Citation: Li Xiaochen, Cao Jing. Interfacial Modification by Porphyrin/Phthalocyanine Complexes for Perovskite Solar Cells[J]. Chemistry, ;2020, 83(11): 962-969. shu

Interfacial Modification by Porphyrin/Phthalocyanine Complexes for Perovskite Solar Cells

Li Xiaochen ,
Cao Jing ^,

State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000

Corresponding author: Cao Jing, caoj@lzu.edu.cn
Received Date: 16 June 2020
Accepted Date: 10 August 2020

Figures(5)

In order to solve the problems of energy shortage and environmental pollution, the research of solar cells has attracted extensive scientific attention. Over the past decade, perovskite solar cells (PSCs) have been developing rapidly, gradually becoming one of the most powerful competitors for commercial silicon-based solar cells. However, the inevitable formation of inherent crystallographic defects during the low-temperature solution process severely limits the improvement of the efficiency and stability of PSCs. Porphyrin/phthalocyanine metal complexes with the excellent stability and photovoltaic properties have been considered for improving the efficiency and long-term stability of cells by using porphyrin/phthalocyanine complexes to passivate defects on the surface and grain boundaries of perovskite films. In this review, we summarize the research progress of highly efficient and stable perovskite solar cells using porphyrin/phthalocyanine metal complexes to modify the perovskite films. Meanwhile, the existent problem and future development of PSCs with porphyrin/phthalocyanine complexes are discussed as well.
- Porphyrin/phthalocyanine metal complexes,
- Interfacial modification,
- Perovskite solar cells
1. [1]
  https://www.nrel.gov/pv/assets/pdfs/best-research-cell-efficiencies.20200630.pdf(accessed: June 2020).
2. [2]
  Tan H R, Jain A, Voznyy O, et al. Science, 2017, 33(6326): 722~726.
3. [3]
  Jena A K, Kulkarni A, Miyasaka T. Chem. Rev., 2019, 119(5): 3036~3103.
4. [4]
  Wang L G, Zhou H P, Hu J N, et al. Science, 2019, 363(6424): 265~270.
5. [5]
  Gao Y, Shi E, Deng S, et al. Nat. Chem., 2019, 11(12): 1151~1157.
6. [6]
  Wang Y, Dar M I, Ono L K, et al. Science, 2019, 365(6453): 591~595.
7. [7]
  Wang Z, Shi Z J, Li T T, et al. Angew. Chem. Int. Ed., 2017, 56(5): 1190~1212.
8. [8]
  Wang K, Subhani W S, Wang Y, et al. Adv. Mater., 2019, 31(50): 1902037.
9. [9]
  Ye F, Zhang H, Wang P, et al. ACS Appl. Mater. Interf., 2019, 11(46): 43452~43459.
10. [10]
  Zhang F, Bi D, Pellet N, et al. Energy Environ. Sci., 2018, 11(12): 3480~3490.
11. [11]
  Jung M, Ji S-G, Kim G, et al. Chem. Soc. Rev., 2019, 48(7): 2011~2038.
12. [12]
  Dagar J, Castro-Hermosa S, Gasbarri M, et al. Nano Res., 2018, 11(5): 2669~2681.
13. [13]
  Liu D, Zhou W, Tang H, et al. Sci. China Chem., 2018, 61(10): 1278~1284.
14. [14]
  Chen W, Zhou Y, Chen G, et al. Adv. Energy Mater., 2019, 9(19): 1803872.
15. [15]
  Saliba M, Correa-Baena J-P, Wolff C M, et al. Chem. Mater., 2018, 30(13): 4193~4201.
16. [16]
  Liu Z, Krückemeier L, Krogmeier B, et al. ACS Energy Lett., 2019, 4(1): 110~117.
17. [17]
  Lee J W, Lee D K, Jeong D N, et al. Adv. Funct. Mater., 2018, 29(47): 1807047.
18. [18]
  Shi D, Adinolfi V, Comin R, et al. Science, 2015, 347(6221): 519~522.
19. [19]
  Ran C, Xu J, Gao W, et al. Chem. Soc. Rev., 2018, 47(12): 4581~4610.
20. [20]
  Zheng X, Deng Y, Chen B, et al. Adv. Mater., 2018, 30(52): 1803428.
21. [21]
  Chen Y, Li N, Wang L, et al. Nat. Commun., 2019, 10(1): 1112.
22. [22]
  Meggiolaro D, Motti S G, Mosconi E, et al. Energy Environ. Sci., 2018, 11(3): 702~713.
23. [23]
  Nie R, Mehta A, Park B W, et al. J. Am. Chem. Soc., 2018, 140(3): 872~875.
24. [24]
  Li X, Chen C C, Cai M, et al. Adv. Energy Mater., 2018, 8(20): 1800715.
25. [25]
  Xu J, Buin A, Ip A H, et al. Nat. Commun., 2015, 6(1): 7081.
26. [26]
  Huang Z, Proppe A H, Tan H, et al. ACS Energy Lett., 2019, 4(7): 1521~1527.
27. [27]
  Liu S, Guan Y, Sheng Y, et al. Adv. Energy Mater., 2020, 10(13): 1902492.
28. [28]
  Rajagopal A, Yao K, Jen A K, et al. Adv. Mater., 2018, 30(32): 1800455.
29. [29]
  Yang S, Dai J, Yu Z, et al. J. Am. Chem. Soc., 2019, 141(14): 5781~5787.
30. [30]
  Meng L, Sun C, Wang R, et al. J. Am. Chem. Soc., 2018, 140(49): 17255~17262.
31. [31]
  Zheng X, Chen B, Dai J, et al. Nat. Energy, 2017, 2(7): 17102.
32. [32]
  Saidaminov M I, Kim J, Jain A, et al. Nat. Energy, 2018, 3(8): 648~654.
33. [33]
  Su G X, Li Q Z, Ishida M, et al. Angew. Chem. Int. Ed., 2020, 59(4): 1537~1541.
34. [34]
  Li Q Z, Li C J, Kim J, et al. J. Am. Chem. Soc., 2019, 141(13): 5294~5302.
35. [35]
  Zeng K W, Tong Z F, Ma L, et al. Energy Environ. Sci., 2020, 13(6): 1617~1657.
36. [36]
  Kurumisawa Y, Higashino T, Nimura S, et al. J. Am. Chem. Soc., 2019, 141(25): 9910~9919.
37. [37]
  Zeng K W, Chen Y Y, Zhu W H, et al. J. Am. Chem. Soc., 2020, 142(11): 5154~5161.
38. [38]
  Urbani M, de la Torre G, Nazeeruddin M K, et al. Chem. Soc. Rev., 2019, 48(10): 2738~2766.
39. [39]
  Li C L, He R Q, Liang Q, et al. Sci. China Chem., 2020, 10.1007/s11426-020-9725-3.
40. [40]
  Wygant B R, Ye A Z, Dolocan A, et al. J. Am. Chem. Soc., 2019, 141(45): 18170~18181.
41. [41]
  Zhang F, Kim D H, Lu H, et al. J. Am. Chem. Soc., 2019, 141(14): 5972~5979.
42. [42]
  Feng X X, Chen R H, Nan Z A, et al. Adv. Sci., 2019, 6(5): 1802040.
43. [43]
  Zhou Y, Zhong H, Han J H, et al. J. Mater. Chem. A, 2019, 7(46): 26334~26341.
44. [44]
  Wang P, Wu Y, Cai B, et al. Adv. Funct. Mater., 2019, 29(47): 1807661.
45. [45]
  Wu W Q, Yang Z, Rudd P N, et al. Sci. Adv., 2019, 5(3): eaav8925.
46. [46]
  Li C P, Yin J, Chen R H, et al. J. Am. Chem. Soc., 2019, 141(15): 6345~6351.
47. [47]
  Li X C, Li C L, Wu Y Y, et al. Sci. China Chem., 2020, 10.1007/s11426-020-9710-7.
48. [48]
  Gao K, Zhu Z, Xu B, et al. Adv. Mater., 2017, 29(47): 1703980.
49. [49]
  Balis N, Verykios A, Soultati A, et al. ACS Appl. Energy Mater., 2018, 1(7): 3216~3229.
50. [50]
  Li B, Zheng C Y, Liu H, et al. ACS Appl. Mater. Interf., 2016, 8(41): 27438~27443.
51. [51]
  Xiao G B, Yu Z F, Cao J, et al. CCS Chem., 2020, 2: 488~494.
52. [52]
  Gao Y, Wu Y, Lu H, et al. Nano Energy, 2019, 59: 517~526.
53. [53]
  Zheng X, Troughton J, Gasparini N, et al. Joule, 2019, 3(8): 1963~1976.
54. [54]
  Feng X X, Lv X D, Liang Q, et al. ACS Appl. Mater. Interf., 2020, 12(14): 16236~16242.
55. [55]
  Liu Y, Qi J, Peng X, et al. Org. Electron., 2018, 59: 414~418.
56. [56]
  Wu S F, Liu Q W, Zheng Y, et al. J. Power Sources, 2017, 359: 303~310.
57. [57]
  Suzuki A, Hayashi Y, Yamasaki Y, et al. AIP Conf. Proc., 2019, 2067(1): 020010.
58. [58]
  Suzuki A, Okumura H, Yamasaki Y, et al. Appl. Surf. Sci., 2019, 488: 586~592.
59. [59]
  Cao J, Li C P, Lv X D, et al. J. Am. Chem. Soc., 2018, 140(37): 11577~11580.
60. [60]
  Li C P, Lv X D, Cao J, et al. Chin. J. Chem., 2018, 37(1): 30~34.
61. [61]
  Xie C, Zhou C, Bin Y, et al. Appl. Phys. Express, 2019, 12(6): 064006.
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