spillover effect. The Z-MCM-41 composite is an excellent support for noble metal Pd catalyst in HDS, which can be ascribed to the synergy of the mesoporous structure of MCM-41 and acidic properties of ZSM-5.
- MCM-41,
- ZSM-5,
- composite zeolite,
- Pd,
- hydrodesulfurization
1. [1]
  SONG C S. An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel[J]. Catal Today, 2003,86:211-263. doi: 10.1016/S0920-5861(03)00412-7
2. [2]
  SHYAMAL K B, MAITY S K, TURAGA U T. Search for an Efficient 4, 6-DMDBT Hydrodesulfurization Catalyst: A Review of Recent Studies[J]. Energ Fuel, 2004,18(5):1227-1237. doi: 10.1021/ef030179+
3. [3]
  KUNISADA N, CHOI K H, KORAI Y, MOCHIDA I, NAKANO K. Novel zeolite based support for NiMo sulfide in deep HDS of gas oil[J]. Appl Catal A, 2004,269:43-51. doi: 10.1016/j.apcata.2004.03.051
4. [4]
  NIQUILLE-RÖTHLISBERGER A, PRINS R. Hydrodesulfurization of 4, 6-dimethyldibenzothiophene and dibenzothiophene over alumina-supported Pt, Pd, and Pt-Pd catalysts[J]. J Catal, 2006,242(1):207-216. doi: 10.1016/j.jcat.2006.06.009
5. [5]
  SUN Y Y, PRINS R. Hydrodesulfurization of 4, 6-Dimethyldibenzothiophene over Noble Metals Supported on Mesoporous Zeolites[J]. Angew Chem Int Edit, 2008,47:8478-8481. doi: 10.1002/anie.v47:44
6. [6]
  STAKHEEV A Y, KUSTOV L M. Effects of the support on the morphology and electronic properties of supported metal cluster: modern concepts and progress in 1990s[J]. Appl Catal A, 1999,188(1/2):3-35.
7. [7]
  YANG Xiao-dong. Hydrodesulfurization Performance of Pt or Pd Catalysts Supported on Mesoporous Molecule Sieves[D]. Liaoning: Dalian University of Technology, 2009.
8. [8]
  WANG A J, RUAN L F, TENG Y, LI X, LU M H, REN J, WANG Y, HU Y K. Hydrodesulfurization of dibenzothiophene over siliceous MCM-41 supported nickel phosphide catalysts[J]. J Catal, 2005,229(2):314-321. doi: 10.1016/j.jcat.2004.09.022
9. [9]
  WANG A J, WANG Y, KABE T, CHEN Y Y, ISHHARA A, QIAN W H. Hydrodesulfurization of dibenzothiophene over siliceous MCM-41-supported catalysts I Sulfided Co-Mo catalysts[J]. J Catal, 2001,199(1):19-29. doi: 10.1006/jcat.2000.3148
10. [10]
  WANG A J, WANG Y, KABE T, CHEN Y Y, ISHHARA A, QIAN W H. Hydrodesulfurization of dibenzothiophene over siliceous MCM-41-supported catalysts Ⅱ Sulfided Ni-Mo catalysts[J]. J Catal, 2002,210(2):319-327. doi: 10.1006/jcat.2002.3674
11. [11]
  BAI X L, SACHTLER W M H. Methylcyclopentane conversion catalysis by zeolite encaged palladium clusters and palladium-proton adducts[J]. J Catal, 1991,129(1):121-129. doi: 10.1016/0021-9517(91)90016-W
12. [12]
  SACHTLER W M H. Metal clusters in zeolites: an intriguing class of catalysts[J]. Acc Chem Res, 1993,26(7):383-387. doi: 10.1021/ar00031a005
13. [13]
  KLOETSTRA K R, ZANDBERGEN H W, JANSEN J C, BEKKUM H V. Overgrowth of mesoporous MCM-41 on faujasite[J]. Micro Mater, 1996,6(5/6):287-293.
14. [14]
  HARTMANN M. Hierarchical Zeolites: A Proven Strategy to Combine Shape Selectivity with Efficient Mass Transport[J]. Angew Chem Int Edit, 2004,43(44):5880-5582. doi: 10.1002/(ISSN)1521-3773
15. [15]
  FANG Y M, HU H Q. An ordered mesoporous aluminosilicate with completely crystalline zeolite wall structure[J]. J Am Chem Soc, 2006,128(33):10636-10637. doi: 10.1021/ja061182l
16. [16]
  WANG Lin-ying, WANG An-jie, LI Xiang, ZHOU Feng, HU Yong-kang. Preparation of Pd and Pt Hydrodesulfurization Catalysts Supported on ZSM-5/MCM-41[J]. Acta Petrolei Sinica, 2012,28(3):380-387.
17. [17]
  WANG A J, KABE T. Fine-tuning of pore size of MCM-41 by adjusting the initial pH of the synthesis mixture[J]. Chem Comm, 1999:2067-2068.
18. [18]
  REN J, WANG A J, LI X, HU Y Y. Hydrodesulfurization of dibenzothiophene catalyzed by Ni-Mo sulfides supported on a mixture of MCM-41 and HY zeolite[J]. Appl Catal A, 2008,344(1/2):175-182.
19. [19]
  CORMA, MARTÍNEZ, MARTÍNEZ-SORIAV. Hydrogenation of Aromatics in Diesel Fuels on Pt/MCM-41 Catalysts[J]. J Catal, 1997,169(2):480-489. doi: 10.1006/jcat.1997.1737
20. [20]
  WANG J, HUANG L M, LI Q Z. Influence of different diluents in Pt/Al₂O₃ catalyst on the hydrogenation of benzene, toluene and o-xylene[J]. Appl Catal A, 1998,175(1/2):191-199.
21. [21]
  WANG J, LI Q Z, YAO J D. The effect of metal-acid balance in Pt-loading dealuminated Y zeolite catalysts on the hydrogenation of benzene[J]. Appl Catal A, 1999,184(2):181-188. doi: 10.1016/S0926-860X(98)00369-X
22. [22]
  MENDES P S F, GREGÓRIO A F C, DAUDIN A, BOUCHY C, SILVA J M, RIBEIRO M F. Elucidation of the zeolite role on the hydrogenating activity of Pt-catalysts[J]. Catal Comm, 2017,89152. doi: 10.1016/j.catcom.2016.11.006
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