Citation: ZHANG Zhenfeng, HU Xingzhou, YAN Qing. PHOTOINDUCED GRAFTING OF ACRYLIC AND ALLYL MONOMERS ON POLYETHYLENE SURFACE*[J]. Chinese Journal of Polymer Science, ;1995, 13(4): 322-330. shu

PHOTOINDUCED GRAFTING OF ACRYLIC AND ALLYL MONOMERS ON POLYETHYLENE SURFACE*

Received Date: 6 February 1994

Photoinduced grafting of acrylic and allyl monomers on polyethylene surface wasgenerally studied by using benzophenone (BP) as a photoinitiator. The grafting process wascarried out either in vapor-phase or in solution of the monomers. In the vapor-phase reactionwith a filter used to cut off the short wavelength UV light, allyl amine is the most reactive ofthe four monomers used and acrylic amide is comparatively more reactive than acrylic acid andallyl alcohol. Acetone, as a solvent and carrier for initiator and monomers,however,shows its reactivity to participate the reaction.The solution grafting with a filter is much faster than the corresponding vapor-phase reaction,and a fullt covered surface by the grafted polymer can be achieved in this way.
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