Citation: GONG Ming-yue, LI Xiao-juan, ZHANG Mei, SONG Hua, HE Ying-ming. Preparation of ionic liquid supported metal-organic framework Py/MOF-199 and its adsorption desulfurization performance[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(10): 1175-1183. shu

Preparation of ionic liquid supported metal-organic framework Py/MOF-199 and its adsorption desulfurization performance

GONG Ming-yue ¹ ,
LI Xiao-juan ¹ ,
ZHANG Mei ^1,2 ,
SONG Hua ^1,2,, ,
HE Ying-ming ³

1.
College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
2.
Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China
3.
Research Institute of Exploration and Development of Daqing Oilfield Company Ltd, Daqing 163000, China

Corresponding author: SONG Hua, songhua2004@sina.com
Received Date: 8 May 2018
Revised Date: 2 August 2018

Fund Project: The project was supported by the National Natural Science Foundation of China (21276048), the Natural Science Foundation of Heilongjiang Province of China (ZD201201) and the General Program of Education Department of Heilongjiang Province (12541060)the National Natural Science Foundation of China 21276048the Natural Science Foundation of Heilongjiang Province of China ZD201201the General Program of Education Department of Heilongjiang Province 12541060

Figures(13)

MOF-199(Cu-BTC) was prepared and the ionic liquid supported MOF-199 adsorbents (Py/MOF-199) were successfully obtained via fixing ionic liquid[Hnmp] [H₂PO₄] onto the MOF-199. Adsorbents were characterized via XRD, FT-IR, SEM, and BET methods. The effects of pretreatment conditions of MOF-199, ionic liquid loading method, ionic liquid content, loading temperature and time on adsorptive removal performance of thiophene were studied. The preparation conditions of Py/MOF-199 adsorbent were optimized via orthogonal experiment, and the desulfurization conditions were also optimized. The results show that after the introduction of[Hnmp] [H₂PO₄] the regular octahedron structure of MOF-199 of Py/MOF-199 was maintained unchanged and the average pore diameter was increased. The optimal preparation conditions of Py/MOF-199 adsorbent are pretreating MOF-199 with Soxhlet extraction and drying in vacuum, then loading[Hnmp] [H₂PO₄] using solvothermal method, loading temperature of 50 ℃, loading time of 8 h, ionic liquid content of 7%. The influence of preparation factors on the desulfurization performance of adsorbent is in order:loading temperature > loading time > ionic liquid content. The optimal desulfurization conditions are model oil of 10 mL, Py/MOF-199 dosage of 0.2 g, adsorption under 70 ℃ for 1 h. Under these conditions, the thiophene desulfurization rate over Py/MOF-199 reached 96.7%.
- adsorptive desulfurization,
- ionic liquids,
- Py/MOF-199,
- thiophene (TP)
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