Citation: Cao Sijia, Chen Fan, Chen Yifa, Wang Bo. Fabrication of Metal-Organic Frameworks into Membranes#[J]. Chemistry, ;2017, 80(1): 3-9. shu

Fabrication of Metal-Organic Frameworks into Membranes#

Cao Sijia ^† ,
Chen Fan ^† ,
Chen Yifa ,
Wang Bo ^*,,

Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology, Beijing, 100081

Corresponding author: Wang Bo, bowang@bit.edu.cn
Received Date: 30 July 2016
Accepted Date: 1 September 2016

Figures(8)

Metal-organic frameworks (MOFs), with well-defined porosity, rich structural diversity and tailable functionality, have drawn a great deal of attention from across the scientific community due to their potential applications in the fields of gas storage, separation, catalysis and chemical sensing, etc. However, MOF crystals are often fragile, insoluble and poor in processability. Commonly processing method is to fabricate MOFs into pellet. Yet the obtained samples can easily break down into tiny particles or fine powders, which might hamper their industrial applications. Herein, we developed four methods (in-situ interweaving, photo-induced postsynthetic polymerization, hot-pressing and electrospinning) to process MOFs into membranes, films and fibers. We further set out to explore their applications in the areas of electrochemistry, separation, detection, safety protection and even the possibility in industrial production.
- Metal-organic-frameworks,
- Processibility,
- Membrane
1. [1]
  H Li, M Eddaoudi, M O'Keeffe et al. Nature, 1999, 402:276-279.
2. [2]
  R Kitaura, S Kitagawa, Y Kubota et al. Science, 2002, 298:2358-2361.
3. [3]
  G Ferey, C Mellot-Draznieks, C Serre et al. Science, 2005, 309:2040-2042.
4. [4]
  S S Y Chui, S M F Lo, J P H Charmant et al. Science, 1999, 283:1148-1150.
5. [5]
  S L Qiu, M Xue, G S Zhu. Chem. Soc. Rev., 2014, 43:6116-6140.
6. [6]
  J R Li, R J Kuppler, H C Zhou. Chem. Soc. Rev., 2009, 38:1477-1504.
7. [7]
  H L Zhou, R B Lin, C T He et al. Nat. Commun., 2013, 4:2534-2541.
8. [8]
  D Y Du, J S Qin, S Li et al. Chem. Soc. Rev., 2014,43:4615-4632.
9. [9]
  G Huang, Q Yang, Q Xu et al. Angew. Chem. Int. Ed., 2016, 55:7379-7383.
10. [10]
  D Tian, Q Chen, Y Li et al. Angew. Chem. Int. Ed., 2014, 53:837-841.
11. [11]
  A U Czaja, N Trukhan, U Müller. Chem. Soc. Rev., 2009, 38:1284-1293.
12. [12]
  K M Choi, H M Jeong, J H Park et al. ACS Nano, 2014, 8:7451-7457.
13. [13]
  L Wang, X Feng, L Ren et al. J. Am. Chem. Soc., 2015, 137:4920-4923.
14. [14]
  Z Weng, Y Su, D W Wang et al. Adv. Energy Mater., 2011, 1:917-922.
15. [15]
  Y Xu, Z Lin, X Huang et al. ACS Nano, 2013, 7:4042-4049.
16. [16]
  X Dong, L Wang, D Wang et al. Langmuir, 2012, 28:293-298.
17. [17]
  X Xiao, X Peng, H Jin et al. Adv. Mater., 2013, 25:5091-5097.
18. [18]
  Y Y Zhang, X Feng, H W Li et al. Angew. Chem. Int. Ed., 2015, 54:4259-4263.
19. [19]
  M Rose, B B hringer, M Jolly et al. Adv. Eng. Mater., 2011, 13:356-360.
20. [20]
  Y Y Zhang, S Yuan, X Feng et al. J. Am. Chem. Soc., 2016, 138:5785-5788.
21. [21]
  Y F Chen, S Q Li, X K Pei. Angew. Chem. Int. Ed., 2016, 55:3419-3423.
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