Citation: TAN Qi-hang, CAO Yang, LI Jin. Preparation and characterization of Mo₂N/Zr-MCM-41 catalyst and its performance in hydrodeoxygenation of Jatropha curcas oil[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(11): 1323-1331. shu

Preparation and characterization of Mo₂N/Zr-MCM-41 catalyst and its performance in hydrodeoxygenation of Jatropha curcas oil

TAN Qi-hang ¹ ,
CAO Yang ^1,2 ,
LI Jin ^1,,

1.
State Key Laboratory of Marine Resource Utilization in South China Sea, College of Materials and Chemical Engineering, Hainan University, Haikou 570228, China
2.
Qiongtai Normal University, Haikou 571127, China

Corresponding author: LI Jin, 316800681@qq.com
Received Date: 17 July 2018
Revised Date: 15 September 2018

Fund Project: the Hainan Provincial Key Projects ZDYF2018134The project was supported by the Hainan Provincial Key Projects (ZDYF2018134)

Figures(5)

MCM-41 and Zr-MCM-41 with different initial n(Si)/n(Zr) ratios were synthesized by hydrothermal method. Mo₂N/Zr-MCM-41 hydrodeoxygenation catalysts were prepared by (NH₄)₆Mo₇O₂₄ carrier co-impregnation, calaination, temperature programing and nitridation, and characterized by XRD, XPS, TEM and Py-FTIR methods. The catalytic performance of Mo₂N/Zr-MCM-41 in hydrodeoxygenation of Jatropha curcas oil was evaluated in a high pressure reactor. The results indicate that Zr modified carrier has the same pore structure as pure silicon MCM-41, and the value of L acid and B acid increases. As the active component, the Mo₂N has an excellent HDO performance. Under the reaction temperature of 350℃ and the hydrogen pressure of 3.0 MPa, the catalyzed product oil is mainly composed of straight chain alkanes and aromatic compounds, accounting for more than 90% of the product components. The deoxygenation rates of the new catalysts with different n(Si)/n(Zr) ratios are all above 98%, and the content of aromatic compounds is higher than that of straight chain alkanes, which accounts for 72.09% of the total composition. The aromatic compounds are mainly single ring and bicyclic aromatic hydrocarbons with the length of carbon chain of C_8-16. After the leprosy oils catalyzed by Mo₂N/Zr-MCM-41 are fractionated, it can be prepared to be biofuels.
- Mo₂N/Zr-MCM-41,
- hydrodeoxygenation,
- Jatropha oil,
- isomerization
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Preparation and characterization of Mo2N/Zr-MCM-41 catalyst and its performance in hydrodeoxygenation of Jatropha curcas oil

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通讯作者: 陈斌, bchen63@163.com

Preparation and characterization of Mo₂N/Zr-MCM-41 catalyst and its performance in hydrodeoxygenation of Jatropha curcas oil