Citation: YANO Shigenobu. INTELLIGENT METATAL COMPLEXES CONTAINING N-GLYCOSIDES FORMED FROM TRIS (2-AMINOETHYL) AMINE AND ALDOSES, HAVING MOLECULAR RECOGNITION ABILITY[J]. Chinese Journal of Polymer Science, ;1998, 16(3): 193-206. shu

INTELLIGENT METATAL COMPLEXES CONTAINING N-GLYCOSIDES FORMED FROM TRIS (2-AMINOETHYL) AMINE AND ALDOSES, HAVING MOLECULAR RECOGNITION ABILITY

YANO Shigenobu

Received Date: 12 December 1997

Assembly of carbohydrates on nickel (Ⅱ) center by utilizing N-glycosidicbond formation with a branched amine: tris(2-aminoethyl)amine (tren), an unprecedentedchiral inversion around the metal center (Co or Mn) induced by an interaction betweensugars and sulfate anions, peroxo-bridged dinuclear cobalt (Ⅲ) complex containing N-glycoside ligands from tren and D-glucose and its reversible dioxygen binding property,and novel trimanganese complexes with a linear Mn3 (Ⅱ, Ⅲ, Ⅱ) assemblage bridged bycarbohydrates are described.
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