Citation: Dai Qiwen, Wang Feng, Wang Jide, Wang Lu. Steam Activation to Activated Carbon and Its Supported Bi-Based Catalyst for Acetylene Hydrochlorination[J]. Chemistry, ;2017, 80(8): 751-759. shu

Steam Activation to Activated Carbon and Its Supported Bi-Based Catalyst for Acetylene Hydrochlorination

Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education v Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi, 830046

Corresponding author: Wang Feng, wangfeng62@126.com
Received Date: 19 February 2017
Accepted Date: 3 April 2017

Figures(10)

Two kinds of activated carbons (ACs) were activated by steam, and a series of Bi/AC catalysts supported on steam-activated ACs were prepared by incipient-wetness impregnation method. Their catalytic performance for acetylene hydrochlorination was investigated. The characterizations of ACs and catalysts were conducted by N₂ adsorption-desorption experiments (BET), scanning electron microscopy (SEM), Fourier transform-infrared spectroscopy (FTIR), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TGA) methods, respectively. The results revealed that: (1) Steam activation reorganized the pore size and channel structure of ACs, especially for the mesoporous AC, whose specific surface area was increased and new micropore structure was formed; (2) Steam activation decreased the amount of coke deposition, which was the decisive factors affecting the catalytic activity, and generated a higher degree of crystallinity and a better dispersity of BiOCl, thus improving the catalytic performance for acetylene hydrochlorination.
- Activated carbon,
- Steam activation,
- Bi based catalyst,
- Acetylene hydrochlorination,
- Pore structure
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