Citation: Yimeng Yang, Xianqiong Jiang, Yuanyuan Li, Wei Tan. Review on Photocatalyzed Cycloaddition Reaction with Chromium Catalysts[J]. Chemistry, ;2021, 84(4): 353-358. shu

Review on Photocatalyzed Cycloaddition Reaction with Chromium Catalysts

College of Biological&Chemical Engineering, Chongqing University of Education, Chongqing, 400067

Corresponding author: Yimeng Yang, yangmeng0306@163.com
Received Date: 6 September 2020
Accepted Date: 2 November 2020

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The preparation of biologically/pharmacologically active compounds via economical and environmentally friendly strategies have received increasing attention in the past century, and have shown great utility in organic synthesis, pharmaceutical chemistry and bio-chemistry. The recent development of transition metal catalyzed photoredox reaction sheds light on this problem. Nonetheless, the replacement of the rare-metal catalyst (Ru or Ir complexes) with earth-abundant metal catalysts (Chromium catalysts) is unambiguously more attractive for practical applications. To this end, the chromium complex as the photocatalyst have been successfully accomplished with high activities. The high chemo-, regio-and stereo-selectivity [2+N] cycloaddition of alkene/alkyne with photocatalysts was the most general protocol to form important ring motif in various natural products and medicinally active compounds. In this paper, the recent experimental and theoretical exploration on Cr complex catalyzed photoredox [2+N] cycloaddition reaction were reviewed. On this basis, the unsettled problems and future development direction were prospected. We hope the provided insights could benefit the deep understanding of Cr complexes catalysed [2+N] cycloaddition and the development of new first-row transition metal catalyst and synthetic strategies.
- Transition metal chromium,
- Photocatalyst,
- Cycloaddition,
- Mechanism
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沈阳化工大学材料科学与工程学院沈阳 110142