Citation: ZHENG Ke, WANG Yong-zhao, HU Xiao-bo, WU Rui-fang, LIU Xiao-li, ZHAO Yong-xiang. Effect of reduction-oxidation pretreatment on the catalytic performance of Co₃O₄ catalyst in N₂O decomposition[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(4): 455-463. shu

Effect of reduction-oxidation pretreatment on the catalytic performance of Co₃O₄ catalyst in N₂O decomposition

ZHENG Ke ^1,2 ,
WANG Yong-zhao ^1,, ,
HU Xiao-bo ^1,2 ,
WU Rui-fang ¹ ,
LIU Xiao-li ^1,2 ,
ZHAO Yong-xiang ¹

1.
Engineering Research Center of Ministry of Education for Fine Chemicals, Taiyuan 030006, China
2.
School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China

Corresponding author: WANG Yong-zhao, catalyst@sxu.edu.cn
Received Date: 21 December 2018
Revised Date: 25 February 2019

Fund Project: the National Natural Science Foundation of China U1710221The project was supported by the National Natural Science Foundation of China (U1710221)

Figures(8)

In this paper, Co₃O₄ catalysts were prepared by the liquid precipitation method, and further was subjected to reduction-oxidation pretreatment to obtain Co₃O₄-RO. The catalysts were characterized by XRD, N₂-physisorption, Raman, H₂-TPR, XPS and O₂-TPD. Their catalytic activities in N₂O decomposition were tested on a fixed-bed continuous flow microreactor. The results show that both the crystallinity and the crystallite size of Co₃O₄-RO decrease in comparison with Co₃O₄. Especially the structural reconstruction resulted from the reduction-oxidation pretreatment weakens the Co-O bond and enhances the oxygen desorption capacity on the catalyst surface, which endows the Co₃O₄-RO a lower activation energy. Thus the catalytic activity of the Co₃O₄-RO in N₂O decomposition increases significantly. At the same time, Co₃O₄-RO shows strong resistance to O₂ (2% in feed)and H₂O (2.3% in feed).
- Co₃O₄,
- reduction-oxidation pretreatment,
- catalytic decomposition of N₂O
1. [1]
  United Nations Environment Programme. LIU Chong-ye. World Environmental Data Manual[M]. Beijing: China Science and Technology Press, 1990: 19-20.
2. [2]
  XU Xiang-yang, GU Cheng, WANG Hong, ZHANG Yuan-yuan, KE Yan, ZHANG Cheng-le, WANG Ming-jin, SONG Bao-hua, LI Cui-qing. Catalytic performance of Co/Hβ in N₂O decomposition[J]. J Fuel Chem Technol, 2014,42(7):877-883.
3. [3]
  RUSSO N, MESCIA D, FINO D, SARACCO G. N₂O decomposition over perovskite catalysts[J]. Ind Eng Chem Res, 2007,46(12):4226-4231. doi: 10.1021/ie0612008
4. [4]
  HUSSAIN M, PARVEEN A, FINO D, RUSSO N. Modified KIT-6 and SBA-15-spherical supported metal catalysts for N₂O decomposition[J]. J Environ Chem Eng, 2013,1(3):164-174. doi: 10.1016/j.jece.2013.04.013
5. [5]
  HERMES A C, HAMILTON S M, HOPKINS W S, HARDING D J, KERPAL C, MEIJER G, FIELICKE A, MACKENZIE S R. Effects of coadsorbed oxygen on the infrared driven decomposition of N₂O on isolated Rh⁵⁺ clusters[J]. J Phys Chem Lett, 2011,2(24):3053-3057. doi: 10.1021/jz2012963
6. [6]
  ZHU Y Y, WANG X D, WANG A Q, WU G T, WANG J H, ZHANG T. Identification of the chemical state of Fe in barium hexaaluminate using Rietveld refinement and ⁵⁷Fe Mössbauer spectroscopy[J]. J Catal, 2011,283:149-160. doi: 10.1016/j.jcat.2011.08.001
7. [7]
  ZHENG Li, WU Cang-cang, XU Xiu-feng. Catalytic decomposition of N₂O over Mg-Co and Mg-Mn-Co composite oxides[J]. J Fuel Chem Technol, 2016,44(12):1494-1501. doi: 10.3969/j.issn.0253-2409.2016.12.013
8. [8]
  DOU Zhe, ZHANG Hai-jie, PAN Yan-fei, XU Xiu-feng. Catalytic decomposition of N₂O over potassium-modified Cu-Co spinel oxides[J]. J Fuel Chem Technol, 2014,42(2):238-245.
9. [9]
  WANG Y Z, HU X B, ZHENG K, ZHANG H X, ZHAO Y X. Effect of precipitants on the catalytic activity of Co-Ce composite oxide for N₂O catalytic decomposition[J]. React Kinet Mech Catal, 2018,123(2):707-721. doi: 10.1007/s11144-017-1293-9
10. [10]
  ZHANG Y, WANG X D, ZHU Y Y, ZHANG T. Stabilization mechanism and crystallographic sites of Ru in Fe-promoted barium hexaaluminate under high-temperature condition for N₂O decomposition[J]. Appl Catal B:Environ, 2013,129:382-393. doi: 10.1016/j.apcatb.2012.10.001
11. [11]
  WANG Jun-ying, XIA Hai-an, JU Xiao-hua, FAN Feng-tao, FENG Zhao-chi, LI Can. Catalytic performance of different types of iron zeolites in N₂O decomposition[J]. Chin J Catal, 2013,34(5):876-888.
12. [12]
  FRANKEN T, PALKOVITS R. Investigation of potassium doped mixed spinels Cu_xCo_3-xO₄ as catalysts for an efficient N₂O decomposition in real reaction conditions[J]. Appl Catal B:Environ, 2015,176-177:298-305. doi: 10.1016/j.apcatb.2015.04.002
13. [13]
  YAN L, REN T, WANG X L, JI D, SUO J S. Catalytic decomposition of N₂O over M_xCo_1-xCo₂O₄ (M =Ni, Mg) spinel oxides[J]. Appl Catal B:Environ, 2003,45(2):85-90. doi: 10.1016/S0926-3373(03)00174-7
14. [14]
  TAO F F, SHAN J J, NGUYEN L, WANG Z, ZHANG S, ZHANG L, WU Z, HUANG W, ZENG S, HU P. Understanding complete oxidation of methane on spinel oxides at a molecular level[J]. Nat Commun, 2015,6:1-10.
15. [15]
  XIE X W, LI Y, LIU Z Q, HARUTA M, SHWN W J. Low-temperature oxidation of CO catalysed by Co₃O₄ nanorods[J]. Nature, 2009,458(7239):746-749. doi: 10.1038/nature07877
16. [16]
  HOU C P, XIA G F, SUN X, WU Y, JIN C, YAN Z N, LI M F, HU Z H, NIE H, LI D D. Thermodynamics of oxidation of an alumina-supported cobalt catalyst by water in F-T synthesis[J]. Catal Today, 2016,264:91-97. doi: 10.1016/j.cattod.2015.08.042
17. [17]
  KONSOLAKIS M I. Recent advances on nitrous oxide (N₂O) decomposition over non-noble metal oxide catalysts:Catalytic performance, mechanistic considerations and surface chemistry aspects[J]. ACS Catal, 2015,5:6397-6421. doi: 10.1021/acscatal.5b01605
18. [18]
  WANG Y Z, HU X B, ZHENG K, WEI X H, ZHAO Y X. Effect of SnO₂ on the structure and catalytic performance of Co₃O₄ for N₂O decomposition[J]. Catal Commun, 2018,111:70-74. doi: 10.1016/j.catcom.2018.04.004
19. [19]
  YU H B, WANG X P, WU X X, CHEN Y. Promotion of Ag for Co₃O₄ catalyzing N₂O decomposition under simulatedreal reaction conditions[J]. Chem Eng J, 2018,334:800-808. doi: 10.1016/j.cej.2017.10.079
20. [20]
  YU H B, TURSUN M, WANG X P, WU X X. Pb_0.04Co catalyst for N₂O decomposition in presence of impurity gases[J]. Appl Catal B:Environ, 2016,185:110-118. doi: 10.1016/j.apcatb.2015.12.011
21. [21]
  KIM S H, NAM S W, LIM T H, LEE H I. Effect of pretreatment on the activity of Ni catalyst for CO removal reaction by water-gas shift and methanation[J]. Appl Catal B:Environ, 2008,81(1/2):97-104.
22. [22]
  SADYKOV V A, TIKHOV S F, TSYBULYA S V, KRYUKOVA G N, VENIAMINOV S A, KOLOMⅡCHUK V N, BULGAKOV N N, PAUKSHTIS E A, IVANOV V P, KOSHCHEEV S V, ZAIKOVSKⅡ V I, ISUPOVA L A, BURGINA L B. Role of defect structure in structural sensitivity of the oxidation reactions catalyzed by dispersed transition metal oxides[J]. J Mol Catal A:Chem, 2000,158(1):361-365. doi: 10.1016/S1381-1169(00)00105-9
23. [23]
  YU Y B, TAKEI T, OHASHI H, HE H, ZHANG X L, HARUTA M. Pretreatments of Co₃O₄ at moderate temperature for CO oxidation at -80℃[J]. J Catal, 2009,267(2):121-128. doi: 10.1016/j.jcat.2009.08.003
24. [24]
  YANG J, GUO J, WANG Y B. Reduction-oxidation pretreatment enhanced catalytic performance of Co₃O₄/Al₂O₃ over CO oxidation[J]. Appl Surf Sci, 2018,453:330-335. doi: 10.1016/j.apsusc.2018.05.103
25. [25]
  HUSSAIN S T, LARACHI F. Surface modification of supported Ru:Mn/SiO₂ Fischer-Tropsch synthesis catalysts[J]. J Trace Microprobe Tech, 2002,20(2):197-209. doi: 10.1081/TMA-120003724
26. [26]
  CAI J, JIANG F, LIU X H. Exploring pretreatment effects in Co/SiO₂ Fischer-Tropsch catalysts:Different oxidizing gases applied to oxidation-reduction process[J]. Appl Catal B:Environ, 2017,210:1-13. doi: 10.1016/j.apcatb.2017.03.036
27. [27]
  WANG Jun-gang, LI De-bao, HUANG Wei, JIA Li-tao, SUN Zhi-qiang, LIU Bing, SUN Yu-han. Influence of reduction-oxidation pretreatment on the performance of bi-modal structure Co-based catalysts in Fischer-Tropsch synthesis[J]. J Fuel Chem Technol, 2012,40(4):441-446. doi: 10.3969/j.issn.0253-2409.2012.04.010
28. [28]
  SOUZA L K C D, ZAMIAN J R, FILHO G N D R, SOLEDADE L E B, SANTOS I M G D, SOUZA A G, SCHELLER T, ANGELICA R S, COSTA C E F D. Blue pigments based on Co_xZn_1-xAl₂O₄ spinels synthesized by the polymeric precursor method[J]. Dyes Pigm, 2009,81(3):187-192. doi: 10.1016/j.dyepig.2008.09.017
29. [29]
  MAHAMMADUNNISA S K, AKANKSHA T, KRUSHNAMURTY K, SUBRAHMANYAM C H. Catalytic decomposition of N₂O over CeO₂ supported Co₃O₄ catalysts[J]. J Chem Sci, 2016,128(123):1795-1804.
30. [30]
  HOU X D, WANG Y Z, ZHAO Y X. Effect of CeO₂ doping on structure and catalytic performance of Co₃O₄ catalyst for low-temperature CO oxidation[J]. Catal Lett, 2008,123:321-326. doi: 10.1007/s10562-008-9426-4
31. [31]
  DOW W P, WANG Y P, HUANG T J. Yttria-stabilized zirconia supported copper oxide catalyst.1.Effect of oxygen vacancy of support on copper oxide reduction[J]. J Catal, 1996,160(2):155-170. doi: 10.1006/jcat.1996.0135
32. [32]
  XIE P F, LUO Y J, MA Z, WANG L Y, HUANG C Y, YUE Y H, HUA W M, GAO Z. CoZSM-11 catalysts for N₂O decomposition:Effect of preparation methods and nature of active sites[J]. Appl Catal B:Environ, 2015,170-171:34-42. doi: 10.1016/j.apcatb.2015.01.027
33. [33]
  CHEN J, SHI W, LI J. Catalytic combustion of methane over cerium-doped cobalt chromite catalysts[J]. Catal Today, 2011,175(1):216-222. doi: 10.1016/j.cattod.2011.03.061
34. [34]
  LEE Y N, LAGO R M, FIERRO J L G, CORTES V, SAPINA F, MARTINEZ E. Study of ceria-supported nickel catalyst and effect of yttria doping on carbon dioxide reforming of methane[J]. Appl Catal A:Gen, 2001,218(1/2):69-79.
35. [35]
  WANG K, CAO Y L, HU J D, LI Y Z, XIE J, JIA D Z. Solvent-free chemical approach to synthesize various morphological Co₃O₄ for CO oxidation[J]. Acs Appl Mater Inter, 2017,9(19):16128-16137. doi: 10.1021/acsami.7b01142
36. [36]
  XUE L, ZHANG C B, HE H, TERAOKA Y. Catalytic decomposition of N₂O over CeO₂promoted Co₃O₄ spinel catalyst[J]. J Chin Rare Earth Soc, 2006,75(3):167-174.
37. [37]
  HUANG C D, ZHU Y Y, WANG X D, LIU X, WANG J H, ZHANG T. Sn promoted BaFeO_3-δ catalysts for N₂O decomposition:Optimization of Fe active centers[J]. J Catal, 2017,347:9-20. doi: 10.1016/j.jcat.2016.12.020
38. [38]
  IVANOVA Y A, SUTORMINA E F, ISUPOVA I A, VOVK E I. Catalytic activity of the oxide catalysts based on Ni_0.75Co_2.25O₄ modified with cesium cations in a reaction of N₂O decomposition[J]. Kinet Catal, 2017,58(6):793-799. doi: 10.1134/S002315841705007X
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
3. [3]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
4. [4]
  Linping Li , Junhui Su , Yanping Qiu , Yangqin Gao , Ning Li , Lei Ge . Design and fabrication of ternary Au/Co3O4/ZnCdS spherical composite photocatalyst for facilitating efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100472-100472. doi: 10.1016/j.cjsc.2024.100472
5. [5]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-0. doi: 10.3866/PKU.WHXB202408005
6. [6]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
7. [7]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
8. [8]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(Ⅵ) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-0. doi: 10.3866/PKU.WHXB202309020
9. [9]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
10. [10]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
11. [11]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
12. [12]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-0. doi: 10.3866/PKU.WHXB202408002
13. [13]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2024.100332
14. [14]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
15. [15]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
16. [16]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
17. [17]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
18. [18]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C₃N₄ Photocatalyst for Highly-Efficient H₂O₂ Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005
19. [19]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
20. [20]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(1048)
HTML views(139)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of reduction-oxidation pretreatment on the catalytic performance of Co3O4 catalyst in N2O decomposition

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of reduction-oxidation pretreatment on the catalytic performance of Co₃O₄ catalyst in N₂O decomposition