Citation: JIA Yu-jie, JIANG Jian-chun, SUN Kang, CHEN Chao. Oxidation of formic acid over palladium catalyst supported on activated carbon derived from polyaniline and modified lignosulfonate composite[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(1): 100-105. shu

Oxidation of formic acid over palladium catalyst supported on activated carbon derived from polyaniline and modified lignosulfonate composite

Institute of Chemical Industry of Forest Products, CAF; Key Lab of Biomass Energy and Material, Jiangsu Province; National Engineering Lab. for Biomass Chemical Utilization; Key and Open Laboratory of Forest Chemical Engineering, SFA, Nanjing 210042, China

Corresponding author: JIANG Jian-chun, bio_energe@126.com
Received Date: 9 September 2016
Revised Date: 25 October 2016

Fund Project: projects in Forestry Public Benefit Research Sector 201404610

Figures(10)

Activated carbons (AC) were obtained through carbonization of polyaniline and modified lignosulfonate composite (PAn-MLS) under different temperatures; they are characterized by fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, nitrogen sorption and scanning electron microscope (SEM). With these carbon materials as the support, a series of Pd-AC catalysts for the oxidation of formic acid were prepared by liquid phase reduction and characterized by X-ray diffraction (XRD), transmission electron microscope (TEM) and electrochemical analysis. The results show that with the activated carbon prepared at 800℃ (AC800) as the support, the Pd-AC800 catalyst obtained performs best in the oxidation of formic acid; the palladium particles have an average size of 5.4 nm and the electro-active surface area reaches 53.78 m²/g. As the oxidation of formic acid over Pd-AC800 is realized through direct pathway rather than CO pathway, Pd-AC800 may be considered as a potential electrode material in direct formic acid fuel cells (DFAFC).
- polyaniline,
- modified lignosulfonate,
- activated carbon,
- Pd-AC,
- formic acid,
- oxidation,
- direct formic acid fuel cells
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