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Citation: Dong Anjie, Feng Shiyou, Wan Tong, Sun Duoxian, An Yingli. The Particle Size and Morphology Studies of Waterborne Acrylic-Polyurethane Hybrid Microemulsions[J]. Chinese Journal of Applied Chemistry, ;1998, 15(1): 101-103. shu

The Particle Size and Morphology Studies of Waterborne Acrylic-Polyurethane Hybrid Microemulsions

1.
Institute Of Medical and Environmental Friendly Materials, Tianjin University, Tianjin 300072;
2.
The State Key Laboratory of Functional Polymer Materials forAdsorption and Separation, Nankai University, Tianjin 300072

Received Date: 4 June 1997
Revised Date: 3 September 1997

Core/shell type acrylic-polyurethane hybrid microemulsions in which polyurethane as the shell and acrylic polymer as the core were prepared successfully. Different cross-link-ing structures between core and shell can be formed by introducing hydroethyl acrylate and adipoyl dihydrazine at the ends of the polyurethane chains. The photon correlation spec-troscopy studies revealed that the mean particle size of the emulsions were smaller than 200 nm. The particle morphology results revealed the core/shell structure of the uncross-linking type microemulsions and interpenetrating networks of the cross-linking type microemulsions.
- polyurethane,
- microemulsion particle,
- preparation,
- core/shell structure
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