Citation: ZHANG Huan-ling, WANG Guo-wei, SHAN Hong-hong, LI Chun-yi. Propane dehydrogenation over NiSn-based catalysts[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(12): 1529-1536. shu

Propane dehydrogenation over NiSn-based catalysts

State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266580, China

Corresponding author: WANG Guo-wei, wangguowei@upc.edu.cn
Received Date: 7 July 2017
Revised Date: 30 September 2017

Fund Project: The project was supported by the National Natural Science Foundation of China(21606257, U1362201)the National Natural Science Foundation of China 21606257the National Natural Science Foundation of China U1362201

Figures(7)

In this paper, we studied the effects of supports, such as SiO₂, MgO, Al₂O₃ and MgAl₂O₄, on the performance of supported NiSn catalyst for propane dehydrogenation. NH₃ temperature-programmed desorption, H₂ temperature-programmed reduction were applied for the characterization of the catalysts. The results show that SiO₂ with large specific surface area and large pore size can achieve good contact between catalyst and reactants, leading to a high content of Ni_2.67Sn₂ alloy and a reduced diffusion resistance, In addition, their weak acid improve dehydrogenation activity and propene selectivity.
- propane dehydrogenation,
- NiSn-based catalysts,
- support
1. [1]
  SHEN Ju-hua. Development of propene production at home and abroad[J]. Chem Technol Market, 2005,28(11):15-19.
2. [2]
  ZHANG Y W, ZHOU Y M, SHI J J, ZHOU S J, ZHANG Z W, ZHANG S C, GUO M G. Propane dehydrogenation over PtSnNa/La-doped Al₂O₃ catalyst: Effect of La content[J]. Fuel Process Technol, 2013,111(3):94-104.
3. [3]
  ZANGENEH F T, SAHEBDELFAR S, BAHMANI M. Propane dehydrogenation over a commercial Pt-Sn/A1₂O₃ catalyst for isobutane dehydrogenation: Optimization of reaction conditions[J]. Chin J Chem Eng, 2013,21(7):730-735. doi: 10.1016/S1004-9541(13)60537-6
4. [4]
  CHEN M, XU J, CAO Y, HE H Y, FAN K N, ZHUANG J H. Dehydrogenation of propane over In₂O₃-Al₂O₃ mixed oxide in the presence of carbon dioxide[J]. J Catal, 2010,272(1):101-108. doi: 10.1016/j.jcat.2010.03.007
5. [5]
  BAI L Y, ZHOU Y M, ZHANG Y W, LIU H, SHENG X L, XUE M W. Influence of the competitive adsorbates on the catalytic properties of PtSnNaMg/ZSM-5 catalysts for propane dehydrogenation[J]. Ind Eng Chem Res, 2011,50(8):4345-4350. doi: 10.1021/ie1018639
6. [6]
  CHEN Jian-jiu, SHI Hai-ying, WANG Yong. Propane dehydrogenation process technology[J]. Prog Fine Petrochem, 2000,1(12):23-28. doi: 10.3969/j.issn.1009-8348.2000.12.007
7. [7]
  SAHEBDELFAR S, RAVANCHI M T, ZANGENEH F T, MEHRAZMA S, RAJABI S. Kinetic study of propane dehydrogenation and side reactions over Pt-Sn/Al₂O₃ catalyst[J]. Chem Eng Res Des, 2012,90(8):1090-1097. doi: 10.1016/j.cherd.2011.11.004
8. [8]
  ZHOU Hong-zhong. Current situation and development trend of propene market at home and abroad[J]. Chem Technol Eco, 2004,22(9):28-31.
9. [9]
  ZHANG Yi-wei, ZHOU Yu-ming, QIU An-ding, WANG Yu, XU Yi, WU Pei-cheng. The effects of Na on the performance of PtSn/ZSM-5 catalyzed propane dehydrogenation[J]. Acta Phys-Chim Sin, 2006,22(6):672-678.
10. [10]
  MA Yan-ping, YANG Ru-xin, ZHAO Yan. Propane catalytic dehydrogenation production technology and industrial application[J]. Guangdong Chem Ind, 2012,39(7):87-87.
11. [11]
  WANG Hong-qiu, ZHENG Yi-dan. Advances in propane dehydrogenation to produce propene[J]. Petrochem Technol, 2011,8(2):63-66.
12. [12]
  ZHU Yi-cai. Technical economic analysis of propane dehydrogenation[J]. Petroleum Petrochem Today, 2012,20(8):36-42.
13. [13]
  GAI Xi-kun, TIAN Yuan-yu, XIA Dao-hong. Analysis of propane catalytic dehydrogenation to propene[J]. Pet Refin Eng, 2010,40(12):27-32. doi: 10.3969/j.issn.1002-106X.2010.12.007
14. [14]
  GORRIZ O F, CADUS L E. Supported chromium oxide calatysts using metal carboxylate complexes: dehydrogenation of propane[J]. Appl Catal A: Gen, 1999,180(1/2):247-260.
15. [15]
  CIMINO A, CORDISHI D, DE ROSSI S, FERRARIS G, GAZZOLI D, INDOVINA V, VALIGI M. Studies on chromia zirconia catalysts Ⅲ. Propene hydrogenation[J]. J Catal, 1991,127(2):777-787. doi: 10.1016/0021-9517(91)90198-D
16. [16]
  TAN Xiao-lin, MA Bo, ZHANG Xi-wen, ZHANG Hai-juan, LI Jiang-hong. Research progress of Cr-based propane dehydrogenation catalyst[J]. Prog Chem, 2000,29(1):51-57.
17. [17]
  QIU An-ding, FAN Yi-ning. Effect of adding tin component on propane dehydrogenation of Pt/ZSM-5 catalyst[J]. J Fuel Chem Technol, 2008,36(5):637-640.
18. [18]
  DONG Wen-sheng, WANG Xin-kui, PENG Shao-yi. Effect of Ca on structure and propane dehydrogenation of PtSn/MgAl₂O₄[J]. J Mol Catal, 1998,12(3):183-188.
19. [19]
  SUN Yi-fei, LI Guang-chao, PAN Xin-di, HUANG Chuan-jing, WENG Wei-zheng, WAN Hui-lin. Oxidative dehydrogenation of propane to propene on Ni-Co oxide catalyst supported on mesoporous alumina[J]. Acta Phys-Chim Sin, 2012,28(9):2135-2140.
20. [20]
  XU Ai-jiu, LIN Qin, ZHAO Ri-ge-tu, ZHANG Yu. Propane dehydrogenation of NiO/blast furnace slag catalyst[J]. Rare Metal Mater Eng, 2009,45(s1):99-102.
21. [21]
  LIANG Xu, LIU Yan-xia, JIANG Yuan-li, WEI Ling-chao. Preparation and characterization of silicon modified alumina and nickel base catalystⅡ[J]. Ind Catal, 2016,24(9):41-44.
22. [22]
  WANG G W, LI C Y, SHAN H H. Highly efficient metal sulfide catalysts for selective dehydrogenation of isobutane to isobutene[J]. ACS Catal, 2014,4(4):1139-1143. doi: 10.1021/cs5000944
23. [23]
  WANG G W, MENG Z, LIU J W, LI C Y, SHAN H H. Promoting effect of sulfur addition on the catalytic performance of Ni/MgAl₂O₄ catalysts for isobutane dehydrogenation[J]. ACS Catal, 2013,3(12):2992-3001. doi: 10.1021/cs400705p
24. [24]
  WANG G W, WANG H R, ZHANG H L, ZHU Q Q, LI C Y, SHAN H H. Highly selective and stable NiSn/SiO₂ catalyst for isobutane dehydrogenation: Effects of Sn addition[J]. ChemCatChem, 2016,8(19):3137-3145. doi: 10.1002/cctc.v8.19
25. [25]
  MIAO Jian-wen, SONG Guo-hua, FAN Yi-ning. Oxidative dehydrogenation of propane oxidation catalyzed by silica supported vanadium oxide with different channel structure[J]. Chin J Catal, 2009,30(11):1143-1149. doi: 10.3321/j.issn:0253-9837.2009.11.013
26. [26]
  ZHANG Y W, ZHOU Y M, SHI J J, ZHOU S J, SHENG X L, ZHANG Z W, XIANG S M. Comparative study of bimetallic Pt-Sn catalysts supported on different supports for propane dehydrogenation[J]. J Mol Catal A: Chem, 2014,381(1):138-147.
27. [27]
  HE S B, SUN C H, DU H H, BAI X H, WANG B. Effect of carbon addition on the Pt-Sn/γ-Al₂O₃ catalyst for long chain paraffin dehydrogenation to olefin[J]. Chem Eng J, 2008,141(1):284-289.
28. [28]
  LAI Y L, HE S B, LI X R, SUN C L, SEAHAN K. Dehydrogenation of n-dodecane over Pt-Sn/Mg-Al-O catalysts: Investigating the catalyst performance while monitoring the products[J]. Appl Catal A: Gen, 2014,469(17):74-80.
29. [29]
  HE S B, SUN C L, YANG X, WANG B, BAI X H, BAI Z W. Characterization of coke deposited on spent catalysts for long-chain-paraffin dehydrogenation[J]. Chem Eng J, 2010,163(3):389-394. doi: 10.1016/j.cej.2010.07.024
30. [30]
  BRUSCHI L, MISTURE G. Adsorption within and on regularly patterned substrates[J]. J Low Temp Phys, 2009,157(3-4):206-220. doi: 10.1007/s10909-009-9913-z
31. [31]
  MISTURE G, BRUSCHI L, LEE W. Adsorption on highly ordered porous alumina[J]. J Low Temp Phys, 2016,185(1-2):138-160. doi: 10.1007/s10909-016-1619-4
32. [32]
  LI X, MENG F H, CHENG Y, GAO Y, LI Z. Catalytic methanation in a slurry-bed reactor over Ni/SiO₂ catalysts: Improvement by ZrO₂ and β-cyclodextrin addition[J]. React Kinet Mech Catal, 2017,122(1):525-538. doi: 10.1007/s11144-017-1213-z
33. [33]
  WANG H R, WANG H, LI L Y, LI C Y. Nature of active tin species and promoting effect of nickle in silica supported tin oxide for dehydrogenation of propane[J]. Appl Surf Sc, 2017,407:456-452. doi: 10.1016/j.apsusc.2017.02.216
34. [34]
  QIU An-ding, LI En-xia, FAN Yi-ning. Effect of carrier composition on dehydrogenation of propane over supported PtSn/ZSM-5 catalysts[J]. Chin J Catal, 2007,28(11):970-974. doi: 10.3321/j.issn:0253-9837.2007.11.009
35. [35]
  BALLARINI A D, ZGOLICZ P, VILELLA I M J, MIGUEL S R D, CASTRO A A, SCELZA O A. n-Butane dehydrogenation on Pt, PtSn and PtGe supported on γ-Al₂O₃ deposited on spheres of α-Al₂O₃ by washcoating[J]. Appl Catal A: Gen, 2010,381(1-2):83-91. doi: 10.1016/j.apcata.2010.03.053
36. [36]
  XU Jun-ke, LI Zhao-jing, WANG Ji-hui, ZHOU Wei, MA Jian-xin. Characterization and analysis of carbon deposition on the surface of Ni/Al₂O₃ by methane dry reforming catalyst[J]. Acta Phys-Chim Sin, 2009,25(2):253-260.
37. [37]
  KOBAYASHI Y, HORIGUCHI J, KOBAYASHI S, YAMAZAKI Y, OMATA K, NAGAO D, KONNO M, YAMADA M. Effect of NiO content in mesoporous NiO-Al₂O₃ catalysts for high pressure partial oxidation of methane to synga[J]. Appl Catal A: Gen, 2011,395(1-2):129-137. doi: 10.1016/j.apcata.2011.01.034
38. [38]
  DONG Wen-sheng, WANG Xin-kui, WANG Hao-jing, PENG Shao-yi. The study of TPR and H₂-TPD over Pt-Sn/MgAl₂O₄catalyst[J]. Chin J Catal, 1999,20(5):577-580.
39. [39]
  ZHENG Liang-ke, XU Cheng-hua, LIU Jian-ying, LIU Sheng-yu. Catalytic hydrogenation of furfural to liquid phase by catalytic Cu-Ni catalyst based on hydrotalcite-like precursor[J]. Fine Catal, 2010,27(11):1078-1085.
40. [40]
  YANG Ya-xian, QIN Da-wei, XIE Hui. Study on preparation of syngas from methane reforming with MgO modified Ni/γ-Al₂O₃ catalyst[J]. Nat Gas Chem Ind, 2012,37(6):40-43.
41. [41]
  SUN Meng, YANG Qi, LU Wen, FAN Zhe-yong, FEI Jin-hua, ZHENG Xiao-ming, WHEELOCK T D. Effect of calcination temperature on the structure of Ni/MgO catalyst and its effect on the performance of catalyst in toluene reforming of toluene[J]. Chin J Catal, 2012,33(9):1508-1516.
42. [42]
  KUMAR M, ABERUAGBA F, GUPTA J K, RAWAT K S, SHARMA L D, MURALI DHARA G. Temperature-programmed reduction and acidic properties of molybdenum supported on MgO-Al₂O₃ and their correlation with catalytic activity[J]. J Mol Catal A: Chem, 2004,213(2):217-223. doi: 10.1016/j.molcata.2003.12.005
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . Research Progress on Carbon-based Catalysts for Catalytic Dehydrogenation of Liquid Organic Hydrogen Carriers. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-0. doi: 10.1016/j.actphy.2024.100044
3. [3]
  Lele Feng , Xueying Bai , Jifeng Pang , Hongchen Cao , Xiaoyan Liu , Wenhao Luo , Xiaofeng Yang , Pengfei Wu , Mingyuan Zheng . Single-atom Pd boosted Cu catalysts for ethanol dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(9): 100100-0. doi: 10.1016/j.actphy.2025.100100
4. [4]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 2406012-0. doi: 10.3866/PKU.WHXB202406012
5. [5]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Liu Fei . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 2408004-0. doi: 10.3866/PKU.WHXB202408004
6. [6]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
7. [7]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
8. [8]
  Xinghai Liu , Hongke Wu . Exploration and Practice of Ideological and Political Education in Heterocyclic Chemistry Based on "Fentanyl" Event. University Chemistry, 2024, 39(8): 359-364. doi: 10.3866/PKU.DXHX202312100
9. [9]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
10. [10]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
11. [11]
  Xueting Feng , Ziang Shang , Rong Qin , Yunhu Han . Advances in Single-Atom Catalysts for Electrocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2305005-0. doi: 10.3866/PKU.WHXB202305005
12. [12]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
13. [13]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048
14. [14]
  Huiwei Ding , Bo Peng , Zhihao Wang , Qiaofeng Han . Advances in Metal or Nonmetal Modification of Bismuth-Based Photocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2305048-0. doi: 10.3866/PKU.WHXB202305048
15. [15]
  Yushan Cai , Fang-Xing Xiao . Revisiting MXenes-based Photocatalysis Landscape: Progress, Challenges, and Future Perspectives. Acta Physico-Chimica Sinica, 2024, 40(8): 2306048-0. doi: 10.3866/PKU.WHXB202306048
16. [16]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-0. doi: 10.3866/PKU.WHXB202312024
17. [17]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016
18. [18]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
19. [19]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
20. [20]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(2129)
HTML views(884)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142