Citation: GUO Shu-peng, WANG Min, WANG Jun-gang, MA Zhong-yi, JIA Li-tao, HOU Bo, LI De-bao. Study on the F-T reaction performance of Co/Al₂O₃-SiO₂ catalyst[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(2): 198-203. shu

Study on the F-T reaction performance of Co/Al₂O₃-SiO₂ catalyst

GUO Shu-peng ^1,2 ,
WANG Min ^1,2 ,
WANG Jun-gang ¹ ,
MA Zhong-yi ^1,, ,
JIA Li-tao ¹ ,
HOU Bo ¹ ,
LI De-bao ^1,,

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: MA Zhong-yi, mazhgyi@sxicc.ac.cn LI De-bao, dbli@sxicc.ac.cn
Received Date: 5 September 2017
Revised Date: 18 December 2017

Fund Project: The project was supported by Shanxi Basic Research Fund (201601D021044, 201701D121037)Shanxi Basic Research Fund 201701D121037Shanxi Basic Research Fund 201601D021044

Figures(4)

The γ-Al₂O₃ modified with different content of SiO₂ by impregnation method was used as supports to prepare Co/Al₂O₃ catalyst.The effects of SiO₂ additives on phase structure of the cobalt-based catalysts, reduction behavior and the influence on the F-T synthesis performance were studied by using N₂ adsorption, XRD, H₂-TPR and XPS characterization methods and activity test.The results showed that with the introduction of SiO₂, the interaction between support and cobalt was effectively weakened, thus the reducibility and catalytic activity of the catalysts were significantly improved.However, when the amount of SiO₂ continued to increase, the reduction degree of the catalyst continued to improve, but the dispersion decreased by 32% at the same time.Compared with unmodified Co/Al₂O₃ catalyst, the activity of the catalyst remained basically unchanged.
- Fischer-Tropsch synthesis,
- SiO₂ modification,
- reducibility
1. [1]
  SUN Yu-han, CHEN Jian-gang, WANG Jun-gang, JIA Li-tao, HOU Bo, LI De-bao, ZHANG Juan. The development of cobalt-based catalysts for fischer-tropsch synthesis[J]. Chin J Catal, 2010,31(8):919-927.
2. [2]
  XING C, YANG G H, WANG D, ZENG C Y, JIN Y Z, YANG R Q, SUEHIRO Y, TSUBAKI N. Controllable encapsulation of cobalt clusters inside carbon nanotubes as effective catalysts for Fischer-Tropsch synthesis[J]. Catal Today, 2013,215:24-28. doi: 10.1016/j.cattod.2013.02.018
3. [3]
  KHODAKOV A Y, CHU W, FONGARLAND P. Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels[J]. Chem Rev, 2007,107(5):1692-1744. doi: 10.1021/cr050972v
4. [4]
  LI Jin-lin, WAN You-jun, ZHANG Yu-hua, XIONG Hai-feng. Studies on the reduction process of the supported cobalt catalysis for Fischer-Tropsch Synthesis[J]. J South-Cent Univ Nat(Nat Sci Ed), 2007,26(2):1-6.
5. [5]
  ZHANG Y H, XIONG H F, LIEW K Y, LI J L. Effect of magnesia on alumina-supported cobalt Fischer-Tropsch synthesis catalysts[J]. J Mol Catal A:Chem, 2005,237(1/2):172-181.
6. [6]
  BAO A, LIEW K Y, LI J L. Fischer-Tropsch synthesis on CaO-promoted Co/Al₂O₃ catalysts[J]. J Mol Catal A:Chem, 2009,304(1/2):47-51.
7. [7]
  LI Jia-bo, LIN Quan. Supporter modification of Fischer-Tropsch cobalt catalyst[J]. Clean Coal Technol, 2015,21(1):65-68.
8. [8]
  PATERMARAKIS G, NICOLOPOULOS N. Catalysis ove porous anodic alumina film catalysts with different pore surface concentrations[J]. J Catal, 1999,187(2):311-320. doi: 10.1006/jcat.1999.2627
9. [9]
  SUN X Y, ZHANG X J, ZHANG Y, TSUBAKI N. Reversible promotional effect of SiO₂ modification to Co/Al₂O₃ catalyst for Fischer-Tropsch synthesis[J]. Appl Cata A:Gen, 2010,377(1/2):134-139.
10. [10]
  ARNOLDY P, MOULIJN J A. Temperature-programmed reductio of CoO/Al₂O₃ catalysts[J]. J Catal, 1985,93(1):38-54. doi: 10.1016/0021-9517(85)90149-6
11. [11]
  KOGELBAUER A, GOODWIN J G, QUKACI R. Ruthenium promotion of Co/Al₂O₃ Fischer-Tropsch catalysts[J]. J Catal, 1996,160(1):125-133. doi: 10.1006/jcat.1996.0130
12. [12]
  FAN L, YOKOTA K, FUJIMOTO K. Supercritical phase Fischer-Tropsch synthesis:Catalyst pore-size effect[J]. AIChE J, 1992,38(10):1639-1648. doi: 10.1002/(ISSN)1547-5905
13. [13]
  SEXTON B A, HUGHES A E, TURNEY T W. An XPS and TPR study of the reduction of promoted cobalt-kieselguhr Fischer-Tropsch catalysts[J]. J Catal, 1986,97(2):390-406. doi: 10.1016/0021-9517(86)90011-4
14. [14]
  GUERRERORUIZ A, SEPULVEDAESCRIBANO A, RODRIGUEZRAMOS I. Carbon monoxide hydrogenation over carbon supported cobalt or ruthenium catalysts:Promoting effects of magnesium, vanadium and cerium oxides[J]. Appl Catal A:Gen, 1994,120(1):71-83. doi: 10.1016/0926-860X(94)80334-X
15. [15]
  GRASS M E, ZHANG Y, BUTCHER D R, PARK J Y, LI Y, BLUHM H, BRATLIE K M, ZHANG T, SOMORJAI G A. A reactive oxide overlayer on rhodium nanoparticles during CO oxidation and its size dependence studied by in situ ambient-pressure X-ray photoelectron spectroscopy[J]. Angew Chem Int Ed Eng, 2008,47(46):8893-8896. doi: 10.1002/anie.v47:46
16. [16]
  PRIETO G, DE M M, CONCEPCION P, MURCIANO R, MURCIANO R, PERGHERS B C, MARTTINEZ A. Cobalt-catalyzed Fischer-Tropsch synthesis:Chemical nature of the oxide support as a performance descriptor[J]. ACS Catal, 2015,5(6):3323-3335. doi: 10.1021/acscatal.5b00057
17. [17]
  BEZEMER G L, BITTER J H, KUIPERS H, OOSTERBEEK H, HOLEWIJN J E, XU X D, KAPTEIJN F, VANDILLEN A J, DEJONG K P. Cobalt particle size effects in the Fischer-Tropsch reaction studied with carbon nanofiber supported catalysts[J]. J Am Chem Soc, 2005,128(6):3956-3964.
18. [18]
  ZHANG Y, KOIKE M, TSUBAKI N. Preparation of alumina-silica bimodal pore catalysts for Fischer-Tropsch synthesis[J]. Catal Lett, 2005,99(3/4):193-198.
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Study on the F-T reaction performance of Co/Al₂O₃-SiO₂ catalyst