Citation: LIU Yan, ZHU Guo-hua, WU Kui, LI Wen-song, WANG Wei-yan, YANG Yun-quan. Preparation of Al-based layered double hydroxides and corresponding mixed oxides supported Pt catalysts and their performance in the hydrodeoxygenation of p-cresol[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(10): 1193-1201. shu

Preparation of Al-based layered double hydroxides and corresponding mixed oxides supported Pt catalysts and their performance in the hydrodeoxygenation of p-cresol

LIU Yan ^1,2 ,
ZHU Guo-hua ¹ ,
WU Kui ¹ ,
LI Wen-song ¹ ,
WANG Wei-yan ^1,, ,
YANG Yun-quan ^1,,

1.
School of Chemical Engineering, Xiangtan University, Xiangtan 411105, China
2.
School of Chemical and Material Engineering, Huaihua University, Huaihua 418000, China

Corresponding author: WANG Wei-yan, wangweiyan@xtu.edu.cn YANG Yun-quan, yangyunquan@xtu.edu.cn
Received Date: 16 July 2018
Revised Date: 29 August 2018

Fund Project: the National Natural Science Foundation of China 21676225the National Natural Science Foundation of China 21776236Natural Science Foundation of Hunan Province 2018JJ2384The project was supported by the National Natural Science Foundation of China (21776236, 21676225), Natural Science Foundation of Hunan Province (2018JJ2384), the Scientific Research Foundation of Huaihua University (HHUY2017-08) and Collaborative Innovation Centre of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilizationthe Scientific Research Foundation of Huaihua University HHUY2017-08

Figures(7)

Al-based layered double hydroxides and corresponding mixed oxides were prepared and used as the supports for the Pt based catalysts; their catalytic performance in the hydrodeoxygenation (HDO) of p-cresol was then investigated. The results indicate that the catalytic performance of Pt based catalysts is related to the composition and structure of the support; Pt directly supported on the Al-based layered double hydroxides exhibits higher activity in p-cresol HDO than that supported on corresponding mixed oxides. Especially, for the HDO at 275 ℃ and 2 MPa for 1 h, the conversion of p-cresol over Pt-Ni-Al-H is 99.8%, with a selectivity of 1.4% to toluene, whereas the selectivity to toluene over Pt-Zn-Al-H reaches 84.1%. Moreover, the Pt based catalysts are also active for the dehydrogenation of methylcyclohexane to toluene, which can effectively reduce the hydrogen consumption in HDO.
- Pt,
- hydrodeoxygenation,
- p-cresol,
- layered double hydroxide,
- mixed metal oxides,
- dehydrogenation
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