Citation: ZHENG Ke, WANG Yong-zhao, HU Xiao-bo, WU Rui-fang, LIU Xiao-li, ZHAO Yong-xiang. Effect of reduction-oxidation pretreatment on the catalytic performance of Co₃O₄ catalyst in N₂O decomposition[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(4): 455-463. shu

Effect of reduction-oxidation pretreatment on the catalytic performance of Co₃O₄ catalyst in N₂O decomposition

ZHENG Ke ^1,2 ,
WANG Yong-zhao ^1,, ,
HU Xiao-bo ^1,2 ,
WU Rui-fang ¹ ,
LIU Xiao-li ^1,2 ,
ZHAO Yong-xiang ¹

1.
Engineering Research Center of Ministry of Education for Fine Chemicals, Taiyuan 030006, China
2.
School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China

Corresponding author: WANG Yong-zhao, catalyst@sxu.edu.cn
Received Date: 21 December 2018
Revised Date: 25 February 2019

Fund Project: the National Natural Science Foundation of China U1710221The project was supported by the National Natural Science Foundation of China (U1710221)

Figures(8)

In this paper, Co₃O₄ catalysts were prepared by the liquid precipitation method, and further was subjected to reduction-oxidation pretreatment to obtain Co₃O₄-RO. The catalysts were characterized by XRD, N₂-physisorption, Raman, H₂-TPR, XPS and O₂-TPD. Their catalytic activities in N₂O decomposition were tested on a fixed-bed continuous flow microreactor. The results show that both the crystallinity and the crystallite size of Co₃O₄-RO decrease in comparison with Co₃O₄. Especially the structural reconstruction resulted from the reduction-oxidation pretreatment weakens the Co-O bond and enhances the oxygen desorption capacity on the catalyst surface, which endows the Co₃O₄-RO a lower activation energy. Thus the catalytic activity of the Co₃O₄-RO in N₂O decomposition increases significantly. At the same time, Co₃O₄-RO shows strong resistance to O₂ (2% in feed)and H₂O (2.3% in feed).
- Co₃O₄,
- reduction-oxidation pretreatment,
- catalytic decomposition of N₂O
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Effect of reduction-oxidation pretreatment on the catalytic performance of Co₃O₄ catalyst in N₂O decomposition