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Citation: Xie Suyuan, Zhang Qiang, Huang Rongbin, Zheng Lansun. Synthesis of Perhalogenated Pyrene by Plasma Reaction[J]. Chinese Journal of Applied Chemistry, ;1998, 15(6): 61-64. shu

Synthesis of Perhalogenated Pyrene by Plasma Reaction

State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen 361005

Received Date: 22 June 1998
Revised Date: 7 October 1998

A series of perhalogenated aromatic compounds were synthesized by arc-discharging of solid polytetrafluoroethylene and glow-discharge of chloroform vapor, respectively. Among the products, perchloropyrene(C₁₆Cl₁₀) and perfluoropyrene (C₁₆F₁₀) were separated and charac-terized. The features of the plasma reaction and product formation mechanism have been discussed. The products of the plasma reaction are normally a series of compounds with similar structure. Their formation appeared not to be affected by the compositions or structures of the reagents, as well as the discharge conditions.
- perchloropyrene,
- perfluoropyrene,
- plasma synthesis,
- arc-discharge,
- glow-discharge
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